Comparative study on two-step concentrated acid hydrolysis for the extraction of sugars from lignocellulosic biomass
•Two-step concentrated acid hydrolysis has been conducted with oak, pine, and EFB.•Oak, pine, and EFB have been characterized in the compositional and XRD analysis.•Crystalline structure change in raw biomass has been clearly shown in XRD analysis.•Optimum condition was selected on the highest sugar...
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| Veröffentlicht in: | Bioresource technology 2014-07, Vol.164, p.221-231 |
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| creator | Wijaya, Yanuar Philip Putra, Robertus Dhimas Dhewangga Widyaya, Vania Tanda Ha, Jeong-Myeong Suh, Dong Jin Kim, Chang Soo |
| description | •Two-step concentrated acid hydrolysis has been conducted with oak, pine, and EFB.•Oak, pine, and EFB have been characterized in the compositional and XRD analysis.•Crystalline structure change in raw biomass has been clearly shown in XRD analysis.•Optimum condition was selected on the highest sugar recovery in the shortest time.•Pine has the highest recalcitrance based on the CrI and sugar recovery correlation.
Among all the feasible thermochemical conversion processes, concentrated acid hydrolysis has been applied to break the crystalline structure of cellulose efficiently and scale up for mass production as lignocellulosic biomass fractionation process. Process conditions are optimized by investigating the effect of decrystallization sulfuric acid concentration (65–80wt%), hydrolysis temperature (80°C and 100°C), hydrolysis reaction time (during two hours), and biomass species (oak wood, pine wood, and empty fruit bunch (EFB) of palm oil) toward sugar recovery. At the optimum process condition, 78–96% sugars out of theoretically extractable sugars have been fractionated by concentrated sulfuric acid hydrolysis of the three different biomass species with 87–90g/L sugar concentration in the hydrolyzate and highest recalcitrance of pine (softwood) was determined by the correlation of crystallinity index and sugar yield considering reaction severity. |
| doi_str_mv | 10.1016/j.biortech.2014.04.084 |
| format | Article |
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Among all the feasible thermochemical conversion processes, concentrated acid hydrolysis has been applied to break the crystalline structure of cellulose efficiently and scale up for mass production as lignocellulosic biomass fractionation process. Process conditions are optimized by investigating the effect of decrystallization sulfuric acid concentration (65–80wt%), hydrolysis temperature (80°C and 100°C), hydrolysis reaction time (during two hours), and biomass species (oak wood, pine wood, and empty fruit bunch (EFB) of palm oil) toward sugar recovery. At the optimum process condition, 78–96% sugars out of theoretically extractable sugars have been fractionated by concentrated sulfuric acid hydrolysis of the three different biomass species with 87–90g/L sugar concentration in the hydrolyzate and highest recalcitrance of pine (softwood) was determined by the correlation of crystallinity index and sugar yield considering reaction severity.</description><identifier>ISSN: 0960-8524</identifier><identifier>EISSN: 1873-2976</identifier><identifier>DOI: 10.1016/j.biortech.2014.04.084</identifier><identifier>PMID: 24859214</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Biological and medical sciences ; Biomass ; Biotechnology - methods ; Carbohydrates - isolation & purification ; Cellulose - chemistry ; Concentrated acid hydrolysis ; Crystallinity ; Crystallization ; EFB ; Fruit - chemistry ; Fundamental and applied biological sciences. Psychology ; Glucose - analysis ; Hydrolysis ; Hydrolysis - drug effects ; Lignin - chemistry ; Lignocellulose ; Mass production ; Oak wood ; Palm Oil ; Pine ; Pine wood ; Pinus - chemistry ; Plant Oils - chemistry ; Quercus - chemistry ; Sugars ; Sulfuric acid ; Sulfuric Acids - pharmacology ; Temperature ; Time Factors ; Wood ; Xylose - analysis</subject><ispartof>Bioresource technology, 2014-07, Vol.164, p.221-231</ispartof><rights>2014 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><rights>Copyright © 2014 Elsevier Ltd. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c530t-522c88f8dd82cde8af27cedb1cb064629dec67a5202af00451bdccb9ba929da33</citedby><cites>FETCH-LOGICAL-c530t-522c88f8dd82cde8af27cedb1cb064629dec67a5202af00451bdccb9ba929da33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.biortech.2014.04.084$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>315,781,785,3551,27929,27930,46000</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28528359$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/24859214$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Wijaya, Yanuar Philip</creatorcontrib><creatorcontrib>Putra, Robertus Dhimas Dhewangga</creatorcontrib><creatorcontrib>Widyaya, Vania Tanda</creatorcontrib><creatorcontrib>Ha, Jeong-Myeong</creatorcontrib><creatorcontrib>Suh, Dong Jin</creatorcontrib><creatorcontrib>Kim, Chang Soo</creatorcontrib><title>Comparative study on two-step concentrated acid hydrolysis for the extraction of sugars from lignocellulosic biomass</title><title>Bioresource technology</title><addtitle>Bioresour Technol</addtitle><description>•Two-step concentrated acid hydrolysis has been conducted with oak, pine, and EFB.•Oak, pine, and EFB have been characterized in the compositional and XRD analysis.•Crystalline structure change in raw biomass has been clearly shown in XRD analysis.•Optimum condition was selected on the highest sugar recovery in the shortest time.•Pine has the highest recalcitrance based on the CrI and sugar recovery correlation.
