Pd-Catalyzed Electrohydrogenation of Carbon Dioxide to Formate: High Mass Activity at Low Overpotential and Identification of the Deactivation Pathway

Electrochemical reduction of CO2 to formate (HCO2 –) powered by renewable electricity is a possible carbon-negative alternative to synthesizing formate from fossil fuels. This process is energetically inefficient because >1 V of overpotential is required for CO2 reduction to HCO2 – on the metals...

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Veröffentlicht in:Journal of the American Chemical Society 2015-04, Vol.137 (14), p.4701-4708
Hauptverfasser: Min, Xiaoquan, Kanan, Matthew W
Format: Artikel
Sprache:eng
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