Concomitant spin-canted antiferromagnetic ordering and proton conduction in homometallic and homoleptic coordination polymers

Concomitant spin-canted antiferromagnetic ordering and proton conduction in homometallic and homoleptic coordination polymers

Two unprecedented oxonate based 1D coordination polymers with Fe(II) and Co(II) have been synthesized. A detailed magnetic investigation revealed that these complexes are the first oxonate based systems to exhibit spin canted antiferromagnetic ordering at low temperatures. Proton conductivity studie...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2015-03, Vol.44 (9), p.3949-3953
Hauptverfasser: Goswami, Soumyabrata, Biswas, Soumava, Konar, Sanjit
Format: Artikel
Sprache:eng
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Antiferromagnetism
Coordination polymers
Filing
High temperature
Humidity
Order disorder
Proton conduction
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container_title Dalton transactions : an international journal of inorganic chemistry
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creator Goswami, Soumyabrata
Biswas, Soumava
Konar, Sanjit
description Two unprecedented oxonate based 1D coordination polymers with Fe(II) and Co(II) have been synthesized. A detailed magnetic investigation revealed that these complexes are the first oxonate based systems to exhibit spin canted antiferromagnetic ordering at low temperatures. Proton conductivity studies of the complexes showed good proton conduction ability at elevated temperatures and under high humidity conditions.
doi_str_mv 10.1039/c4dt03575e
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Antiferromagnetism
Coordination polymers
Filing
High temperature
Humidity
Order disorder
Proton conduction
title Concomitant spin-canted antiferromagnetic ordering and proton conduction in homometallic and homoleptic coordination polymers
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