Among all the feasible thermochemical conversion processes, concentrated acid hydrolysis has been applied to break the crystalline structure of cellulose efficiently and scale up for mass production as lignocellulosic biomass fractionation process. Process conditions are optimized by investigating the effect of decrystallization sulfuric acid concentration (65–80wt%), hydrolysis temperature (80°C and 100°C), hydrolysis reaction time (during two hours), and biomass species (oak wood, pine wood, and empty fruit bunch (EFB) of palm oil) toward sugar recovery. At the optimum process condition, 78–96% sugars out of theoretically extractable sugars have been fractionated by concentrated sulfuric acid hydrolysis of the three different biomass species with 87–90g/L sugar concentration in the hydrolyzate and highest recalcitrance of pine (softwood) was determined by the correlation of crystallinity index and sugar yield considering reaction severity.</description><subject>Biological and medical sciences</subject><subject>Biomass</subject><subject>Biotechnology - methods</subject><subject>Carbohydrates - isolation & purification</subject><subject>Cellulose - chemistry</subject><subject>Concentrated acid hydrolysis</subject><subject>Crystallinity</subject><subject>Crystallization</subject><subject>EFB</subject><subject>Fruit - chemistry</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>Glucose - analysis</subject><subject>Hydrolysis</subject><subject>Hydrolysis - drug effects</subject><subject>Lignin - chemistry</subject><subject>Lignocellulose</subject><subject>Mass production</subject><subject>Oak wood</subject><subject>Palm Oil</subject><subject>Pine</subject><subject>Pine wood</subject><subject>Pinus - chemistry</subject><subject>Plant Oils - chemistry</subject><subject>Quercus - chemistry</subject><subject>Sugars</subject><subject>Sulfuric acid</subject><subject>Sulfuric Acids - pharmacology</subject><subject>Temperature</subject><subject>Time Factors</subject><subject>Wood</subject><subject>Xylose - analysis</subject><issn>0960-8524</issn><issn>1873-2976</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqNkc1u3CAURlHVqpkmfYWITaVuPAUMNt61GqU_UqRumjXCl-sMI9tMAaeZtw-jmbTLVLoSi3s--MQh5JqzNWe8-bRb9z7EjLBdC8blmpXR8hVZcd3Wleja5jVZsa5hlVZCXpB3Ke0YYzVvxVtyIaRWneByRfImTHsbbfYPSFNe3IGGmeY_oUoZ9xTCDDjnskdHLXhHtwcXw3hIPtEhRJq3SPGxAJB9CYaBpuXexrKMYaKjv58D4DguY0geaOk82ZSuyJvBjgnfn89Lcvf15tfme3X789uPzZfbClTNcqWEAK0H7ZwW4FDbQbSArufQs0Y2onMITWuVYMIOjEnFewfQd73tys7W9SX5eLp3H8PvBVM2k0_HOnbGsCTDm5YrrSXnL6NKSsa55O1_oLVsOym0KmhzQiGGlCIOZh_9ZOPBcGaOHs3OPHs0R4-GldGyBK_Pbyz9hO5v7FlcAT6cAZvAjkO0M_j0jyvWda26wn0-cVj--cFjNAk8FqnOR4RsXPAvdXkC09nBwA</recordid><startdate>20140701</startdate><enddate>20140701</enddate><creator>Wijaya, Yanuar Philip</creator><creator>Putra, Robertus Dhimas Dhewangga</creator><creator>Widyaya, Vania Tanda</creator><creator>Ha, Jeong-Myeong</creator><creator>Suh, Dong Jin</creator><creator>Kim, Chang Soo</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SU</scope><scope>7TB</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>KR7</scope></search><sort><creationdate>20140701</creationdate><title>Comparative study on two-step concentrated acid hydrolysis for the extraction of sugars from lignocellulosic biomass</title><author>Wijaya, Yanuar Philip ; Putra, Robertus Dhimas Dhewangga ; Widyaya, Vania Tanda ; Ha, Jeong-Myeong ; Suh, Dong Jin ; Kim, Chang Soo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c530t-522c88f8dd82cde8af27cedb1cb064629dec67a5202af00451bdccb9ba929da33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Biological and medical sciences</topic><topic>Biomass</topic><topic>Biotechnology - methods</topic><topic>Carbohydrates - isolation & purification</topic><topic>Cellulose - chemistry</topic><topic>Concentrated acid hydrolysis</topic><topic>Crystallinity</topic><topic>Crystallization</topic><topic>EFB</topic><topic>Fruit - chemistry</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>Glucose - analysis</topic><topic>Hydrolysis</topic><topic>Hydrolysis - drug effects</topic><topic>Lignin - chemistry</topic><topic>Lignocellulose</topic><topic>Mass