The Effect of Polymer Chain Alignment and Relaxation on Force-Induced Chemical Reactions in an Elastomer

Simultaneous measurements of mechanical response, optical birefringence, and fluorescence signal are acquired in situ during tensile testing of a mechanophore‐linked elastomeric polymer. Mechanical stress, deformation, and polymer chain alignment are correlated with force‐induced chemical reaction o...

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Veröffentlicht in:	Advanced functional materials 2014-03, Vol.24 (11), p.1529-1537
Hauptverfasser:	Beiermann, Brett A., Kramer, Sharlotte L. B., May, Preston A., Moore, Jeffrey S., White, Scott R., Sottos, Nancy R.
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation Alignment Birefringence Chain reactions Chains (polymeric) Conversion Fluorescence mechanochemistry photoelasticity spiropyran Stresses
Online-Zugang:	Volltext
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