Durability of nickel-metal hydride (Ni-MH) battery cathode using nickel-aluminum layered double hydroxide/carbon (Ni-Al LDH/C) composite
We report the durability of the optimized nickel-aluminum layered double hydroxide/carbon (Ni-Al LDH/C) composite prepared by liquid phase deposition (LPD) as cathode active materials in nickel metal hydride (Ni-MH) secondary battery. The positive electrode was used for charge-discharge measurements...
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| Veröffentlicht in: | Journal of power sources 2014-02, Vol.247, p.572-578 |
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| container_title | Journal of power sources |
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| creator | ALEXIS BIENVENU BELEKE HIGUCHI, Eiji INOUE, Hiroshi MIZUHATA, Minoru |
| description | We report the durability of the optimized nickel-aluminum layered double hydroxide/carbon (Ni-Al LDH/C) composite prepared by liquid phase deposition (LPD) as cathode active materials in nickel metal hydride (Ni-MH) secondary battery. The positive electrode was used for charge-discharge measurements under two different current: 5 mA for 300 cycles in half-cell conditions, and 5.8 mA for 569 cycles in battery regime, respectively. The optimized Ni-Al LDH/C composite exhibits a good lifespan and stability with the capacity retention above 380 mA h gcomp-1 over 869 cycles. Cyclic voltammetry shows that the alpha -Ni(OH)2/ gamma -NiOOH redox reaction is maintained even after 869 cycles, and the higher current regime is beneficial in terms of materials utilization. X-ray diffraction (XRD) patterns of the cathode after charge and discharge confirms that the alpha -Ni(OH)2/ gamma -NiOOH redox reaction occurs without any intermediate phase. |
| doi_str_mv | 10.1016/j.jpowsour.2013.08.001 |
| format | Article |
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The positive electrode was used for charge-discharge measurements under two different current: 5 mA for 300 cycles in half-cell conditions, and 5.8 mA for 569 cycles in battery regime, respectively. The optimized Ni-Al LDH/C composite exhibits a good lifespan and stability with the capacity retention above 380 mA h gcomp-1 over 869 cycles. Cyclic voltammetry shows that the alpha -Ni(OH)2/ gamma -NiOOH redox reaction is maintained even after 869 cycles, and the higher current regime is beneficial in terms of materials utilization. X-ray diffraction (XRD) patterns of the cathode after charge and discharge confirms that the alpha -Ni(OH)2/ gamma -NiOOH redox reaction occurs without any intermediate phase.</description><identifier>ISSN: 0378-7753</identifier><identifier>EISSN: 1873-2755</identifier><identifier>DOI: 10.1016/j.jpowsour.2013.08.001</identifier><identifier>CODEN: JPSODZ</identifier><language>eng</language><publisher>Amsterdam: Elsevier</publisher><subject>Applied sciences ; Battery ; Carbon ; Cathodes ; Direct energy conversion and energy accumulation ; Durability ; Electrical engineering. 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The positive electrode was used for charge-discharge measurements under two different current: 5 mA for 300 cycles in half-cell conditions, and 5.8 mA for 569 cycles in battery regime, respectively. The optimized Ni-Al LDH/C composite exhibits a good lifespan and stability with the capacity retention above 380 mA h gcomp-1 over 869 cycles. Cyclic voltammetry shows that the alpha -Ni(OH)2/ gamma -NiOOH redox reaction is maintained even after 869 cycles, and the higher current regime is beneficial in terms of materials utilization. X-ray diffraction (XRD) patterns of the cathode after charge and discharge confirms that the alpha -Ni(OH)2/ gamma -NiOOH redox reaction occurs without any intermediate phase.</description><subject>Applied sciences</subject><subject>Battery</subject><subject>Carbon</subject><subject>Cathodes</subject><subject>Direct energy conversion and energy accumulation</subject><subject>Durability</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Electrical power engineering</subject><subject>Electrochemical conversion: primary and secondary batteries, fuel cells</subject><subject>Electrodes</subject><subject>Exact sciences and technology</subject><subject>Hydroxides</subject><subject>Materials</subject><subject>Nickel</subject><subject>Redox reactions</subject><issn>0378-7753</issn><issn>1873-2755</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqFkc1u1DAUhS0EEkPhFZA3SO0iGTu2Y3tZTYGpNMCme8uxb6gHJx7sRCVvwGOT_m5ZXenoO99dHIQ-UlJTQtvtsT6e0l1Jc64bQllNVE0IfYU2VElWNVKI12hDmFSVlIK9Re9KOZKVoJJs0N-rOdsuxDAtOPV4DO4XxGqAyUZ8u_gcPODz76H6tr_AnZ0myAt2drpNaz6XMP58rtg4D2GcBxztAhk89mnuIjxI0p9Vs3U2d2l8sF1GfLjab3cX2KXhlEqY4D1609tY4MPTPUM3Xz7f7PbV4cfX693loXJc8KkSxDLuJeuVA67B8V5KZSnzRFsl15x4RRkjpAffC98o0Lx1qvFSd1oLdobOH7WnnH7PUCYzhOIgRjtCmouhraRCc83o_1HRcKZ1K9sVbR9Rl1MpGXpzymGweTGUmPuRzNE8j2TuRzJEmXWCtfjp6YctzsY-29GF8tJuVMOF0Jr9AyVplds</recordid><startdate>20140201</startdate><enddate>20140201</enddate><creator>ALEXIS BIENVENU BELEKE</creator><creator>HIGUCHI, Eiji</creator><creator>INOUE, Hiroshi</creator><creator>MIZUHATA, Minoru</creator><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>C1K</scope><scope>SOI</scope><scope>7QF</scope><scope>7SP</scope><scope>7SR</scope><scope>7SU</scope><scope>7TB</scope><scope>8FD</scope><scope>FR3</scope><scope>JG9</scope><scope>KR7</scope><scope>L7M</scope></search><sort><creationdate>20140201</creationdate><title>Durability of nickel-metal hydride (Ni-MH) battery cathode using nickel-aluminum layered double hydroxide/carbon (Ni-Al LDH/C) composite</title><author>ALEXIS BIENVENU BELEKE ; HIGUCHI, Eiji ; INOUE, Hiroshi ; MIZUHATA, Minoru</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c454t-50a34d73f8ce49ec4f778a13d09a8773f0d813300fedf5d28e946c82d79b9953</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Applied sciences</topic><topic>Battery</topic><topic>Carbon</topic><topic>Cathodes</topic><topic>Direct energy conversion and energy accumulation</topic><topic>Durability</topic><topic>Electrical engineering. 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| fulltext | fulltext |
| identifier | ISSN: 0378-7753 |
| ispartof | Journal of power sources, 2014-02, Vol.247, p.572-578 |
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| language | eng |
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| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Applied sciences Battery Carbon Cathodes Direct energy conversion and energy accumulation Durability Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Electrodes Exact sciences and technology Hydroxides Materials Nickel Redox reactions |
| title | Durability of nickel-metal hydride (Ni-MH) battery cathode using nickel-aluminum layered double hydroxide/carbon (Ni-Al LDH/C) composite |
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