New processing method for tungsten carbide nano-crystalline particles and nano structural carbon via polyacrylonitrile gasification
A simple processing route has been developed for a nano-sized crystalline tungsten mono-carbide (WC) and a novel nano-structural carbon materials. Starting materials for WC synthesis were selected tungstic acid (H2WO4) and polyacrylonitrile (PAN) powders. The starting powders were heat-treated at 12...
Gespeichert in:
| Veröffentlicht in: | Journal of the Ceramic Society of Japan 2014/07/01, Vol.122(1427), pp.570-573 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 573 |
|---|---|
| container_issue | 1427 |
| container_start_page | 570 |
| container_title | Journal of the Ceramic Society of Japan |
| container_volume | 122 |
| creator | ONOKI, Takamasa SHINODA, Yutaka AKATSU, Takashi WAKAI, Fumihiro |
| description | A simple processing route has been developed for a nano-sized crystalline tungsten mono-carbide (WC) and a novel nano-structural carbon materials. Starting materials for WC synthesis were selected tungstic acid (H2WO4) and polyacrylonitrile (PAN) powders. The starting powders were heat-treated at 1200°C for 30 min with a nitorgen gas flow in an alumina tube. The acquired WC powder had a nano-sized crystalline and high-specific surface area (26.0 m2 g−1). Crystallite diameter size was estimated to less than 20 nm. Compared with theoretical value, approximately 2.0 mass % of free carbon was measured in the prepared WC. It was observed that layered graphitic carbon was formed around the WC particles. If the graphitic carbon is separated from the WC particles by appropriate techniques or processing conditions, these techniques using PAN as a carbon source may have possibility for processing not only WC but also nano-structural carbon materials such as graphene. |
| doi_str_mv | 10.2109/jcersj2.122.570 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1671602696</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1671602696</sourcerecordid><originalsourceid>FETCH-LOGICAL-c579t-81f9020c60097d33fcc8e40b9d8df6ad4fe534b4a725f9478b4581e460fdfd1c3</originalsourceid><addsrcrecordid>eNpdkc1vEzEQxVcIJErhzNUSFy6b-mu93iOK-KqqcADOlmOPU68cO9heUM7845gkqtSe5knze6OZeV33luAVJXi6mQ3kMtMVoXQ1jPhZd0UYl70Y2PC8aSlpj0fOXnavSpkxFpQzedX93cAfdMjJQCk-7tAe6n2yyKWM6hJ3pUJERuett4Cijqk3-ViqDsFHQAedqzcBCtLRntqo1LyYumQdTrYU0W-v0SGFo27OkKKv2QdAO12880ZXn-Lr7oXTocCbS73ufn76-GP9pb_79vnr-sNdb4Zxqr0kbsIUG4HxNFrGnDESON5OVlontOUOBsa3XI90cBMf5ZYPkgAX2FlniWHX3fvz3HbvrwVKVXtfDISgI6SlKCJGIjAVk2jouyfonJYc23aKDJyRNp3JRt2cKZNTKRmcOmS_1_moCFb_Q1GXUFQLRbVQmmNzdsztiTt44C-PfMQTTseTuF1_v1UbwjHhD6C511lBZP8Ac1WfvQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1543147838</pqid></control><display><type>article</type><title>New processing method for tungsten carbide nano-crystalline particles and nano structural carbon via polyacrylonitrile gasification</title><source>J-STAGE (Japan Science & Technology Information Aggregator, Electronic) Freely Available Titles - Japanese</source><creator>ONOKI, Takamasa ; SHINODA, Yutaka ; AKATSU, Takashi ; WAKAI, Fumihiro</creator><creatorcontrib>ONOKI, Takamasa ; SHINODA, Yutaka ; AKATSU, Takashi ; WAKAI, Fumihiro</creatorcontrib><description>A simple processing route has been developed for a nano-sized crystalline tungsten mono-carbide (WC) and a novel nano-structural carbon materials. Starting materials for WC synthesis were selected tungstic acid (H2WO4) and polyacrylonitrile (PAN) powders. The starting powders were heat-treated at 1200°C for 30 min with a nitorgen gas flow in an alumina tube. The acquired WC powder had a nano-sized crystalline and high-specific surface area (26.0 m2 g−1). Crystallite diameter size was estimated to less than 20 nm. Compared with theoretical value, approximately 2.0 mass % of free carbon was measured in the prepared WC. It was observed that layered graphitic carbon was formed around the WC particles. If the graphitic carbon is separated from the WC particles by appropriate techniques or processing conditions, these techniques using PAN as a carbon source may have possibility for processing not only WC but also nano-structural carbon materials such as graphene.