Cationic polymerization of isobutylene at room temperature

This review highlights recent approaches toward polyisobutylene (PIB) by an energy efficient room temperature cationic polymerization. Special focus is laid on our own work using modified Lewis acids and nitrile‐ligated metal complexes associated with weakly coordinating anions. In both cases, suita...

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Veröffentlicht in:	Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2013-02, Vol.51 (3), p.471-486
Hauptverfasser:	Kostjuk, Sergei V., Yeong, Hui Yee, Voit, Brigitte
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions Applied sciences catalysis Catalysts Cationic Cationic polymerization Chain transfer Exact sciences and technology Lewis acid Organic polymers Physicochemistry of polymers polyisobutylene Polyisobutylenes Polymerization polyolefins Preparation, kinetics, thermodynamics, mechanism and catalysts Reproduction room temperature weakly coordinating anions
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