The cationic polymerization of 2, 4, 6-trimethylstyrene: from "truly living" to "controlled" polymers?

The cationic polymerization of 2,4,6‐trimethylstyrene in dichloromethane was initiated by the corresponding chloride with GaCl3 and BCl3 as Lewis acids. With GaCl3, the initiator, as well as the propagating ends, are fully ionized. The resulting cation appears stable from −70 to −30°C, leading to “t...

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Veröffentlicht in:	Macromolecular symposia. 2002-07, Vol.183 (1), p.43-52
Hauptverfasser:	Vairon, J.-P., Moreau, M., Charleux, B., Cretol, A., Faust, R.
Format:	Artikel
Sprache:	eng
Schlagworte:	Cationic polymerization Chlorides Ionization Lewis acid Polydispersity Polymers Propagation (polymerization) Rate constants
Online-Zugang:	Volltext
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