Magnetic ionic plastic crystal: choline[FeCl4]
A novel organic ionic plastic crystal (OIPC) based on a quaternary ammonium cation and a tetrachloroferrate anion has been synthesized with the intention of combining the properties of the ionic plastic crystal and the magnetism originating from the iron incorporated in the anion. The thermal analys...
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| Veröffentlicht in: | Physical chemistry chemical physics : PCCP 2013-08, Vol.15 (30), p.12724-12733 |
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| container_title | Physical chemistry chemical physics : PCCP |
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| creator | DE PEDRO, I GARCIA-SAIZ, A RODRIGUEZ FERNANDEZ, J GONZALEZ, J DE LARRAMENDI, Ruiz I ROJO, T AFONSO, Carlos A. M SIMEONOV, Svilen P WAERENBORGH, J. C BLANCO, Jesús A RAMAJO, B |
| description | A novel organic ionic plastic crystal (OIPC) based on a quaternary ammonium cation and a tetrachloroferrate anion has been synthesized with the intention of combining the properties of the ionic plastic crystal and the magnetism originating from the iron incorporated in the anion. The thermal analysis of the obtained OIPC showed a solid-solid phase transition below room temperature and a high melting point above 220 °C, indicating their plastic crystalline behaviour over a wide temperature range, as well as thermal stability up to approximately 200 °C. The magnetization measurements show the presence of three-dimensional antiferromagnetic ordering below 4 K. The results from electrochemical characterization display a solid-state ionic conduction sufficiently high and stable (between 10(-2.7) and 10(-3.6) S cm(-1) from 20 to 180 °C) for electrochemical applications. |
| doi_str_mv | 10.1039/c3cp50749a |
| format | Article |
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The results from electrochemical characterization display a solid-state ionic conduction sufficiently high and stable (between 10(-2.7) and 10(-3.6) S cm(-1) from 20 to 180 °C) for electrochemical applications.</description><identifier>ISSN: 1463-9076</identifier><identifier>EISSN: 1463-9084</identifier><identifier>DOI: 10.1039/c3cp50749a</identifier><identifier>PMID: 23793066</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Ammonium Compounds - chemistry ; Anions ; Chemistry ; Choline - chemistry ; Conduction heating ; Crystal structure ; Crystallization ; Crystals ; Dielectric Spectroscopy ; Electrochemistry ; Exact sciences and technology ; Ferrous Compounds - chemistry ; General and physical chemistry ; Ions - chemistry ; Iron ; Iron - chemistry ; Magnetics ; Magnetism ; Magnetization ; Phase Transition ; Thermodynamics ; Three dimensional ; Transition Temperature</subject><ispartof>Physical chemistry chemical physics : PCCP, 2013-08, Vol.15 (30), p.12724-12733</ispartof><rights>2014 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c416t-df51da3e64b3ff0db862b9ef5c53f2b73814d77bf8a203f36b6231f6cc6dee573</citedby><cites>FETCH-LOGICAL-c416t-df51da3e64b3ff0db862b9ef5c53f2b73814d77bf8a203f36b6231f6cc6dee573</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27540357$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/23793066$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>DE PEDRO, I</creatorcontrib><creatorcontrib>GARCIA-SAIZ, A</creatorcontrib><creatorcontrib>RODRIGUEZ FERNANDEZ, J</creatorcontrib><creatorcontrib>GONZALEZ, J</creatorcontrib><creatorcontrib>DE LARRAMENDI, Ruiz I</creatorcontrib><creatorcontrib>ROJO, T</creatorcontrib><creatorcontrib>AFONSO, Carlos A. 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The magnetization measurements show the presence of three-dimensional antiferromagnetic ordering below 4 K. The results from electrochemical characterization display a solid-state ionic conduction sufficiently high and stable (between 10(-2.7) and 10(-3.6) S cm(-1) from 20 to 180 °C) for electrochemical applications.