K shell X-ray fluorescence parameters of Co, Ni, Cu and Zn in phthalocyanine complexes
The influence of the chemical effects on σKα,β production cross-sections and Kβ/Kα intensity ratios of Co, Ni, Cu and Zn elements in the phthalocyanine complexes was investigated. The samples were excited by 59.5keV γ-rays from an 241Am annular radioactive source. K X-rays emitted by the samples wer...
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| Veröffentlicht in: | Radiation physics and chemistry (Oxford, England : 1993) England : 1993), 2014-08, Vol.101, p.30-35 |
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| container_title | Radiation physics and chemistry (Oxford, England : 1993) |
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| creator | Doğan, M. Cengiz, E. Dilber, G. Nas, A. Tıraşoğlu, E. Kantekin, H. |
| description | The influence of the chemical effects on σKα,β production cross-sections and Kβ/Kα intensity ratios of Co, Ni, Cu and Zn elements in the phthalocyanine complexes was investigated. The samples were excited by 59.5keV γ-rays from an 241Am annular radioactive source. K X-rays emitted by the samples were counted by an Ultra-LEGe detector with a resolution of 150eV at 5.9keV. We observed the effects of different ligands on the σKβ production cross-sections and the Kβ/Kα intensity ratios. These effects were interpreted according to the charge transfer process from the central atoms to the ligands.
•This work considers the K X-ray fluorescence parameters of phthalocyanine complexes.•These parameters were obtained using EDXRF methods.•The results are in good agreement with theoretical and experimental values. |
| doi_str_mv | 10.1016/j.radphyschem.2014.03.024 |
| format | Article |
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•This work considers the K X-ray fluorescence parameters of phthalocyanine complexes.•These parameters were obtained using EDXRF methods.•The results are in good agreement with theoretical and experimental values.</description><identifier>ISSN: 0969-806X</identifier><identifier>EISSN: 1879-0895</identifier><identifier>DOI: 10.1016/j.radphyschem.2014.03.024</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>Charge transfer ; Chemical effect ; Copper ; Cross sections ; Intensity ratios ; Ligands ; Nickel ; Shells ; Ultra-LEGe detector ; X-ray fluorescence ; X-rays ; Zinc</subject><ispartof>Radiation physics and chemistry (Oxford, England : 1993), 2014-08, Vol.101, p.30-35</ispartof><rights>2014 Elsevier Ltd</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c354t-617870dd69fbb5eb63ee96f40505c144ed4991e817ffaae90156064b3df468ea3</citedby><cites>FETCH-LOGICAL-c354t-617870dd69fbb5eb63ee96f40505c144ed4991e817ffaae90156064b3df468ea3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0969806X1400098X$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65534</link.rule.ids></links><search><creatorcontrib>Doğan, M.</creatorcontrib><creatorcontrib>Cengiz, E.</creatorcontrib><creatorcontrib>Dilber, G.</creatorcontrib><creatorcontrib>Nas, A.</creatorcontrib><creatorcontrib>Tıraşoğlu, E.</creatorcontrib><creatorcontrib>Kantekin, H.</creatorcontrib><title>K shell X-ray fluorescence parameters of Co, Ni, Cu and Zn in phthalocyanine complexes</title><title>Radiation physics and chemistry (Oxford, England : 1993)</title><description>The influence of the chemical effects on σKα,β production cross-sections and Kβ/Kα intensity ratios of Co, Ni, Cu and Zn elements in the phthalocyanine complexes was investigated. The samples were excited by 59.5keV γ-rays from an 241Am annular radioactive source. K X-rays emitted by the samples were counted by an Ultra-LEGe detector with a resolution of 150eV at 5.9keV. We observed the effects of different ligands on the σKβ production cross-sections and the Kβ/Kα intensity ratios. These effects were interpreted according to the charge transfer process from the central atoms to the ligands.