production</topic><topic>Oak wood</topic><topic>Palm Oil</topic><topic>Pine</topic><topic>Pine wood</topic><topic>Pinus - chemistry</topic><topic>Plant Oils - chemistry</topic><topic>Quercus - chemistry</topic><topic>Sugars</topic><topic>Sulfuric acid</topic><topic>Sulfuric Acids - pharmacology</topic><topic>Temperature</topic><topic>Time Factors</topic><topic>Wood</topic><topic>Xylose - analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wijaya, Yanuar Philip</creatorcontrib><creatorcontrib>Putra, Robertus Dhimas Dhewangga</creatorcontrib><creatorcontrib>Widyaya, Vania Tanda</creatorcontrib><creatorcontrib>Ha, Jeong-Myeong</creatorcontrib><creatorcontrib>Suh, Dong Jin</creatorcontrib><creatorcontrib>Kim, Chang Soo</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Environmental Engineering Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><jtitle>Bioresource technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wijaya, Yanuar Philip</au><au>Putra, Robertus Dhimas Dhewangga</au><au>Widyaya, Vania Tanda</au><au>Ha, Jeong-Myeong</au><au>Suh, Dong Jin</au><au>Kim, Chang Soo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Comparative study on two-step concentrated acid hydrolysis for the extraction of sugars from lignocellulosic biomass</atitle><jtitle>Bioresource technology</jtitle><addtitle>Bioresour Technol</addtitle><date>2014-07-01</date><risdate>2014</risdate><volume>164</volume><spage>221</spage><epage>231</epage><pages>221-231</pages><issn>0960-8524</issn><eissn>1873-2976</eissn><abstract>•Two-step concentrated acid hydrolysis has been conducted with oak, pine, and EFB.•Oak, pine, and EFB have been characterized in the compositional and XRD analysis.•Crystalline structure change in raw biomass has been clearly shown in XRD analysis.•Optimum condition was selected on the highest sugar recovery in the shortest time.•Pine has the highest recalcitrance based on the CrI and sugar recovery correlation.
Among all the feasible thermochemical conversion processes, concentrated acid hydrolysis has been applied to break the crystalline structure of cellulose efficiently and scale up for mass production as lignocellulosic biomass fractionation process. Process conditions are optimized by investigating the effect of decrystallization sulfuric acid concentration (65–80wt%), hydrolysis temperature (80°C and 100°C), hydrolysis reaction time (during two hours), and biomass species (oak wood, pine wood, and empty fruit bunch (EFB) of palm oil) toward sugar recovery. At the optimum process condition, 78–96% sugars out of theoretically extractable sugars have been fractionated by concentrated sulfuric acid hydrolysis of the three different biomass species with 87–90g/L sugar concentration in the hydrolyzate and highest recalcitrance of pine (softwood) was determined by the correlation of crystallinity index and sugar yield considering reaction severity.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><pmid>24859214</pmid><doi>10.1016/j.biortech.2014.04.084</doi><tpages>11</tpages></addata></record> |
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| identifier | ISSN: 0960-8524 |
| ispartof | Bioresource technology, 2014-07, Vol.164, p.221-231 |
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| language | eng |
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| source | MEDLINE; ScienceDirect Journals (5 years ago - present) |
| subjects | Biological and medical sciences Biomass Biotechnology - methods Carbohydrates - isolation & purification Cellulose - chemistry Concentrated acid hydrolysis Crystallinity Crystallization EFB Fruit - chemistry Fundamental and applied biological sciences. Psychology Glucose - analysis Hydrolysis Hydrolysis - drug effects Lignin - chemistry Lignocellulose Mass production Oak wood Palm Oil Pine Pine wood Pinus - chemistry Plant Oils - chemistry Quercus - chemistry Sugars Sulfuric acid Sulfuric Acids - pharmacology Temperature Time Factors Wood Xylose - analysis |
| title | Comparative study on two-step concentrated acid hydrolysis for the extraction of sugars from lignocellulosic biomass |
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