Geochemical multielement signatures of glacial and interglacial facies of the Okhotsk Sea deepwater sediments during the past 350kyr: A response to global climate changes at the orbital and millennial scales

The previously dated deepwater sediment core MR06-04 PC-7R (length 1723cm; 350kyr) recovered from the central Okhotsk Sea (OS) was analyzed for biogenic compounds and for 63 chemical elements (using the inductively coupled plasma-mass spectrometry method) with a high resolution (1cm; ~200years). A o...

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Veröffentlicht in:Paleoceanography 2015-03, Vol.30 (3), p.303-316
Hauptverfasser: Chebykin, Eugene P, Gorbarenko, Sergey A, Stepanova, Ol'ga G, Panov, Vsevolod S, Goldberg, Evgeny L
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container_issue 3
container_start_page 303
container_title Paleoceanography
container_volume 30
creator Chebykin, Eugene P
Gorbarenko, Sergey A
Stepanova, Ol'ga G
Panov, Vsevolod S
Goldberg, Evgeny L
description The previously dated deepwater sediment core MR06-04 PC-7R (length 1723cm; 350kyr) recovered from the central Okhotsk Sea (OS) was analyzed for biogenic compounds and for 63 chemical elements (using the inductively coupled plasma-mass spectrometry method) with a high resolution (1cm; ~200years). A one box model with two main members" and mathematical methods (based on multielemental composition of sediments) for the calculation of weight fractions (at each time slice) of two main types of geochemical facies that dominate during considerably diverse climatic periods (glacial maxima and interglacial optima) were proposed and tested. This model can be applied to other analogous natural systems whose sedimentation is driven by two main types of geochemical facies. The application of the developed model to the studied core revealed that variations of weight fractions of the typical interglacial and glacial geochemical facies in the sediments along the core depth (named as warm and cold "covariators," respectively) change synchronously with global and regional climate variability. Profiles of warm and inversed cold covariators coincide tightly, and their values increase during warm marine isotope stages and substages and decrease during cold ones over the last 350kyr. Millennial scale changes in covariators had occurred simultaneously with abrupt variability in the OS productivity and sediment lithology and with millennial global climate variability. Some discrepancies in the warm and inversed cold covariators calculated using specific mathematical treatments revealed the episodic influence of volcanogenic matter presented in the core by visible tephra layers and cryptotephras. Key Points A 350kyr multielemental record of the Okhotsk Sea sediment core is obtained Fractions of glacial and interglacial facies along the core depth are calculated Profiles of both types of facies fractions vary in phase with climate changes
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A one box model with two main members" and mathematical methods (based on multielemental composition of sediments) for the calculation of weight fractions (at each time slice) of two main types of geochemical facies that dominate during considerably diverse climatic periods (glacial maxima and interglacial optima) were proposed and tested. This model can be applied to other analogous natural systems whose sedimentation is driven by two main types of geochemical facies. The application of the developed model to the studied core revealed that variations of weight fractions of the typical interglacial and glacial geochemical facies in the sediments along the core depth (named as warm and cold "covariators," respectively) change synchronously with global and regional climate variability. Profiles of warm and inversed cold covariators coincide tightly, and their values increase during warm marine isotope stages and substages and decrease during cold ones over the last 350kyr. Millennial scale changes in covariators had occurred simultaneously with abrupt variability in the OS productivity and sediment lithology and with millennial global climate variability. Some discrepancies in the warm and inversed cold covariators calculated using specific mathematical treatments revealed the episodic influence of volcanogenic matter presented in the core by visible tephra layers and cryptotephras. 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A one box model with two main members" and mathematical methods (based on multielemental composition of sediments) for the calculation of weight fractions (at each time slice) of two main types of geochemical facies that dominate during considerably diverse climatic periods (glacial maxima and interglacial optima) were proposed and tested. This model can be applied to other analogous natural systems whose sedimentation is driven by two main types of geochemical facies. The application of the developed model to the studied core revealed that variations of weight fractions of the typical interglacial and glacial geochemical facies in the sediments along the core depth (named as warm and cold "covariators," respectively) change synchronously with global and regional climate variability. Profiles of warm and inversed cold covariators coincide tightly, and their values increase during warm marine isotope stages and substages and decrease during cold ones over the last 350kyr. Millennial scale changes in covariators had occurred simultaneously with abrupt variability in the OS productivity and sediment lithology and with millennial global climate variability. Some discrepancies in the warm and inversed cold covariators calculated using specific mathematical treatments revealed the episodic influence of volcanogenic matter presented in the core by visible tephra layers and cryptotephras. 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350kyr) recovered from the central Okhotsk Sea (OS) was analyzed for biogenic compounds and for 63 chemical elements (using the inductively coupled plasma-mass spectrometry method) with a high resolution (1cm; ~200years). 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Millennial scale changes in covariators had occurred simultaneously with abrupt variability in the OS productivity and sediment lithology and with millennial global climate variability. Some discrepancies in the warm and inversed cold covariators calculated using specific mathematical treatments revealed the episodic influence of volcanogenic matter presented in the core by visible tephra layers and cryptotephras. Key Points A 350kyr multielemental record of the Okhotsk Sea sediment core is obtained Fractions of glacial and interglacial facies along the core depth are calculated Profiles of both types of facies fractions vary in phase with climate changes</abstract><cop>Washington</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1002/2014PA002718</doi><tpages>14</tpages></addata></record>
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source Wiley Online Library; Wiley Online Library Journals; Wiley-Blackwell AGU Digital Archive
subjects Chemical compounds
Chemical elements
Climate
Climate change
Climate variability
Cold
Composition
Deep water
Depth
Elements
Geochemistry
Glacial periods
Global climate
Global climate variability
High resolution
Inductively coupled plasma mass spectrometry
Interglacial periods
Isotopes
Length
Lithology
Mass spectrometry
Mass spectroscopy
Mathematical analysis
Mathematical models
Methods
Microprocessors
Phase transitions
Productivity
Profiles
Regional climates
Resolution
Sediment
Sedimentary facies
Sedimentation
Sediments
Signatures
Spectrometry
Tephra
Variability
Volcanoes
Weight
title Geochemical multielement signatures of glacial and interglacial facies of the Okhotsk Sea deepwater sediments during the past 350kyr: A response to global climate changes at the orbital and millennial scales
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