</description><identifier>ISSN: 1882-0743</identifier><identifier>EISSN: 1348-6535</identifier><identifier>DOI: 10.2109/jcersj2.122.570</identifier><language>eng</language><publisher>Tokyo: The Ceramic Society of Japan</publisher><subject>Carbon ; Catalyst ; Cemented carbide ; Crystal structure ; Gasification ; Graphene ; Heat treatment ; Materials selection ; Nanostructure ; Polyacrylonitriles</subject><ispartof>Journal of the Ceramic Society of Japan, 2014/07/01, Vol.122(1427), pp.570-573</ispartof><rights>2014 The Ceramic Society of Japan</rights><rights>Copyright Japan Science and Technology Agency 2014</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,1876,4009,27902,27903,27904</link.rule.ids></links><search><creatorcontrib>ONOKI, Takamasa</creatorcontrib><creatorcontrib>SHINODA, Yutaka</creatorcontrib><creatorcontrib>AKATSU, Takashi</creatorcontrib><creatorcontrib>WAKAI, Fumihiro</creatorcontrib><title>New processing method for tungsten carbide nano-crystalline particles and nano structural carbon via polyacrylonitrile gasification</title><title>Journal of the Ceramic Society of Japan</title><addtitle>J. Ceram. Soc. Japan</addtitle><description>A simple processing route has been developed for a nano-sized crystalline tungsten mono-carbide (WC) and a novel nano-structural carbon materials. Starting materials for WC synthesis were selected tungstic acid (H2WO4) and polyacrylonitrile (PAN) powders. The starting powders were heat-treated at 1200°C for 30 min with a nitorgen gas flow in an alumina tube. The acquired WC powder had a nano-sized crystalline and high-specific surface area (26.0 m2 g−1). Crystallite diameter size was estimated to less than 20 nm. Compared with theoretical value, approximately 2.0 mass % of free carbon was measured in the prepared WC. It was observed that layered graphitic carbon was formed around the WC particles. If the graphitic carbon is separated from the WC particles by appropriate techniques or processing conditions, these techniques using PAN as a carbon source may have possibility for processing not only WC but also nano-structural carbon materials such as graphene.</description><subject>Carbon</subject><subject>Catalyst</subject><subject>Cemented carbide</subject><subject>Crystal structure</subject><subject>Gasification</subject><subject>Graphene</subject><subject>Heat treatment</subject><subject>Materials selection</subject><subject>Nanostructure</subject><subject>Polyacrylonitriles</subject><issn>1882-0743</issn><issn>1348-6535</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNpdkc1vEzEQxVcIJErhzNUSFy6b-mu93iOK-KqqcADOlmOPU68cO9heUM7845gkqtSe5knze6OZeV33luAVJXi6mQ3kMtMVoXQ1jPhZd0UYl70Y2PC8aSlpj0fOXnavSpkxFpQzedX93cAfdMjJQCk-7tAe6n2yyKWM6hJ3pUJERuett4Cijqk3-ViqDsFHQAedqzcBCtLRntqo1LyYumQdTrYU0W-v0SGFo27OkKKv2QdAO12880ZXn-Lr7oXTocCbS73ufn76-GP9pb_79vnr-sNdb4Zxqr0kbsIUG4HxNFrGnDESON5OVlontOUOBsa3XI90cBMf5ZYPkgAX2FlniWHX3fvz3HbvrwVKVXtfDISgI6SlKCJGIjAVk2jouyfonJYc23aKDJyRNp3JRt2cKZNTKRmcOmS_1_moCFb_Q1GXUFQLRbVQmmNzdsztiTt44C-PfMQTTseTuF1_v1UbwjHhD6C511lBZP8Ac1WfvQ</recordid><startdate>2014</startdate><enddate>2014</enddate><creator>ONOKI, Takamasa</creator><creator>SHINODA, Yutaka</creator><creator>AKATSU, Takashi</creator><creator>WAKAI, Fumihiro</creator><general>The Ceramic Society of Japan</general><general>Japan Science and Technology Agency</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>7QF</scope><scope>7U5</scope><scope>8BQ</scope><scope>L7M</scope></search><sort><creationdate>2014</creationdate><title>New processing method for tungsten carbide nano-crystalline particles and nano structural carbon via polyacrylonitrile