Thermal annealing effect on cellulose acetate reverse osmosis membrane structure
The structure variation of cellulose acetate (CA) reverse osmosis (RO) membranes due to thermal annealing was investigated by using gas adsorption. When the CA membranes were dehydrated by freeze-drying, the morphology of the unannealed membrane was similar to that of the annealed membrane. On the c...
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Veröffentlicht in: | Desalination 1995, Vol.101 (2), p.195-200 |
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creator | Han, Myeong-Jin Bhattacharyya, Dibakar |
description | The structure variation of cellulose acetate (CA) reverse osmosis (RO) membranes due to thermal annealing was investigated by using gas adsorption. When the CA membranes were dehydrated by freeze-drying, the morphology of the unannealed membrane was similar to that of the annealed membrane. On the contrary, with air-drying which induced structure collapse of the CA membranes, gas adsorption behavior of the unannealed membrane showed a significant difference from that of the annealed membrane. The CA RO membrane in an unannealed state totally collapsed during air-drying, but the membrane that was annealed for 10 min at 90°C showed significantly reduced collapsing compared to the unannealed one. However, even though the CA membranes were annealed, use of methanol as the wetting agent caused complete collapsing during air-drying. |
doi_str_mv | 10.1016/0011-9164(95)00022-T |
format | Article |
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When the CA membranes were dehydrated by freeze-drying, the morphology of the unannealed membrane was similar to that of the annealed membrane. On the contrary, with air-drying which induced structure collapse of the CA membranes, gas adsorption behavior of the unannealed membrane showed a significant difference from that of the annealed membrane. The CA RO membrane in an unannealed state totally collapsed during air-drying, but the membrane that was annealed for 10 min at 90°C showed significantly reduced collapsing compared to the unannealed one. 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When the CA membranes were dehydrated by freeze-drying, the morphology of the unannealed membrane was similar to that of the annealed membrane. On the contrary, with air-drying which induced structure collapse of the CA membranes, gas adsorption behavior of the unannealed membrane showed a significant difference from that of the annealed membrane. The CA RO membrane in an unannealed state totally collapsed during air-drying, but the membrane that was annealed for 10 min at 90°C showed significantly reduced collapsing compared to the unannealed one. However, even though the CA membranes were annealed, use of methanol as the wetting agent caused complete collapsing during air-drying.</description><subject>Applied sciences</subject><subject>Chemical engineering</subject><subject>Exact sciences and technology</subject><subject>Marine</subject><subject>Membrane separation (reverse osmosis, dialysis...)</subject><subject>Reverse osmosis</subject><subject>Thermal annealing</subject><issn>0011-9164</issn><issn>1873-4464</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1995</creationdate><recordtype>article</recordtype><recordid>eNp9kE9LxDAQxYMouK5-Aw89iOihmqTZpLkIsvgPFvRQzyFNJxppmzVpF_z2pu6yR0_DwJs37_0QOif4hmDCbzEmJJeEsyu5uMYYU5pXB2hGSlHkjHF2iGZ7yTE6ifErrVQWxQy9VZ8QOt1muu9Bt67_yMBaMEPm-8xA246tj5BpA4MeIAuwgZB2HzsfXcw66Oqge8jiEEYzjAFO0ZHVbYSz3Zyj98eHavmcr16fXpb3q9wwjIdcc8sLrDWxkjWEsKbBtsaaAkggjRE1ExxDXVNaGk6tLghvhKypwFpwyWgxR5db33Xw3yPEQXUuToFTGj9GRbgQWBRlErKt0AQfYwCr1sF1OvwogtWET01s1MRGyYX6w6eqdHax89fR6NamlsbF_W2xoIyWk_vdVgap68ZBUNE46A00LiSKqvHu_z-_nHyEpw</recordid><startdate>1995</startdate><enddate>1995</enddate><creator>Han, Myeong-Jin</creator><creator>Bhattacharyya, Dibakar</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TN</scope><scope>7UA</scope><scope>C1K</scope><scope>F1W</scope><scope>H96</scope><scope>L.G</scope></search><sort><creationdate>1995</creationdate><title>Thermal annealing effect on cellulose acetate reverse osmosis membrane structure</title><author>Han, Myeong-Jin ; Bhattacharyya, Dibakar</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c400t-a6f630aa1f94d114dd0fb0a2ee9e1dc7b4760ebb228c62fa316d79b270a769423</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1995</creationdate><topic>Applied sciences</topic><topic>Chemical engineering</topic><topic>Exact sciences and technology</topic><topic>Marine</topic><topic>Membrane separation (reverse osmosis, dialysis...)</topic><topic>Reverse osmosis</topic><topic>Thermal annealing</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Han, Myeong-Jin</creatorcontrib><creatorcontrib>Bhattacharyya, Dibakar</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Oceanic Abstracts</collection><collection>Water Resources Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy & Non-Living Resources</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><jtitle>Desalination</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Han, Myeong-Jin</au><au>Bhattacharyya, Dibakar</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermal annealing effect on cellulose acetate reverse osmosis membrane structure</atitle><jtitle>Desalination</jtitle><date>1995</date><risdate>1995</risdate><volume>101</volume><issue>2</issue><spage>195</spage><epage>200</epage><pages>195-200</pages><issn>0011-9164</issn><eissn>1873-4464</eissn><coden>DSLNAH</coden><abstract>The structure variation of cellulose acetate (CA) reverse osmosis (RO) membranes due to thermal annealing was investigated by using gas adsorption. 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subjects | Applied sciences Chemical engineering Exact sciences and technology Marine Membrane separation (reverse osmosis, dialysis...) Reverse osmosis Thermal annealing |
title | Thermal annealing effect on cellulose acetate reverse osmosis membrane structure |
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