Solute-volume effects in electrolyte transport

A model elucidates two transport mechanisms associated with the volumes dissolved electrolytes occupy: the ‘excluded-volume effect’, which arises when concentration polarization induces solution-density gradients that drive volume redistribution; and ‘Faradaic convection’, which occurs when interfac...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Electrochimica acta 2014-07, Vol.135, p.447-460
Hauptverfasser:	Liu, Jing, Monroe, Charles W.
Format:	Artikel
Sprache:	eng
Schlagworte:	Concentrated-solution theory Convection modes Diffusion Electrolytes Finite-volume effects Local density variation Mathematical analysis Mathematical models Non-aqueous electrolytes Nonaqueous electrolytes Polarization Reaction-induced convection Transport
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!