On the coarsening of the phase morphology of PP/EVA blends during compounding in a twin screw extruder
The coarsening of the phase morphology of polypropylene (PP) blends, containing 20 wt% of the copolymer ethylene vinyl acetate (EVA) as the dispersed phase, during compounding in a co-rotating twin screw extruder (Co-TSE) was investigated. Blending was performed by applying a fixed screw profile, te...
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Veröffentlicht in: | Polymer testing 2014-04, Vol.34, p.175-182 |
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description | The coarsening of the phase morphology of polypropylene (PP) blends, containing 20 wt% of the copolymer ethylene vinyl acetate (EVA) as the dispersed phase, during compounding in a co-rotating twin screw extruder (Co-TSE) was investigated. Blending was performed by applying a fixed screw profile, temperature and screw rotation speed, with various flow rates, which allowed identification of the effect of the residence time on the blend morphology. The average EVA particle size increased linearly with the mean extrusion residence time. From this relationship, the coarsening kinetics, including the minimum droplet size that would be obtained and the coarsening rate due to the domination of coalescence over droplet breakup during extrusion, was quantified. The data reported herein provide greater insight into Wu's theory for the prediction of the droplet size in polymer blends compounded in a Co-TSE. |
doi_str_mv | 10.1016/j.polymertesting.2014.01.012 |
format | Article |
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Blending was performed by applying a fixed screw profile, temperature and screw rotation speed, with various flow rates, which allowed identification of the effect of the residence time on the blend morphology. The average EVA particle size increased linearly with the mean extrusion residence time. From this relationship, the coarsening kinetics, including the minimum droplet size that would be obtained and the coarsening rate due to the domination of coalescence over droplet breakup during extrusion, was quantified. The data reported herein provide greater insight into Wu's theory for the prediction of the droplet size in polymer blends compounded in a Co-TSE.</description><identifier>ISSN: 0142-9418</identifier><identifier>EISSN: 1873-2348</identifier><identifier>DOI: 10.1016/j.polymertesting.2014.01.012</identifier><identifier>CODEN: POTEDZ</identifier><language>eng</language><publisher>Kindlington: Elsevier Ltd</publisher><subject>Applied sciences ; Blends ; Coalescence ; Coarsening ; Droplets ; Ethylene vinyl acetates ; Exact sciences and technology ; Extrusion moulding ; Machinery and processing ; Morphology ; Moulding ; Phase morphology ; Plastics ; Polymer blends ; Polymer industry, paints, wood ; Polypropylenes ; PP/EVA ; Screws ; Technology of polymers ; Twin screw extruder</subject><ispartof>Polymer testing, 2014-04, Vol.34, p.175-182</ispartof><rights>2014 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c543t-57dbd84b68e3f2d5bdde18323407d394f2b5ba454f1f5a053f615974fb94bafd3</citedby><cites>FETCH-LOGICAL-c543t-57dbd84b68e3f2d5bdde18323407d394f2b5ba454f1f5a053f615974fb94bafd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.polymertesting.2014.01.012$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,777,781,3537,27905,27906,45976</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28339616$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Canto, L.B.</creatorcontrib><title>On the coarsening of the phase morphology of PP/EVA blends during compounding in a twin screw extruder</title><title>Polymer testing</title><description>The coarsening of the phase morphology of polypropylene (PP) blends, containing 20 wt% of the copolymer ethylene vinyl acetate (EVA) as the dispersed phase, during compounding in a co-rotating twin screw extruder (Co-TSE) was investigated. Blending was performed by applying a fixed screw profile, temperature and screw rotation speed, with various flow rates, which allowed identification of the effect of the residence time on the blend morphology. The average EVA particle size increased linearly with the mean extrusion residence time. From this relationship, the coarsening kinetics, including the minimum droplet size that would be obtained and the coarsening rate due to the domination of coalescence over droplet breakup during extrusion, was quantified. The data reported herein provide greater insight into Wu's theory for the prediction of the droplet size in polymer blends compounded in a Co-TSE.