Synthesis of cubic Ia-3d mesoporous silica in anionic surfactant templating system with the aid of acetate
[Display omitted] •The cubic Ia-3d mesostructure was obtained with the aid of sodium acetate.•Salts have the ability to induce caterpillar-like morphology of mesoporous silica.•Di-amine functionalized 3D bicontinuous cubic Ia-3d mesoporous silicas were obtained. Mesoporous silica with three-dimensio...
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| Veröffentlicht in: | Journal of colloid and interface science 2014-08, Vol.427 (427), p.42-48 |
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| container_title | Journal of colloid and interface science |
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| creator | Deng, Shao-Xin Xu, Xue-Yan He, Wen-Chao Wang, Jin-Gui Chen, Tie-Hong |
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•The cubic Ia-3d mesostructure was obtained with the aid of sodium acetate.•Salts have the ability to induce caterpillar-like morphology of mesoporous silica.•Di-amine functionalized 3D bicontinuous cubic Ia-3d mesoporous silicas were obtained.
Mesoporous silica with three-dimensional (3D) bicontinuous cubic Ia-3d structure and fascinating caterpillar-like morphology was synthesized by using anionic surfactant N-lauroylsarcosine sodium (Sar-Na) as the template and 3-amionpropyltrimethoxysilane (APS) as the co-structure-directing agent (CSDA) with the aid of acetate. A phase transformation from high interfacial curvature 2D hexagonal to low interfacial curvature 3D cubic Ia-3d occurred in the presence of a proper amount of acetate. Other species of salts (excluding acetate) had the ability to induce the caterpillar-like morphology, but failed to induce the cubic Ia-3d mesostructure. Furthermore, [3-(2-aminoethyl)-aminopropyl]trimethoxysilane (DAPS) was also used as the CSDA to synthesize Ia-3d mesostructured silica under the aid of sodium acetate. After extraction of the anionic surfactants, amino and di-amine functionalized 3D bicontinuous cubic Ia-3d mesoporous silicas were obtained and used as supports to immobilize Pd nanoparticles for supported catalysts. The catalytic activity of the catalysts was tested by catalytic hydrogenation of allyl alcohol. |
| doi_str_mv | 10.1016/j.jcis.2013.12.028 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1671609703</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0021979713011053</els_id><sourcerecordid>1531955264</sourcerecordid><originalsourceid>FETCH-LOGICAL-c419t-27dcdfa9199f91c54f3f67133efd72d0128e106e16a894c130898e0bbec2ad8b3</originalsourceid><addsrcrecordid>eNqFkU2LFDEQhoMo7rj6BzxILoKXblNJfwW8yOLHwoIH9RzSScVN050ek7Qy_940M-5RT0XBUw9V9RLyElgNDLq3Uz0Zn2rOQNTAa8aHR-QATLZVD0w8JgfGOFSyl_0VeZbSxBhA28qn5Io3jRA95wcyfT2FfI_JJ7o6arbRG3qrK2Hpgmk9rnHdEk1-9kZTH6gOfg0FSVt02mQdMs24HGedffhB0ymVjv72-Z4WKdXe7lZtMOuMz8kTp-eELy71mnz_-OHbzefq7sun25v3d5VpQOaK99ZYpyVI6SSYtnHCdT0Igc723DLgAwLrEDo9yMaAYIMckI0jGq7tMIpr8ubsPcb154Ypq8Ung_OsA5ZrFBRbx2TPxP_RVoBsW941BeVn1MQ1pYhOHaNfdDwpYGqPQ01qj0PtcSjgqsRRhl5d_Nu4oH0Y-fv_Ary-ADoZPbuow-544IaWN0O3L_ruzGF53C-PUSXjMRi0PqLJyq7-X3v8AVIjqNI</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1531955264</pqid></control><display><type>article</type><title>Synthesis of cubic Ia-3d mesoporous silica in anionic surfactant templating system with the aid of acetate</title><source>MEDLINE</source><source>Elsevier ScienceDirect Journals</source><creator>Deng, Shao-Xin ; Xu, Xue-Yan ; He, Wen-Chao ; Wang, Jin-Gui ; Chen, Tie-Hong</creator><creatorcontrib>Deng, Shao-Xin ; Xu, Xue-Yan ; He, Wen-Chao ; Wang, Jin-Gui ; Chen, Tie-Hong</creatorcontrib><description>[Display omitted]
•The cubic Ia-3d mesostructure was obtained with the aid of sodium acetate.•Salts have the ability to induce caterpillar-like morphology of mesoporous silica.•Di-amine functionalized 3D bicontinuous cubic Ia-3d mesoporous silicas were obtained.
