Dehydrogenation of N2HX (X=2-4) by nitrogen atoms: thermochemical and kinetics

Thermochemical and kinetics of sequential hydrogen abstraction reactions from hydrazine by nitrogen atoms were studied. The dehydrogenation was divided in three steps, N2H4 + N, N2H3 + N, and N2H2 + N. The thermal rate constants were calculated within the framework of canonical variational theory, w...

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Veröffentlicht in:	The Journal of chemical physics 2013-11, Vol.139 (19), p.194301-194301
Hauptverfasser:	Spada, Rene Felipe Keidel, Ferrão, Luiz Fernando de Araujo, Roberto-Neto, Orlando, Machado, Francisco Bolivar Correto
Format:	Artikel
Sprache:	eng
Schlagworte:	Curvature Dehydrogenation Hydrazines Hydrogen storage Mathematical analysis Nitrogen atoms Physics Rate constants Reaction kinetics Thermochemical properties Tunnelling
Online-Zugang:	Volltext
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