</description><subject>Applied sciences</subject><subject>Blends</subject><subject>Coalescence</subject><subject>Coarsening</subject><subject>Droplets</subject><subject>Ethylene vinyl acetates</subject><subject>Exact sciences and technology</subject><subject>Extrusion moulding</subject><subject>Machinery and processing</subject><subject>Morphology</subject><subject>Moulding</subject><subject>Phase morphology</subject><subject>Plastics</subject><subject>Polymer blends</subject><subject>Polymer industry, paints, wood</subject><subject>Polypropylenes</subject><subject>PP/EVA</subject><subject>Screws</subject><subject>Technology of polymers</subject><subject>Twin screw extruder</subject><issn>0142-9418</issn><issn>1873-2348</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqNkE1rHDEMhk1podsk_8GHFnqZjT_nA3oJIWkLgeSQ5mo8tpz1MmNP7Zkm--_r6YZCbgGBhPToFXoR-kzJlhJan--3UxwOI6QZ8uzD45YRKraElmDv0Ia2Da8YF-17tCkDVnWCth_Rp5z3hBBZFDbI3QY87wCbqFOGUERwdP86005nwGNM0y4O8fGw9u_uzq8eLnA_QLAZ2yWtvInjFJdg19oHrPH8VFI2CZ4wPM9psZBO0QenhwxnL_kE_bq-ur_8Ud3cfv95eXFTGSn4XMnG9rYVfd0Cd8zK3lqgLS8_kMbyTjjWy14LKRx1UhPJXU1l1wjXd6LXzvIT9PWoO6X4eymuqNFnA8OgA8QlK1o3tCasbWRBvx1Rk2LOCZyakh91OihK1Gqv2qvX9qrVXkVoCVbWv7xc0tnowSUdjM__NVjLeVfTunDXRw7K2388JJWNh2DA-gRmVjb6tx38C8Evms8</recordid><startdate>20140401</startdate><enddate>20140401</enddate><creator>Canto, L.B.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20140401</creationdate><title>On the coarsening of the phase morphology of PP/EVA blends during compounding in a twin screw extruder</title><author>Canto, L.B.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c543t-57dbd84b68e3f2d5bdde18323407d394f2b5ba454f1f5a053f615974fb94bafd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Applied sciences</topic><topic>Blends</topic><topic>Coalescence</topic><topic>Coarsening</topic><topic>Droplets</topic><topic>Ethylene vinyl acetates</topic><topic>Exact sciences and technology</topic><topic>Extrusion moulding</topic><topic>Machinery and processing</topic><topic>Morphology</topic><topic>Moulding</topic><topic>Phase morphology</topic><topic>Plastics</topic><topic>Polymer blends</topic><topic>Polymer industry, paints, wood</topic><topic>Polypropylenes</topic><topic>PP/EVA</topic><topic>Screws</topic><topic>Technology of polymers</topic><topic>Twin screw extruder</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Canto, L.B.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer testing</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Canto, L.B.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>On the coarsening of the phase morphology of PP/EVA blends during compounding in a twin screw extruder</atitle><jtitle>Polymer testing</jtitle><date>2014-04-01</date><risdate>2014</risdate><volume>34</volume><spage>175</spage><epage>182</epage><pages>175-182</pages><issn>0142-9418</issn><eissn>1873-2348</eissn><coden>POTEDZ</coden><abstract>The coarsening of the phase morphology of polypropylene (PP) blends, containing 20 wt% of the copolymer ethylene vinyl acetate (EVA) as the dispersed phase, during compounding in a co-rotating twin screw extruder (Co-TSE) was investigated. Blending was performed by applying a fixed screw profile, temperature and screw rotation speed, with various flow rates, which allowed identification of the effect of the residence time on the blend morphology. The average EVA particle size increased linearly with the mean extrusion residence time. From this relationship, the coarsening kinetics, including the minimum droplet size that would be obtained and the coarsening rate due to the domination of coalescence over droplet breakup during extrusion, was quantified. The data reported herein provide greater insight into Wu's theory for the prediction of the droplet size in polymer blends compounded in a Co-TSE.</abstract><cop>Kindlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.polymertesting.2014.01.012</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
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source | Elsevier ScienceDirect Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals |
subjects | Applied sciences Blends Coalescence Coarsening Droplets Ethylene vinyl acetates Exact sciences and technology Extrusion moulding Machinery and processing Morphology Moulding Phase morphology Plastics Polymer blends Polymer industry, paints, wood Polypropylenes PP/EVA Screws Technology of polymers Twin screw extruder |
title | On the coarsening of the phase morphology of PP/EVA blends during compounding in a twin screw extruder |
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