High-strength composite yarns derived from oxygen plasma modified super-aligned carbon nanotube arrays

Spinning carbon nanotube (CNT) yarns from super-aligned carbon nanotube (SACNT) arrays is a promising approach to fabricate high-strength fibers. However the reported tensile strengths of the as-prepared fibers are far below that of an individual CNT. It is therefore still a challenge to improve the...

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Veröffentlicht in:Nano research 2013-03, Vol.6 (3), p.208-215
Hauptverfasser: Wei, Haoming, Wei, Yang, Wu, Yang, Liu, Liang, Fan, Shoushan, Jiang, Kaili
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container_end_page 215
container_issue 3
container_start_page 208
container_title Nano research
container_volume 6
creator Wei, Haoming
Wei, Yang
Wu, Yang
Liu, Liang
Fan, Shoushan
Jiang, Kaili
description Spinning carbon nanotube (CNT) yarns from super-aligned carbon nanotube (SACNT) arrays is a promising approach to fabricate high-strength fibers. However the reported tensile strengths of the as-prepared fibers are far below that of an individual CNT. It is therefore still a challenge to improve their mechanical strengths. Here we report that the tensile strengths and Young's moduli can be further improved to 2.2 GPa and 200 GPa respectively, if we first treat the SACNT array with oxygen plasma by using a reactive ion etching (RIE) facility, then dry spin yarns from it and make composite fibers with polyvinyl alcohol. According to the experimental results obtained using scanning electron microscopy (SEM), Raman spectroscopy and X-ray photoelectron spectroscopy (XPS), the improvement is attributed to the oxygen RIE process, as it can create functional groups on the outer walls of CNTs and thus improve the interaction between the CNTs and the polymer molecules.
doi_str_mv 10.1007/s12274-013-0297-7
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identifier ISSN: 1998-0124
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source Springer Nature - Complete Springer Journals
subjects Arrays
Atomic/Molecular Structure and Spectra
Biomedicine
Biotechnology
Carbon
Carbon nanotubes
Chemical vapor deposition
Chemistry and Materials Science
Condensed Matter Physics
Fibers
Laser etching
Materials Science
Mechanical properties
Nanostructure
Nanotechnology
Oxygen
Oxygen plasma
Plasma etching
Polymers
Polyvinyl alcohol
Research Article
Scanning electron microscopy
Silicon wafers
Spectroscopy
Spectrum analysis
Tensile strength
X射线光电子能谱
Yarn
Yarns
复合纱线
拉伸强度
氧等离子体处理
电子显微镜
碳纳米管阵列
等离子体改性
高强度纤维
title High-strength composite yarns derived from oxygen plasma modified super-aligned carbon nanotube arrays
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