Efficient conversion of cellulose into biofuel precursor 5-hydroxymethylfurfural in dimethyl sulfoxide–ionic liquid mixtures
•Conversion of cellulose into HMF was developed in DMSO catalyzed by AlCl3.•HMF yield of 20.5% was obtained from cellulose in DMSO.•Ionic liquid [BMIM]Cl largely promoted the conversion of cellulose into HMF in DMSO.•High HMF yield of 54.9% was obtained in a mixed solvent DMSO-[BMIM]Cl (10 wt.%). In...
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| Veröffentlicht in: | Bioresource technology 2014-01, Vol.151, p.361-366 |
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| creator | Xiao, Shaohua Liu, Bing Wang, Yimei Fang, Zhongfeng Zhang, Zehui |
| description | •Conversion of cellulose into HMF was developed in DMSO catalyzed by AlCl3.•HMF yield of 20.5% was obtained from cellulose in DMSO.•Ionic liquid [BMIM]Cl largely promoted the conversion of cellulose into HMF in DMSO.•High HMF yield of 54.9% was obtained in a mixed solvent DMSO-[BMIM]Cl (10 wt.%).
In recent years, cellulose has received increasing attention as a potential material for the production of biofuels and bio-based chemicals. In this study, a new process for the efficient conversion of cellulose into 5-hydroxymethylfurfural (HMF) was developed by the use of AlCl3 as the catalyst in DMSO–ionic liquid ([BMIM]Cl) mixtures. Various reaction parameters such as reaction time, reaction temperature, solvent and catalyst dosage were investigated in detail. A high HMF yield of 54.9% was obtained from cellulose at 150°C after 9h in a mixed solvent of DMSO–[BMIM]Cl (10wt.%). More importantly, the catalytic system could be reused for several times despite of the slight loss of its catalytic activity. |
| doi_str_mv | 10.1016/j.biortech.2013.10.095 |
| format | Article |
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In recent years, cellulose has received increasing attention as a potential material for the production of biofuels and bio-based chemicals. In this study, a new process for the efficient conversion of cellulose into 5-hydroxymethylfurfural (HMF) was developed by the use of AlCl3 as the catalyst in DMSO–ionic liquid ([BMIM]Cl) mixtures. Various reaction parameters such as reaction time, reaction temperature, solvent and catalyst dosage were investigated in detail. A high HMF yield of 54.9% was obtained from cellulose at 150°C after 9h in a mixed solvent of DMSO–[BMIM]Cl (10wt.%). More importantly, the catalytic system could be reused for several times despite of the slight loss of its catalytic activity.</description><identifier>ISSN: 0960-8524</identifier><identifier>EISSN: 1873-2976</identifier><identifier>DOI: 10.1016/j.biortech.2013.10.095</identifier><identifier>PMID: 24269827</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>5-Hydroxymethylfurfural ; AlCl3 ; Aluminum Compounds - pharmacology ; Biofuel production ; Biofuels ; Biological and medical sciences ; Biotechnology ; Catalysis - drug effects ; Catalysts ; Cellulose ; Cellulose - metabolism ; Chlorides - pharmacology ; Conversion ; Dehydration ; Dimethyl ; Dimethyl Sulfoxide - pharmacology ; Energy ; Fuels ; Fundamental and applied biological sciences. Psychology ; Furaldehyde - analogs & derivatives ; Furaldehyde - chemistry ; Furaldehyde - metabolism ; Imidazoles - pharmacology ; Industrial applications and implications. Economical aspects ; Ionic liquids ; Ionic Liquids - pharmacology ; Lewis Acids - pharmacology ; Liquids ; Precursors ; Solvents ; Temperature</subject><ispartof>Bioresource technology, 2014-01, Vol.151, p.361-366</ispartof><rights>2013 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><rights>Copyright © 2013 Elsevier Ltd. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c464t-81bc2877c616e0659527f04d24fa10aabefa598d8a65b95245defedf55d15c113</citedby><cites>FETCH-LOGICAL-c464t-81bc2877c616e0659527f04d24fa10aabefa598d8a65b95245defedf55d15c113</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.biortech.2013.10.095$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,4024,27923,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28282286$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/24269827$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Xiao, Shaohua</creatorcontrib><creatorcontrib>Liu, Bing</creatorcontrib><creatorcontrib>Wang, Yimei</creatorcontrib><creatorcontrib>Fang, Zhongfeng</creatorcontrib><creatorcontrib>Zhang, Zehui</creatorcontrib><title>Efficient conversion of cellulose into biofuel precursor 5-hydroxymethylfurfural in dimethyl sulfoxide–ionic liquid mixtures</title><title>Bioresource technology</title><addtitle>Bioresour Technol</addtitle><description>•Conversion of cellulose into HMF was developed in DMSO catalyzed by AlCl3.•HMF yield of 20.5% was obtained from cellulose in DMSO.•Ionic liquid [BMIM]Cl largely promoted the conversion of cellulose into HMF in DMSO.•High HMF yield of 54.9% was obtained in a mixed solvent DMSO-[BMIM]Cl (10 wt.%).