Mesoporous silica with three-dimensional (3D) bicontinuous cubic Ia-3d structure and fascinating caterpillar-like morphology was synthesized by using anionic surfactant N-lauroylsarcosine sodium (Sar-Na) as the template and 3-amionpropyltrimethoxysilane (APS) as the co-structure-directing agent (CSDA) with the aid of acetate. A phase transformation from high interfacial curvature 2D hexagonal to low interfacial curvature 3D cubic Ia-3d occurred in the presence of a proper amount of acetate. Other species of salts (excluding acetate) had the ability to induce the caterpillar-like morphology, but failed to induce the cubic Ia-3d mesostructure. Furthermore, [3-(2-aminoethyl)-aminopropyl]trimethoxysilane (DAPS) was also used as the CSDA to synthesize Ia-3d mesostructured silica under the aid of sodium acetate. After extraction of the anionic surfactants, amino and di-amine functionalized 3D bicontinuous cubic Ia-3d mesoporous silicas were obtained and used as supports to immobilize Pd nanoparticles for supported catalysts. The catalytic activity of the catalysts was tested by catalytic hydrogenation of allyl alcohol.</description><identifier>ISSN: 0021-9797</identifier><identifier>EISSN: 1095-7103</identifier><identifier>DOI: 10.1016/j.jcis.2013.12.028</identifier><identifier>PMID: 24433722</identifier><identifier>CODEN: JCISA5</identifier><language>eng</language><publisher>Amsterdam: Elsevier Inc</publisher><subject>Acetates ; Amination ; Anionic surfactant ; Anions - chemistry ; Catalysis ; Catalysts ; Caterpillar-like ; Chemistry ; Colloidal state and disperse state ; Curvature ; Exact sciences and technology ; General and physical chemistry ; Ia-3d ; Morphology ; Porosity ; Porous materials ; Sarcosine - analogs & derivatives ; Sarcosine - chemistry ; Silica ; Silicon dioxide ; Silicon Dioxide - chemical synthesis ; Silicon Dioxide - chemistry ; Sodium acetate ; Sodium Acetate - chemistry ; Surface-Active Agents - chemistry ; Surfactants ; Three dimensional</subject><ispartof>Journal of colloid and interface science, 2014-08, Vol.427 (427), p.42-48</ispartof><rights>2013 Elsevier Inc.</rights><rights>2015 INIST-CNRS</rights><rights>Copyright © 2013 Elsevier Inc. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c419t-27dcdfa9199f91c54f3f67133efd72d0128e106e16a894c130898e0bbec2ad8b3</citedby><cites>FETCH-LOGICAL-c419t-27dcdfa9199f91c54f3f67133efd72d0128e106e16a894c130898e0bbec2ad8b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0021979713011053$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28524863$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/24433722$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Deng, Shao-Xin</creatorcontrib><creatorcontrib>Xu, Xue-Yan</creatorcontrib><creatorcontrib>He, Wen-Chao</creatorcontrib><creatorcontrib>Wang, Jin-Gui</creatorcontrib><creatorcontrib>Chen, Tie-Hong</creatorcontrib><title>Synthesis of cubic Ia-3d mesoporous silica in anionic surfactant templating system with the aid of acetate</title><title>Journal of colloid and interface science</title><addtitle>J Colloid Interface Sci</addtitle><description>[Display omitted]
•The cubic Ia-3d mesostructure was obtained with the aid of sodium acetate.•Salts have the ability to induce caterpillar-like morphology of mesoporous silica.•Di-amine functionalized 3D bicontinuous cubic Ia-3d mesoporous silicas were obtained.
