Effect of π–π+ Stacking on the Layering of Ionic Liquids Confined to an Amorphous Carbon Surface

Effect of π–π+ Stacking on the Layering of Ionic Liquids Confined to an Amorphous Carbon Surface

In the current paper, AFM studies were conducted on nanometer-thick ionic liquids (ILs) confined to an amorphous carbon (AC) surface, which is critical to the design of the next-generation media lubricant for hard disk drives (HDDs). The results indicated that the existence of the delocalized ring i...

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Veröffentlicht in:ACS applied materials & interfaces 2015-04, Vol.7 (13), p.7078-7081
Hauptverfasser: Gong, Xiao, Kozbial, Andrew, Rose, Franck, Li, Lei
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Rose, Franck
Li, Lei
description In the current paper, AFM studies were conducted on nanometer-thick ionic liquids (ILs) confined to an amorphous carbon (AC) surface, which is critical to the design of the next-generation media lubricant for hard disk drives (HDDs). The results indicated that the existence of the delocalized ring in the cation is critical to layering of ILs. Extended layering was observed only when there is imidazolium ring in the cation. When the imidazolium ring is replaced by an aliphatic moiety, “drop-on-layer” (dewetting) structure was observed. On the basis of the experimental results, we proposed that π–π+ stacking between sp2 carbon in the AC and the imidazolium cation in the ILs is the key to the extended layering of ILs at the ILs/AC interface.
doi_str_mv 10.1021/acsami.5b01140
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title Effect of π–π+ Stacking on the Layering of Ionic Liquids Confined to an Amorphous Carbon Surface
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