In recent years, cellulose has received increasing attention as a potential material for the production of biofuels and bio-based chemicals. In this study, a new process for the efficient conversion of cellulose into 5-hydroxymethylfurfural (HMF) was developed by the use of AlCl3 as the catalyst in DMSO–ionic liquid ([BMIM]Cl) mixtures. Various reaction parameters such as reaction time, reaction temperature, solvent and catalyst dosage were investigated in detail. A high HMF yield of 54.9% was obtained from cellulose at 150°C after 9h in a mixed solvent of DMSO–[BMIM]Cl (10wt.%). More importantly, the catalytic system could be reused for several times despite of the slight loss of its catalytic activity.</description><subject>5-Hydroxymethylfurfural</subject><subject>AlCl3</subject><subject>Aluminum Compounds - pharmacology</subject><subject>Biofuel production</subject><subject>Biofuels</subject><subject>Biological and medical sciences</subject><subject>Biotechnology</subject><subject>Catalysis - drug effects</subject><subject>Catalysts</subject><subject>Cellulose</subject><subject>Cellulose - metabolism</subject><subject>Chlorides - pharmacology</subject><subject>Conversion</subject><subject>Dehydration</subject><subject>Dimethyl</subject><subject>Dimethyl Sulfoxide - pharmacology</subject><subject>Energy</subject><subject>Fuels</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>Furaldehyde - analogs & derivatives</subject><subject>Furaldehyde - chemistry</subject><subject>Furaldehyde - metabolism</subject><subject>Imidazoles - pharmacology</subject><subject>Industrial applications and implications. Economical aspects</subject><subject>Ionic liquids</subject><subject>Ionic Liquids - pharmacology</subject><subject>Lewis Acids - pharmacology</subject><subject>Liquids</subject><subject>Precursors</subject><subject>Solvents</subject><subject>Temperature</subject><issn>0960-8524</issn><issn>1873-2976</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkcuKHCEUQCUkZDqT_MLgJpBNddQqtWqXMEweMJBNshZLr7SNXfZoOXRvQv4hf5gviUX3JMtGQbie-9CD0A0la0qoeL9djz6mGcxmzQhta3BNBv4MrWgv24YNUjxHKzII0vScdVfoVc5bQkhLJXuJrljHxNAzuUI_75zzxsM0YxOnR0jZxwlHhw2EUELMgP00R1y7uQIB7xOYknJMmDebo03xcNzBvDkGV1LdOlQcW3-K4VyCiwdv4c-v37WuNzj4h-It3vnDXBLk1-iF0yHDm_N5jX58uvt--6W5__b56-3H-8Z0opubno6G9VIaQQUQwQfOpCOdZZ3TlGg9gtN86G2vBR_rZcctOLCOc0u5obS9Ru9OdfcpPhTIs9r5vDxRTxBLVlRIytuOiu4yyivMBWuHy2gdfqCylUtVcUJNijkncGqf_E6no6JELUbVVj0ZVYvRJV6N1sSbc48y7sD-S3tSWIG3Z0Bno4NLejI-_-f6ulgvKvfhxEH950cPSeXFuwHrq9NZ2egvzfIXfiHGZw</recordid><startdate>201401</startdate><enddate>201401</enddate><creator>Xiao, Shaohua</creator><creator>Liu, Bing</creator><creator>Wang, Yimei</creator><creator>Fang, Zhongfeng</creator><creator>Zhang, Zehui</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SU</scope><scope>7TB</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>KR7</scope></search><sort><creationdate>201401</creationdate><title>Efficient conversion of cellulose into biofuel precursor 5-hydroxymethylfurfural in dimethyl sulfoxide–ionic liquid mixtures</title><author>Xiao, Shaohua ; Liu, Bing ; Wang, Yimei ; Fang, Zhongfeng ; Zhang, Zehui</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c464t-81bc2877c616e0659527f04d24fa10aabefa598d8a65b95245defedf55d15c113</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>5-Hydroxymethylfurfural</topic><topic>AlCl3</topic><topic>Aluminum Compounds - pharmacology</topic><topic>Biofuel production</topic><topic>Biofuels</topic><topic>Biological and medical sciences</topic><topic>Biotechnology</topic><topic>Catalysis - drug effects</topic><topic>Catalysts</topic><topic>Cellulose</topic><topic>Cellulose - metabolism</topic><topic>Chlorides - pharmacology</topic><topic>Conversion</topic><topic>Dehydration</topic><topic>Dimethyl</topic><topic>Dimethyl Sulfoxide - pharmacology</topic><topic>Energy</topic><topic>Fuels</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>Furaldehyde - analogs & derivatives</topic><topic>Furaldehyde - chemistry</topic><topic>Furaldehyde - metabolism</topic><topic>Imidazoles - pharmacology</topic><topic>Industrial applications and implications. Economical aspects</topic><topic>Ionic liquids</topic><topic>Ionic Liquids - pharmacology</topic><topic>Lewis Acids - pharmacology</topic><topic>Liquids</topic><topic>Precursors</topic><topic>Solvents</topic><topic>Temperature</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xiao, Shaohua</creatorcontrib><creatorcontrib>Liu, Bing</creatorcontrib><creatorcontrib>Wang, Yimei</creatorcontrib><creatorcontrib>Fang, Zhongfeng</creatorcontrib><creatorcontrib>Zhang, Zehui</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Environmental Engineering Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><jtitle>Bioresource technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xiao, Shaohua</au><au>Liu, Bing</au><au>Wang, Yimei</au><au>Fang, Zhongfeng</au><au>Zhang, Zehui</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Efficient conversion of cellulose into biofuel precursor 5-hydroxymethylfurfural in dimethyl sulfoxide–ionic liquid mixtures</atitle><jtitle>Bioresource technology</jtitle><addtitle>Bioresour Technol</addtitle><date>2014-01</date><risdate>2014</risdate><volume>151</volume><spage>361</spage><epage>366</epage><pages>361-366</pages><issn>0960-8524</issn><eissn>1873-2976</eissn><abstract>•Conversion of cellulose into HMF was developed in DMSO catalyzed by AlCl3.•HMF yield of 20.5% was obtained from cellulose in DMSO.•Ionic liquid [BMIM]Cl largely promoted the conversion of cellulose into HMF in DMSO.•High HMF yield of 54.9% was obtained in a mixed solvent DMSO-[BMIM]Cl (10 wt.%).
In recent years, cellulose has received increasing attention as a potential material for the production of biofuels and bio-based chemicals. In this study, a new process for the efficient conversion of cellulose into 5-hydroxymethylfurfural (HMF) was developed by the use of AlCl3 as the catalyst in DMSO–ionic liquid ([BMIM]Cl) mixtures. Various reaction parameters such as reaction time, reaction temperature, solvent and catalyst dosage were investigated in detail. A high HMF yield of 54.9% was obtained from cellulose at 150°C after 9h in a mixed solvent of DMSO–[BMIM]Cl (10wt.%). More importantly, the catalytic system could be reused for several times despite of the slight loss of its catalytic activity.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><pmid>24269827</pmid><doi>10.1016/j.biortech.2013.10.095</doi><tpages>6</tpages></addata></record> |
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| subjects | 5-Hydroxymethylfurfural AlCl3 Aluminum Compounds - pharmacology Biofuel production Biofuels Biological and medical sciences Biotechnology Catalysis - drug effects Catalysts Cellulose Cellulose - metabolism Chlorides - pharmacology Conversion Dehydration Dimethyl Dimethyl Sulfoxide - pharmacology Energy Fuels Fundamental and applied biological sciences. Psychology Furaldehyde - analogs & derivatives Furaldehyde - chemistry Furaldehyde - metabolism Imidazoles - pharmacology Industrial applications and implications. Economical aspects Ionic liquids Ionic Liquids - pharmacology Lewis Acids - pharmacology Liquids Precursors Solvents Temperature |
| title | Efficient conversion of cellulose into biofuel precursor 5-hydroxymethylfurfural in dimethyl sulfoxide–ionic liquid mixtures |
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