Aqueous ring-opening metathesis polymerization and copolymerization of 2,3-dicarboxylic acid anhydride, 2,3-bis(methoxymethyl) and 2,3-dicarboxylic acid mono-methyl ester derivatives of 7-oxanorbornene
The aqueous ring-opening metathesis polymerization of 2,3-dicarboxylic acid anhydride (I), 2,3-bis(methoxymethyl) (II) and 2,3-dicarboxylic acid mono-methyl ester (III) derivatives of 7-oxanorbornene was explored. Reactions were catalysed by commercial ruthenium trichloride with aqueous ethanol or w...
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| Veröffentlicht in: | European polymer journal 1993, Vol.29 (2), p.269-279 |
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| container_title | European polymer journal |
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| creator | Lu, Shui-Yu Quayle, Peter Heatley, Frank Booth, Colin Yeates, Stephen G. Padget, John C. |
| description | The aqueous ring-opening metathesis polymerization of 2,3-dicarboxylic acid anhydride (I), 2,3-bis(methoxymethyl) (II) and 2,3-dicarboxylic acid mono-methyl ester (III) derivatives of 7-oxanorbornene was explored. Reactions were catalysed by commercial ruthenium trichloride with aqueous ethanol or water as solvent. The anhydride ring opened during polymerization of I. The rate of polymerization of III exceeded that of II. The copolymerization of II and III was investigated for the case of monomers either mixed initially or added sequentially. Solubility data indicated that statistical copolymers were produced in both cases. |
| doi_str_mv | 10.1016/0014-3057(93)90093-U |
| format | Article |
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Reactions were catalysed by commercial ruthenium trichloride with aqueous ethanol or water as solvent. The anhydride ring opened during polymerization of I. The rate of polymerization of III exceeded that of II. The copolymerization of II and III was investigated for the case of monomers either mixed initially or added sequentially. 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Reactions were catalysed by commercial ruthenium trichloride with aqueous ethanol or water as solvent. The anhydride ring opened during polymerization of I. The rate of polymerization of III exceeded that of II. The copolymerization of II and III was investigated for the case of monomers either mixed initially or added sequentially. Solubility data indicated that statistical copolymers were produced in both cases.</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymerization</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><issn>0014-3057</issn><issn>1873-1945</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1993</creationdate><recordtype>article</recordtype><recordid>eNp9kU1rFTEYhYMoeK3-AxdZiLTQ1GTyMZONUEo_hIKbdh1yk3e8kZnkmkwvHf-h_8rMvaULka4OhOecQ96D0EdGzxhl6gulTBBOZXus-YmmVHNy_wqtWNdywrSQr9HqGXmL3pXyk1LacsVX6M_5rwdIDwXnEH-QtIVYFY8w2WkDJRS8TcM8Qg6_7RRSxDZ67NI_j6nHzSknPjib1-lxHoLD1gVf6c3sc_BwugfWoRzX6E1FFpmHk33e_71jiokcMAxlgox9bdzVxh2UpbIl6dHGVF05QoT36E1vhwIfnvQI3V1d3l3ckNvv198uzm-J40pMpJeS0zUITTUF10inBGeNttIrKX3nGib4mkvXg1KsbVupPXSdEl3PbS8EP0KfD7HbnOrpymTGUBwMg43LHQ1TLdO64RUUB9DlVEqG3mxzGG2eDaNmmc0sm5hlE6O52c9m7qvt01O-Lc4OfbbRhfLsFUK3kuuKfT1gUL-6C5BNcQGiAx8yuMn4FF7u-Qvdq6_k</recordid><startdate>1993</startdate><enddate>1993</enddate><creator>Lu, Shui-Yu</creator><creator>Quayle, Peter</creator><creator>Heatley, Frank</creator><creator>Booth, Colin</creator><creator>Yeates, Stephen G.</creator><creator>Padget, John C.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>1993</creationdate><title>Aqueous ring-opening metathesis polymerization and copolymerization of 2,3-dicarboxylic acid anhydride, 2,3-bis(methoxymethyl) and 2,3-dicarboxylic acid mono-methyl ester derivatives of 7-oxanorbornene</title><author>Lu, Shui-Yu ; Quayle, Peter ; Heatley, Frank ; Booth, Colin ; Yeates, Stephen G. ; Padget, John C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c364t-f5530be49090ec25c643129a5d655d8c2143b35cfe66177759de88648f3af443</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1993</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymerization</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lu, Shui-Yu</creatorcontrib><creatorcontrib>Quayle, Peter</creatorcontrib><creatorcontrib>Heatley, Frank</creatorcontrib><creatorcontrib>Booth, Colin</creatorcontrib><creatorcontrib>Yeates, Stephen G.</creatorcontrib><creatorcontrib>Padget, John C.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>European polymer journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lu, Shui-Yu</au><au>Quayle, Peter</au><au>Heatley, Frank</au><au>Booth, Colin</au><au>Yeates, Stephen G.</au><au>Padget, John C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Aqueous ring-opening metathesis polymerization and copolymerization of 2,3-dicarboxylic acid anhydride, 2,3-bis(methoxymethyl) and 2,3-dicarboxylic acid mono-methyl ester derivatives of 7-oxanorbornene</atitle><jtitle>European polymer journal</jtitle><date>1993</date><risdate>1993</risdate><volume>29</volume><issue>2</issue><spage>269</spage><epage>279</epage><pages>269-279</pages><issn>0014-3057</issn><eissn>1873-1945</eissn><coden>EUPJAG</coden><abstract>The aqueous ring-opening metathesis polymerization of 2,3-dicarboxylic acid anhydride (I), 2,3-bis(methoxymethyl) (II) and 2,3-dicarboxylic acid mono-methyl ester (III) derivatives of 7-oxanorbornene was explored. Reactions were catalysed by commercial ruthenium trichloride with aqueous ethanol or water as solvent. The anhydride ring opened during polymerization of I. The rate of polymerization of III exceeded that of II. The copolymerization of II and III was investigated for the case of monomers either mixed initially or added sequentially. Solubility data indicated that statistical copolymers were produced in both cases.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/0014-3057(93)90093-U</doi><tpages>11</tpages></addata></record> |
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| ispartof | European polymer journal, 1993, Vol.29 (2), p.269-279 |
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| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts |
| title | Aqueous ring-opening metathesis polymerization and copolymerization of 2,3-dicarboxylic acid anhydride, 2,3-bis(methoxymethyl) and 2,3-dicarboxylic acid mono-methyl ester derivatives of 7-oxanorbornene |
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