Mesoporous silica with three-dimensional (3D) bicontinuous cubic Ia-3d structure and fascinating caterpillar-like morphology was synthesized by using anionic surfactant N-lauroylsarcosine sodium (Sar-Na) as the template and 3-amionpropyltrimethoxysilane (APS) as the co-structure-directing agent (CSDA) with the aid of acetate. A phase transformation from high interfacial curvature 2D hexagonal to low interfacial curvature 3D cubic Ia-3d occurred in the presence of a proper amount of acetate. Other species of salts (excluding acetate) had the ability to induce the caterpillar-like morphology, but failed to induce the cubic Ia-3d mesostructure. Furthermore, [3-(2-aminoethyl)-aminopropyl]trimethoxysilane (DAPS) was also used as the CSDA to synthesize Ia-3d mesostructured silica under the aid of sodium acetate. After extraction of the anionic surfactants, amino and di-amine functionalized 3D bicontinuous cubic Ia-3d mesoporous silicas were obtained and used as supports to immobilize Pd nanoparticles for supported catalysts. The catalytic activity of the catalysts was tested by catalytic hydrogenation of allyl alcohol.</description><subject>Acetates</subject><subject>Amination</subject><subject>Anionic surfactant</subject><subject>Anions - chemistry</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Caterpillar-like</subject><subject>Chemistry</subject><subject>Colloidal state and disperse state</subject><subject>Curvature</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Ia-3d</subject><subject>Morphology</subject><subject>Porosity</subject><subject>Porous materials</subject><subject>Sarcosine - analogs & derivatives</subject><subject>Sarcosine - chemistry</subject><subject>Silica</subject><subject>Silicon dioxide</subject><subject>Silicon Dioxide - chemical synthesis</subject><subject>Silicon Dioxide - chemistry</subject><subject>Sodium acetate</subject><subject>Sodium Acetate - chemistry</subject><subject>Surface-Active Agents - chemistry</subject><subject>Surfactants</subject><subject>Three dimensional</subject><issn>0021-9797</issn><issn>1095-7103</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkU2LFDEQhoMo7rj6BzxILoKXblNJfwW8yOLHwoIH9RzSScVN050ek7Qy_940M-5RT0XBUw9V9RLyElgNDLq3Uz0Zn2rOQNTAa8aHR-QATLZVD0w8JgfGOFSyl_0VeZbSxBhA28qn5Io3jRA95wcyfT2FfI_JJ7o6arbRG3qrK2Hpgmk9rnHdEk1-9kZTH6gOfg0FSVt02mQdMs24HGedffhB0ymVjv72-Z4WKdXe7lZtMOuMz8kTp-eELy71mnz_-OHbzefq7sun25v3d5VpQOaK99ZYpyVI6SSYtnHCdT0Igc723DLgAwLrEDo9yMaAYIMckI0jGq7tMIpr8ubsPcb154Ypq8Ung_OsA5ZrFBRbx2TPxP_RVoBsW941BeVn1MQ1pYhOHaNfdDwpYGqPQ01qj0PtcSjgqsRRhl5d_Nu4oH0Y-fv_Ary-ADoZPbuow-544IaWN0O3L_ruzGF53C-PUSXjMRi0PqLJyq7-X3v8AVIjqNI</recordid><startdate>20140801</startdate><enddate>20140801</enddate><creator>Deng, Shao-Xin</creator><creator>Xu, Xue-Yan</creator><creator>He, Wen-Chao</creator><creator>Wang, Jin-Gui</creator><creator>Chen, Tie-Hong</creator><general>Elsevier Inc</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20140801</creationdate><title>Synthesis of cubic Ia-3d mesoporous silica in anionic surfactant templating system with the aid of acetate</title><author>Deng, Shao-Xin ; Xu, Xue-Yan ; He, Wen-Chao ; Wang, Jin-Gui ; Chen, Tie-Hong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c419t-27dcdfa9199f91c54f3f67133efd72d0128e106e16a894c130898e0bbec2ad8b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Acetates</topic><topic>Amination</topic><topic>Anionic surfactant</topic><topic>Anions - chemistry</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Caterpillar-like</topic><topic>Chemistry</topic><topic>Colloidal state and disperse state</topic><topic>Curvature</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Ia-3d</topic><topic>Morphology</topic><topic>Porosity</topic><topic>Porous