Synthesis of graphene/methylene blue/gold nanoparticles composites based on simultaneous green reduction, in situ growth and self-catalysis
The novel composites based on reduced graphene oxide/methylene blue/gold nanoparticles (rGO/MB/AuNPs) were synthesized by a green and easy method. This synthesis was realized through a one-step green reduction of graphene oxide and chloroauric acid by ascorbic acid, with MB as the assistant reductan...
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Veröffentlicht in: | Journal of materials science 2014-07, Vol.49 (14), p.4796-4806 |
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creator | Han, Haitao Pan, Dawei Wu, Xuran Zhang, Qing Zhang, Haiyun |
description | The novel composites based on reduced graphene oxide/methylene blue/gold nanoparticles (rGO/MB/AuNPs) were synthesized by a green and easy method. This synthesis was realized through a one-step green reduction of graphene oxide and chloroauric acid by ascorbic acid, with MB as the assistant reductant and formed AuNPs as the self-catalyst. Except for electroactive substance, MB, which was firmly coated onto the surface of rGO through π–π stacking non-covalent interactions, also serves as the anchor for AuNPs in situ growth due to the electrostatic attraction between positively charged MB and negatively charged chloroauric ions. The characteristics of rGO/MB/AuNPs composites were investigated by various optical and electrical methods. These composites exhibit excellent electrochemical properties and promising prospects for practical application in electrochemical analysis. |
doi_str_mv | 10.1007/s10853-014-8179-2 |
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This synthesis was realized through a one-step green reduction of graphene oxide and chloroauric acid by ascorbic acid, with MB as the assistant reductant and formed AuNPs as the self-catalyst. Except for electroactive substance, MB, which was firmly coated onto the surface of rGO through π–π stacking non-covalent interactions, also serves as the anchor for AuNPs in situ growth due to the electrostatic attraction between positively charged MB and negatively charged chloroauric ions. The characteristics of rGO/MB/AuNPs composites were investigated by various optical and electrical methods. These composites exhibit excellent electrochemical properties and promising prospects for practical application in electrochemical analysis.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-014-8179-2</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Anchors ; Ascorbic acid ; Catalysis ; Characterization and Evaluation of Materials ; Charging ; Chemistry and Materials Science ; Chloroauric acid ; Classical Mechanics ; Composite materials industry ; Crystallography and Scattering Methods ; Electric properties ; Electrochemical analysis ; Gold ; Graphene ; Growth ; Materials Science ; Methylene blue ; Nanoparticles ; Optical properties ; Oxides ; Particulate composites ; Polymer Sciences ; Reduction ; Solid Mechanics ; Synthesis</subject><ispartof>Journal of materials science, 2014-07, Vol.49 (14), p.4796-4806</ispartof><rights>Springer Science+Business Media New York 2014</rights><rights>COPYRIGHT 2014 Springer</rights><rights>Journal of Materials Science is a copyright of Springer, (2014). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c459t-b35dee37ca7a8725f604ae46edd3b381ef987c16060dd8a0edcec2fc368ec2d63</citedby><cites>FETCH-LOGICAL-c459t-b35dee37ca7a8725f604ae46edd3b381ef987c16060dd8a0edcec2fc368ec2d63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10853-014-8179-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10853-014-8179-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Han, Haitao</creatorcontrib><creatorcontrib>Pan, Dawei</creatorcontrib><creatorcontrib>Wu, Xuran</creatorcontrib><creatorcontrib>Zhang, Qing</creatorcontrib><creatorcontrib>Zhang, Haiyun</creatorcontrib><title>Synthesis of graphene/methylene blue/gold nanoparticles composites based on simultaneous green reduction, in situ growth and self-catalysis</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>The novel composites based on reduced graphene oxide/methylene blue/gold nanoparticles (rGO/MB/AuNPs) were synthesized by a green and easy method. This synthesis was realized through a one-step green reduction of graphene oxide and chloroauric acid by ascorbic acid, with MB as the assistant reductant and formed AuNPs as the self-catalyst. Except for electroactive substance, MB, which was firmly coated onto the surface of rGO through π–π stacking non-covalent interactions, also serves as the anchor for AuNPs in situ growth due to the electrostatic attraction between positively charged MB and negatively charged chloroauric ions. The characteristics of rGO/MB/AuNPs composites were investigated by various optical and electrical methods. These composites exhibit excellent electrochemical properties and promising prospects for practical application in electrochemical analysis.