gasification</title><author>ONOKI, Takamasa ; SHINODA, Yutaka ; AKATSU, Takashi ; WAKAI, Fumihiro</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c579t-81f9020c60097d33fcc8e40b9d8df6ad4fe534b4a725f9478b4581e460fdfd1c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Carbon</topic><topic>Catalyst</topic><topic>Cemented carbide</topic><topic>Crystal structure</topic><topic>Gasification</topic><topic>Graphene</topic><topic>Heat treatment</topic><topic>Materials selection</topic><topic>Nanostructure</topic><topic>Polyacrylonitriles</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>ONOKI, Takamasa</creatorcontrib><creatorcontrib>SHINODA, Yutaka</creatorcontrib><creatorcontrib>AKATSU, Takashi</creatorcontrib><creatorcontrib>WAKAI, Fumihiro</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Aluminium Industry Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of the Ceramic Society of Japan</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>ONOKI, Takamasa</au><au>SHINODA, Yutaka</au><au>AKATSU, Takashi</au><au>WAKAI, Fumihiro</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>New processing method for tungsten carbide nano-crystalline particles and nano structural carbon via polyacrylonitrile gasification</atitle><jtitle>Journal of the Ceramic Society of Japan</jtitle><addtitle>J. Ceram. Soc. Japan</addtitle><date>2014</date><risdate>2014</risdate><volume>122</volume><issue>1427</issue><spage>570</spage><epage>573</epage><pages>570-573</pages><issn>1882-0743</issn><eissn>1348-6535</eissn><abstract>A simple processing route has been developed for a nano-sized crystalline tungsten mono-carbide (WC) and a novel nano-structural carbon materials. Starting materials for WC synthesis were selected tungstic acid (H2WO4) and polyacrylonitrile (PAN) powders. The starting powders were heat-treated at 1200°C for 30 min with a nitorgen gas flow in an alumina tube. The acquired WC powder had a nano-sized crystalline and high-specific surface area (26.0 m2 g−1). Crystallite diameter size was estimated to less than 20 nm. Compared with theoretical value, approximately 2.0 mass % of free carbon was measured in the prepared WC. It was observed that layered graphitic carbon was formed around the WC particles. If the graphitic carbon is separated from the WC particles by appropriate techniques or processing conditions, these techniques using PAN as a carbon source may have possibility for processing not only WC but also nano-structural carbon materials such as graphene.</abstract><cop>Tokyo</cop><pub>The Ceramic Society of Japan</pub><doi>10.2109/jcersj2.122.570</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1882-0743 |
| ispartof | Journal of the Ceramic Society of Japan, 2014/07/01, Vol.122(1427), pp.570-573 |
| issn | 1882-0743 1348-6535 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1671602696 |
| source | J-STAGE (Japan Science & Technology Information Aggregator, Electronic) Freely Available Titles - Japanese |
| subjects | Carbon Catalyst Cemented carbide Crystal structure Gasification Graphene Heat treatment Materials selection Nanostructure Polyacrylonitriles |
| title | New processing method for tungsten carbide nano-crystalline particles and nano structural carbon via polyacrylonitrile gasification |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-23T03%3A49%3A14IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=New%20processing%20method%20for%20tungsten%20carbide%20nano-crystalline%20particles%20and%20nano%20structural%20carbon%20via%20polyacrylonitrile%20gasification&rft.jtitle=Journal%20of%20the%20Ceramic%20Society%20of%20Japan&rft.au=ONOKI,%20Takamasa&rft.date=2014&rft.volume=122&rft.issue=1427&rft.spage=570&rft.epage=573&rft.pages=570-573&rft.issn=1882-0743&rft.eissn=1348-6535&rft_id=info:doi/10.2109/jcersj2.122.570&rft_dat=%3Cproquest_cross%3E1671602696%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1543147838&rft_id=info:pmid/&rfr_iscdi=true |