Towards the self-assembly of anisotropic colloids: Monodisperse oblate ellipsoids

[Display omitted] •Developed a new method for creating non-spherical colloidal particles.•Produced oblate ellipsoidal particles of controlled, uniform size and shape.•Optimized method to maintain high fluorescence intensity for 3D confocal imaging.•Opens up new possibilities for studying the behavio...

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Veröffentlicht in:Journal of colloid and interface science 2014-02, Vol.416 (416), p.30-37
Hauptverfasser: Florea, Daniel, Wyss, Hans M.
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Wyss, Hans M.
description [Display omitted] •Developed a new method for creating non-spherical colloidal particles.•Produced oblate ellipsoidal particles of controlled, uniform size and shape.•Optimized method to maintain high fluorescence intensity for 3D confocal imaging.•Opens up new possibilities for studying the behavior of non-spherical colloids. We present a robust and straightforward method for producing colloidal particles of oblate ellipsoidal shape via thermo/mechanical stretching of elastomeric films with embedded spherical particles. Our method produces uniformly sized and shaped colloidal particles. The method can be used for producing biaxially stretched particles of different aspect ratios and volumes; moreover, the method has a higher yield and batch size than previously reported methods for producing non-spherical particles via film stretching. These particles are ideal model systems for studying the self-assembly and gel formation for systems with anisotropic shapes and interactions. We illustrate this by adding of a non-adsorbing polymer to the solvent, thereby inducing directional depletion interactions between the particles.
doi_str_mv 10.1016/j.jcis.2013.10.027
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subjects Anisotropic colloids
Anisotropy
Aspect ratio
Biaxial
Chemistry
Colloidal state and disperse state
Colloids
Depletion
Ellipsoids
Exact sciences and technology
General and physical chemistry
Oblate ellipsoids
Physical and chemical studies. Granulometry. Electrokinetic phenomena
Self assembly
Solvents
Stretching
Thermo/mechanical stretching
title Towards the self-assembly of anisotropic colloids: Monodisperse oblate ellipsoids
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