</description><subject>Anchors</subject><subject>Ascorbic acid</subject><subject>Catalysis</subject><subject>Characterization and Evaluation of Materials</subject><subject>Charging</subject><subject>Chemistry and Materials Science</subject><subject>Chloroauric acid</subject><subject>Classical Mechanics</subject><subject>Composite materials industry</subject><subject>Crystallography and Scattering Methods</subject><subject>Electric properties</subject><subject>Electrochemical analysis</subject><subject>Gold</subject><subject>Graphene</subject><subject>Growth</subject><subject>Materials Science</subject><subject>Methylene blue</subject><subject>Nanoparticles</subject><subject>Optical properties</subject><subject>Oxides</subject><subject>Particulate composites</subject><subject>Polymer Sciences</subject><subject>Reduction</subject><subject>Solid Mechanics</subject><subject>Synthesis</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kV2L1TAQhosoeFz9Ad4FvFGwe_LRNu3lsvixsCC4eh1ykmlPljSpmZT1_Ab_tDlUkBVkCDNknnd44a2q14xeMkrlHhntW1FT1tQ9k0PNn1Q71kpRNz0VT6sdpZzXvOnY8-oF4j2ltJWc7apfd6eQj4AOSRzJlPRyhAD7GfLx5MtEDn6F_RS9JUGHuOiUnfGAxMR5iehyGQ8awZIYCLp59VkHiCuWWwCBJLCryS6G98SdgbyWRXzIR6KDJQh-rI3O2p-Kg5fVs1F7hFd_-kX1_eOHb9ef69svn26ur25r07RDrg-itQBCGi11L3k7drTR0HRgrTiInsE49NKwjnbU2l5TsAYMH43o-tJtJy6qt9vdJcUfK2BWs0MD3m_OFeska5uhEbSgb_5B7-OaQnGnOG8H2bDyCnW5UZP2oFwYY07alLIwOxMDjK78XwnJeM-7oS2Cd48EhcnwM096RVQ3d18fs2xjTYqICUa1JDfrdFKMqnP2astelezVOXvFi4ZvGixsmCD9tf1_0W-jFbQk</recordid><startdate>20140701</startdate><enddate>20140701</enddate><creator>Han, Haitao</creator><creator>Pan, Dawei</creator><creator>Wu, Xuran</creator><creator>Zhang, Qing</creator><creator>Zhang, Haiyun</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20140701</creationdate><title>Synthesis of graphene/methylene blue/gold nanoparticles composites based on simultaneous green reduction, in situ growth and self-catalysis</title><author>Han, Haitao ; Pan, Dawei ; Wu, Xuran ; Zhang, Qing ; Zhang, Haiyun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c459t-b35dee37ca7a8725f604ae46edd3b381ef987c16060dd8a0edcec2fc368ec2d63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Anchors</topic><topic>Ascorbic acid</topic><topic>Catalysis</topic><topic>Characterization and Evaluation of Materials</topic><topic>Charging</topic><topic>Chemistry and Materials Science</topic><topic>Chloroauric acid</topic><topic>Classical Mechanics</topic><topic>Composite materials industry</topic><topic>Crystallography and Scattering Methods</topic><topic>Electric properties</topic><topic>Electrochemical analysis</topic><topic>Gold</topic><topic>Graphene</topic><topic>Growth</topic><topic>Materials Science</topic><topic>Methylene blue</topic><topic>Nanoparticles</topic><topic>Optical properties</topic><topic>Oxides</topic><topic>Particulate composites</topic><topic>Polymer Sciences</topic><topic>Reduction</topic><topic>Solid Mechanics</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Han, Haitao</creatorcontrib><creatorcontrib>Pan, Dawei</creatorcontrib><creatorcontrib>Wu, Xuran</creatorcontrib><creatorcontrib>Zhang, Qing</creatorcontrib><creatorcontrib>Zhang, Haiyun</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Han, Haitao</au><au>Pan, Dawei</au><au>Wu, Xuran</au><au>Zhang, Qing</au><au>Zhang, Haiyun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of graphene/methylene blue/gold nanoparticles composites based on simultaneous green reduction, in situ growth and self-catalysis</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2014-07-01</date><risdate>2014</risdate><volume>49</volume><issue>14</issue><spage>4796</spage><epage>4806</epage><pages>4796-4806</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>The novel composites based on reduced graphene oxide/methylene blue/gold nanoparticles (rGO/MB/AuNPs) were synthesized by a green and easy method. This synthesis was realized through a one-step green reduction of graphene oxide and chloroauric acid by ascorbic acid, with MB as the assistant reductant and formed AuNPs as the self-catalyst. Except for electroactive substance, MB, which was firmly coated onto the surface of rGO through π–π stacking non-covalent interactions, also serves as the anchor for AuNPs in situ growth due to the electrostatic attraction between positively charged MB and negatively charged chloroauric ions. The characteristics of rGO/MB/AuNPs composites were investigated by various optical and electrical methods. These composites exhibit excellent electrochemical properties and promising prospects for practical application in electrochemical analysis.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s10853-014-8179-2</doi><tpages>11</tpages></addata></record> |
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subjects | Anchors Ascorbic acid Catalysis Characterization and Evaluation of Materials Charging Chemistry and Materials Science Chloroauric acid Classical Mechanics Composite materials industry Crystallography and Scattering Methods Electric properties Electrochemical analysis Gold Graphene Growth Materials Science Methylene blue Nanoparticles Optical properties Oxides Particulate composites Polymer Sciences Reduction Solid Mechanics Synthesis |
title | Synthesis of graphene/methylene blue/gold nanoparticles composites based on simultaneous green reduction, in situ growth and self-catalysis |
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