materials</topic><topic>Sarcosine - analogs & derivatives</topic><topic>Sarcosine - chemistry</topic><topic>Silica</topic><topic>Silicon dioxide</topic><topic>Silicon Dioxide - chemical synthesis</topic><topic>Silicon Dioxide - chemistry</topic><topic>Sodium acetate</topic><topic>Sodium Acetate - chemistry</topic><topic>Surface-Active Agents - chemistry</topic><topic>Surfactants</topic><topic>Three dimensional</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Deng, Shao-Xin</creatorcontrib><creatorcontrib>Xu, Xue-Yan</creatorcontrib><creatorcontrib>He, Wen-Chao</creatorcontrib><creatorcontrib>Wang, Jin-Gui</creatorcontrib><creatorcontrib>Chen, Tie-Hong</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of colloid and interface science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Deng, Shao-Xin</au><au>Xu, Xue-Yan</au><au>He, Wen-Chao</au><au>Wang, Jin-Gui</au><au>Chen, Tie-Hong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of cubic Ia-3d mesoporous silica in anionic surfactant templating system with the aid of acetate</atitle><jtitle>Journal of colloid and interface science</jtitle><addtitle>J Colloid Interface Sci</addtitle><date>2014-08-01</date><risdate>2014</risdate><volume>427</volume><issue>427</issue><spage>42</spage><epage>48</epage><pages>42-48</pages><issn>0021-9797</issn><eissn>1095-7103</eissn><coden>JCISA5</coden><abstract>[Display omitted]
•The cubic Ia-3d mesostructure was obtained with the aid of sodium acetate.•Salts have the ability to induce caterpillar-like morphology of mesoporous silica.•Di-amine functionalized 3D bicontinuous cubic Ia-3d mesoporous silicas were obtained.
Mesoporous silica with three-dimensional (3D) bicontinuous cubic Ia-3d structure and fascinating caterpillar-like morphology was synthesized by using anionic surfactant N-lauroylsarcosine sodium (Sar-Na) as the template and 3-amionpropyltrimethoxysilane (APS) as the co-structure-directing agent (CSDA) with the aid of acetate. A phase transformation from high interfacial curvature 2D hexagonal to low interfacial curvature 3D cubic Ia-3d occurred in the presence of a proper amount of acetate. Other species of salts (excluding acetate) had the ability to induce the caterpillar-like morphology, but failed to induce the cubic Ia-3d mesostructure. Furthermore, [3-(2-aminoethyl)-aminopropyl]trimethoxysilane (DAPS) was also used as the CSDA to synthesize Ia-3d mesostructured silica under the aid of sodium acetate. After extraction of the anionic surfactants, amino and di-amine functionalized 3D bicontinuous cubic Ia-3d mesoporous silicas were obtained and used as supports to immobilize Pd nanoparticles for supported catalysts. The catalytic activity of the catalysts was tested by catalytic hydrogenation of allyl alcohol.</abstract><cop>Amsterdam</cop><pub>Elsevier Inc</pub><pmid>24433722</pmid><doi>10.1016/j.jcis.2013.12.028</doi><tpages>7</tpages></addata></record> |
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| subjects | Acetates Amination Anionic surfactant Anions - chemistry Catalysis Catalysts Caterpillar-like Chemistry Colloidal state and disperse state Curvature Exact sciences and technology General and physical chemistry Ia-3d Morphology Porosity Porous materials Sarcosine - analogs & derivatives Sarcosine - chemistry Silica Silicon dioxide Silicon Dioxide - chemical synthesis Silicon Dioxide - chemistry Sodium acetate Sodium Acetate - chemistry Surface-Active Agents - chemistry Surfactants Three dimensional |
| title | Synthesis of cubic Ia-3d mesoporous silica in anionic surfactant templating system with the aid of acetate |
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