N,N'-Dialkyl-N,N'-diaryl-1,10-phenanthroline-2,9-dicarboxamides as donor ligands for separation of rare earth elements with a high and unusual selectivity. DFT computational and experimental studies
N,N'-Dialkyl-N,N'-diaryl-1,10-phenanthroline-2,9-dicarboxamides (IV) were predicted (DFT simulation) and then were proved experimentally to be efficient donor ligands with high and unusual selectivity for the extraction separation of lanthanides. Distribution coefficients D of lanthanide c...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2015-05, Vol.51 (35), p.7466-7469 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Ustynyuk, Yu A Borisova, N E Babain, V A Gloriozov, I P Manuilov, A Y Kalmykov, S N Alyapyshev, M Yu Tkachenko, L I Kenf, E V Ustynyuk, N A |
| description | N,N'-Dialkyl-N,N'-diaryl-1,10-phenanthroline-2,9-dicarboxamides (IV) were predicted (DFT simulation) and then were proved experimentally to be efficient donor ligands with high and unusual selectivity for the extraction separation of lanthanides. Distribution coefficients D of lanthanide cations in two-phase aqueous solution-polar organic solvent decrease with increasing Ln(3+) atomic number. The selectivity factors SFLn1/Ln2 for adjacent lanthanide ions were found to be about 3. |
| doi_str_mv | 10.1039/c5cc01620g |
| format | Article |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | N,N'-Dialkyl-N,N'-diaryl-1,10-phenanthroline-2,9-dicarboxamides as donor ligands for separation of rare earth elements with a high and unusual selectivity. DFT computational and experimental studies |
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