•This work considers the K X-ray fluorescence parameters of phthalocyanine complexes.•These parameters were obtained using EDXRF methods.•The results are in good agreement with theoretical and experimental values.</description><subject>Charge transfer</subject><subject>Chemical effect</subject><subject>Copper</subject><subject>Cross sections</subject><subject>Intensity ratios</subject><subject>Ligands</subject><subject>Nickel</subject><subject>Shells</subject><subject>Ultra-LEGe detector</subject><subject>X-ray fluorescence</subject><subject>X-rays</subject><subject>Zinc</subject><issn>0969-806X</issn><issn>1879-0895</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqNkEFP3DAUhK0KpC5L_4N764GE543txMcqKm3FCi6AEBfL6zwrXiVxamcR-ffNajlw5DSXmdHMR8h3BjkDJq_3eTTN2M7JttjnG2A8hyKHDf9CVqwqVQaVEmdkBUqqrAL5_JVcpLQHgLISxYo83dLUYtfR5yyambruECImi4NFOppoepwwJhocrcMVvfNXtD5QMzT0ZaB-oGM7taYLdjaDH5Da0I8dvmG6JOfOdAm_veuaPN78eqj_ZNv733_rn9vMFoJPmWRlVULTSOV2O4E7WSAq6TgIEJZxjg1XimHFSueMQQVMSJB8VzSOywpNsSY_Tr1jDP8OmCbd-2V915kBwyFpJksm1EaBWKzqZLUxpBTR6TH63sRZM9BHlnqvP7DUR5YaCr2wXLL1KYvLl1ePUSfrj4waH9FOugn-Ey3_AYHUgzA</recordid><startdate>20140801</startdate><enddate>20140801</enddate><creator>Doğan, M.</creator><creator>Cengiz, E.</creator><creator>Dilber, G.</creator><creator>Nas, A.</creator><creator>Tıraşoğlu, E.</creator><creator>Kantekin, H.</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20140801</creationdate><title>K shell X-ray fluorescence parameters of Co, Ni, Cu and Zn in phthalocyanine complexes</title><author>Doğan, M. ; Cengiz, E. ; Dilber, G. ; Nas, A. ; Tıraşoğlu, E. ; Kantekin, H.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c354t-617870dd69fbb5eb63ee96f40505c144ed4991e817ffaae90156064b3df468ea3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Charge transfer</topic><topic>Chemical effect</topic><topic>Copper</topic><topic>Cross sections</topic><topic>Intensity ratios</topic><topic>Ligands</topic><topic>Nickel</topic><topic>Shells</topic><topic>Ultra-LEGe detector</topic><topic>X-ray fluorescence</topic><topic>X-rays</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Doğan, M.</creatorcontrib><creatorcontrib>Cengiz, E.</creatorcontrib><creatorcontrib>Dilber, G.</creatorcontrib><creatorcontrib>Nas, A.</creatorcontrib><creatorcontrib>Tıraşoğlu, E.</creatorcontrib><creatorcontrib>Kantekin, H.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Radiation physics and chemistry (Oxford, England : 1993)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Doğan, M.</au><au>Cengiz, E.</au><au>Dilber, G.</au><au>Nas, A.</au><au>Tıraşoğlu, E.</au><au>Kantekin, H.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>K shell X-ray fluorescence parameters of Co, Ni, Cu and Zn in phthalocyanine complexes</atitle><jtitle>Radiation physics and chemistry (Oxford, England : 1993)</jtitle><date>2014-08-01</date><risdate>2014</risdate><volume>101</volume><spage>30</spage><epage>35</epage><pages>30-35</pages><issn>0969-806X</issn><eissn>1879-0895</eissn><abstract>The influence of the chemical effects on σKα,β production cross-sections and Kβ/Kα intensity ratios of Co, Ni, Cu and Zn elements in the phthalocyanine complexes was investigated. The samples were excited by 59.5keV γ-rays from an 241Am annular radioactive source. K X-rays emitted by the samples were counted by an Ultra-LEGe detector with a resolution of 150eV at 5.9keV. We observed the effects of different ligands on the σKβ production cross-sections and the Kβ/Kα intensity ratios. These effects were interpreted according to the charge transfer process from the central atoms to the ligands.
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| subjects | Charge transfer Chemical effect Copper Cross sections Intensity ratios Ligands Nickel Shells Ultra-LEGe detector X-ray fluorescence X-rays Zinc |
| title | K shell X-ray fluorescence parameters of Co, Ni, Cu and Zn in phthalocyanine complexes |
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