</description><subject>Ammonium Compounds - chemistry</subject><subject>Anions</subject><subject>Chemistry</subject><subject>Choline - chemistry</subject><subject>Conduction heating</subject><subject>Crystal structure</subject><subject>Crystallization</subject><subject>Crystals</subject><subject>Dielectric Spectroscopy</subject><subject>Electrochemistry</subject><subject>Exact sciences and technology</subject><subject>Ferrous Compounds - chemistry</subject><subject>General and physical chemistry</subject><subject>Ions - chemistry</subject><subject>Iron</subject><subject>Iron - chemistry</subject><subject>Magnetics</subject><subject>Magnetism</subject><subject>Magnetization</subject><subject>Phase Transition</subject><subject>Thermodynamics</subject><subject>Three dimensional</subject><subject>Transition Temperature</subject><issn>1463-9076</issn><issn>1463-9084</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqF0MtKAzEUBuAgiq3VjQ8g3QgiTE3m5DJxJ8WqUHGjK5EhySQ6krmYTBd9e6d0bJduzgU-DocfoXOCZwSDvDFgWoYFleoAjQnlkEic0cPdLPgIncT4jTEmjMAxGqUgJGDOx2j2rD5r25VmWjZ1X1uv4mYzYR075W-n5qvxZW3fF3bu6ccpOnLKR3s29Al6W9y_zh-T5cvD0_xumRhKeJcUjpFCgeVUg3O40BlPtbSOGQYu1QIyQgshtMtUisEB1zwF4rgxvLCWCZigq-3dNjQ_Kxu7vCqjsd6r2jarmBMuCAMmpPyfgpR9OhxoT6-31IQmxmBd3oayUmGdE5xvosz3Ufb4Yri70pUtdvQvux5cDkBFo7wLqjZl3DvBKO5fhF_oMHpQ</recordid><startdate>20130814</startdate><enddate>20130814</enddate><creator>DE PEDRO, I</creator><creator>GARCIA-SAIZ, A</creator><creator>RODRIGUEZ FERNANDEZ, J</creator><creator>GONZALEZ, J</creator><creator>DE LARRAMENDI, Ruiz I</creator><creator>ROJO, T</creator><creator>AFONSO, Carlos A. M</creator><creator>SIMEONOV, Svilen P</creator><creator>WAERENBORGH, J. C</creator><creator>BLANCO, Jesús A</creator><creator>RAMAJO, B</creator><general>Royal Society of Chemistry</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20130814</creationdate><title>Magnetic ionic plastic crystal: choline[FeCl4]</title><author>DE PEDRO, I ; GARCIA-SAIZ, A ; RODRIGUEZ FERNANDEZ, J ; GONZALEZ, J ; DE LARRAMENDI, Ruiz I ; ROJO, T ; AFONSO, Carlos A. M ; SIMEONOV, Svilen P ; WAERENBORGH, J. 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M</au><au>SIMEONOV, Svilen P</au><au>WAERENBORGH, J. C</au><au>BLANCO, Jesús A</au><au>RAMAJO, B</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Magnetic ionic plastic crystal: choline[FeCl4]</atitle><jtitle>Physical chemistry chemical physics : PCCP</jtitle><addtitle>Phys Chem Chem Phys</addtitle><date>2013-08-14</date><risdate>2013</risdate><volume>15</volume><issue>30</issue><spage>12724</spage><epage>12733</epage><pages>12724-12733</pages><issn>1463-9076</issn><eissn>1463-9084</eissn><abstract>A novel organic ionic plastic crystal (OIPC) based on a quaternary ammonium cation and a tetrachloroferrate anion has been synthesized with the intention of combining the properties of the ionic plastic crystal and the magnetism originating from the iron incorporated in the anion. The thermal analysis of the obtained OIPC showed a solid-solid phase transition below room temperature and a high melting point above 220 °C, indicating their plastic crystalline behaviour over a wide temperature range, as well as thermal stability up to approximately 200 °C. The magnetization measurements show the presence of three-dimensional antiferromagnetic ordering below 4 K. The results from electrochemical characterization display a solid-state ionic conduction sufficiently high and stable (between 10(-2.7) and 10(-3.6) S cm(-1) from 20 to 180 °C) for electrochemical applications.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><pmid>23793066</pmid><doi>10.1039/c3cp50749a</doi><tpages>10</tpages></addata></record> |
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| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Ammonium Compounds - chemistry Anions Chemistry Choline - chemistry Conduction heating Crystal structure Crystallization Crystals Dielectric Spectroscopy Electrochemistry Exact sciences and technology Ferrous Compounds - chemistry General and physical chemistry Ions - chemistry Iron Iron - chemistry Magnetics Magnetism Magnetization Phase Transition Thermodynamics Three dimensional Transition Temperature |
| title | Magnetic ionic plastic crystal: choline[FeCl4] |
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