Synthesis and Polymerization of Renewable 1,3‐Cyclohexadiene Using Metathesis, Isomerization, and Cascade Reactions with Late‐metal Catalysts

Synthesis and subsequent polymerization of renewable 1,3‐cyclohexadiene (1,3‐CHD) from plant oils is reported via metathesis and isomerization reactions. The metathesis reaction required no plant oil purification, minimal catalyst loading, no organic solvents, and simple product recovery by distilla...

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Veröffentlicht in:	Macromolecular rapid communications. 2011-09, Vol.32 (17), p.1338-1342
Hauptverfasser:	Mathers, Robert T., Shreve, Michael J., Meyler, Etan, Damodaran, Krishnan, Iwig, David F., Kelley, Diana J.
Format:	Artikel
Sprache:	eng
Schlagworte:	Cascade chemical reactions cascade reaction Catalysis Catalysts cyclohexadiene (CHD) Cyclohexenes - chemical synthesis Cyclohexenes - chemistry Decomposition reactions Green Chemistry Technology Isomerization Metathesis Polymerization renewable resources Ruthenium - chemistry Soybean Oil - chemistry Stereoisomerism Synthesis Terpenes - chemistry Toluene - chemistry
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