Catalytic and Structural Studies of Hoveyda-Grubbs Type Pre-Catalysts Bearing Modified Ether Ligands

Catalytic and crystallographic studies of Hoveyda–Grubbs type pre‐catalysts M51TM and M52TM were performed. These two new instruments in the olefin metathesis catalyst toolbox were shown to be active at ambient temperature and at low loading, leading to clean formation of ring‐closing, ring‐closing...

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Veröffentlicht in:	Advanced synthesis & catalysis 2012-10, Vol.354 (14-15), p.2734-2742
Hauptverfasser:	Guidone, Stefano, Blondiaux, Enguerrand, Samojłowicz, Cezary, Gułajski, Łukasz, Kędziorek, Mariusz, Malińska, Maura, Pazio, Aleksandra, Woźniak, Krzysztof, Grela, Karol, Doppiu, Angelino, Cazin, Catherine S. J.
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Catalysts Catalysts: preparations and properties Chemistry Decomposition reactions Ethers Exact sciences and technology General and physical chemistry Ligands Metathesis N-heterocyclic carbenes olefin metathesis Olefins ring-closing metathesis ruthenium Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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Zusammenfassung:	Catalytic and crystallographic studies of Hoveyda–Grubbs type pre‐catalysts M51TM and M52TM were performed. These two new instruments in the olefin metathesis catalyst toolbox were shown to be active at ambient temperature and at low loading, leading to clean formation of ring‐closing, ring‐closing enyne and cross metathesis products.
ISSN:	1615-4150 1615-4169
DOI:	10.1002/adsc.201200385