Epitaxial growth of graphene on transition metal surfaces: chemical vapor deposition versus liquid phase deposition

The epitaxial growth of graphene on transition metal surfaces by ex situ deposition of liquid precursors (LPD, liquid phase deposition) is compared to the standard method of chemical vapor deposition (CVD). The performance of LPD strongly depends on the particular transition metal surface. For Pt(11...

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Veröffentlicht in:Journal of physics. Condensed matter 2012-08, Vol.24 (31), p.314204-314204
Hauptverfasser: Grandthyll, Samuel, Gsell, Stefan, Weinl, Michael, Schreck, Matthias, Hüfner, Stefan, Müller, Frank
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container_end_page 314204
container_issue 31
container_start_page 314204
container_title Journal of physics. Condensed matter
container_volume 24
creator Grandthyll, Samuel
Gsell, Stefan
Weinl, Michael
Schreck, Matthias
Hüfner, Stefan
Müller, Frank
description The epitaxial growth of graphene on transition metal surfaces by ex situ deposition of liquid precursors (LPD, liquid phase deposition) is compared to the standard method of chemical vapor deposition (CVD). The performance of LPD strongly depends on the particular transition metal surface. For Pt(111), Ir(111) and Rh(111), the formation of a graphene monolayer is hardly affected by the way the precursor is provided. In the case of Ni(111), the growth of graphene strongly depends on the applied synthesis method. For CVD of propene on Ni(111), a 1 × 1 structure as expected from the vanishing lattice mismatch is observed. However, in spite of the nearly perfect lattice match, a multi-domain structure with 1 × 1 and two additional rotated domains is obtained when an oxygen-containing precursor (acetone) is provided ex situ.
doi_str_mv 10.1088/0953-8984/24/31/314204
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source IOP Publishing Journals; Institute of Physics (IOP) Journals - HEAL-Link
subjects Chemical vapor deposition
Chemical vapor deposition (including plasma-enhanced cvd, mocvd, etc.)
Condensed matter
Cross-disciplinary physics: materials science
rheology
Epitaxial growth
Exact sciences and technology
Graphene
Lattices
Liquid phase deposition
Liquid phase epitaxy
deposition from liquid phases (melts, solutions, and surface layers on liquids)
Materials science
Methods of deposition of films and coatings
film growth and epitaxy
Physics
Precursors
Transition metals
title Epitaxial growth of graphene on transition metal surfaces: chemical vapor deposition versus liquid phase deposition
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