Activation of poly(methyl methacrylate) surfaces by atmospheric pressure plasma
The use of atmospheric plasma generated by Diffuse Coplanar Surface Barrier Discharge (DCSBD) for treatment of poly (methyl methacrylate) (PMMA) sheets is presented. The modified surfaces were characterized by contact angle measurements to determine the free surface energy, atomic force microscope (...
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| Veröffentlicht in: | Polymer degradation and stability 2012-06, Vol.97 (6), p.886-892 |
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| container_title | Polymer degradation and stability |
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| creator | Homola, Tomáš Matoušek, Jindřich Hergelová, Beáta Kormunda, Martin Wu, Linda Y.L. Černák, Mirko |
| description | The use of atmospheric plasma generated by Diffuse Coplanar Surface Barrier Discharge (DCSBD) for treatment of poly (methyl methacrylate) (PMMA) sheets is presented. The modified surfaces were characterized by contact angle measurements to determine the free surface energy, atomic force microscope (AFM) to investigate the changes in surface morphology, and X-ray photoelectron spectroscopy (XPS) to study the chemical composition changes after the plasma treatment. We found that increased free surface energy was related to the enhanced oxygen containing chemical groups on the polymer surface. In respect to the influence of gas composition, similar results were achieved from ambient air, nitrogen and oxygen. AFM measurements showed no effect on surface morphology by the plasma treatment. The stability of hydrophilic property was achieved over 3–5 days after plasma treatment. |
| doi_str_mv | 10.1016/j.polymdegradstab.2012.03.029 |
| format | Article |
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The modified surfaces were characterized by contact angle measurements to determine the free surface energy, atomic force microscope (AFM) to investigate the changes in surface morphology, and X-ray photoelectron spectroscopy (XPS) to study the chemical composition changes after the plasma treatment. We found that increased free surface energy was related to the enhanced oxygen containing chemical groups on the polymer surface. In respect to the influence of gas composition, similar results were achieved from ambient air, nitrogen and oxygen. AFM measurements showed no effect on surface morphology by the plasma treatment. 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The stability of hydrophilic property was achieved over 3–5 days after plasma treatment.</description><subject>air</subject><subject>Applied sciences</subject><subject>atmospheric pressure</subject><subject>Atmospheric pressure plasma</subject><subject>Atomic force microscopy</subject><subject>chemical composition</subject><subject>contact angle</subject><subject>energy</subject><subject>Exact sciences and technology</subject><subject>Gas composition</subject><subject>hydrophilicity</subject><subject>Morphology</subject><subject>nitrogen</subject><subject>oxygen</subject><subject>Physicochemistry of polymers</subject><subject>Plasma treatment</subject><subject>Poly (methyl methacrylate) PMMA</subject><subject>Polymer</subject><subject>Polymer industry, paints, wood</subject><subject>Polymethyl methacrylates</subject><subject>polymethylmethacrylate</subject><subject>Stability</subject><subject>Surface activation</subject><subject>Surface chemistry</subject><subject>Surface energy</subject><subject>Technology of polymers</subject><subject>X-ray photoelectron spectroscopy</subject><subject>XPS</subject><issn>0141-3910</issn><issn>1873-2321</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNqNkE1v1DAQhi0EEkvhN5BLpXJImLGdrwOHqoKCVKkH6NmaOOPWq2Qd7Gyl_Hu82ooDJ3yZg595Z-YR4hKhQsDm875awrTNIz9GGtNKQyUBZQWqAtm_EjvsWlVKJfG12AFqLFWP8Fa8S2kP-ekad-L-2q7-mVYfDkVwxSnwaub1aZuKUyEbt4lW_lSkY3RkORXDVtA6h7Q8cfS2WCKn_MfFMlGa6b1442hK_OGlXoiHb19_3Xwv7-5vf9xc35VWd81a9robW6JWIbYNIdS9RZCgnaqhAc3D2I3c46iGBoCGXvZaoyNHg5KNVY26EFfn3CWG30dOq5l9sjxNdOBwTAabFmusQcmMfjmjNoaUIjuzRD9T3AyCOYk0e_OPSHMSaUCZLDL3X76MomRpcpEO1qe_IbLuOg0SM_fxzDkKhh5jZh5-5qB8AeRD2y4Tt2eCs5lnz9Ek6_lgefSR7WrG4P9zpz9vrJxm</recordid><startdate>20120601</startdate><enddate>20120601</enddate><creator>Homola, Tomáš</creator><creator>Matoušek, Jindřich</creator><creator>Hergelová, Beáta</creator><creator>Kormunda, Martin</creator><creator>Wu, Linda Y.L.</creator><creator>Černák, Mirko</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>FBQ</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20120601</creationdate><title>Activation of poly(methyl methacrylate) surfaces by atmospheric pressure plasma</title><author>Homola, Tomáš ; 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| ispartof | Polymer degradation and stability, 2012-06, Vol.97 (6), p.886-892 |
| issn | 0141-3910 1873-2321 |
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| source | Elsevier ScienceDirect Journals |
| subjects | air Applied sciences atmospheric pressure Atmospheric pressure plasma Atomic force microscopy chemical composition contact angle energy Exact sciences and technology Gas composition hydrophilicity Morphology nitrogen oxygen Physicochemistry of polymers Plasma treatment Poly (methyl methacrylate) PMMA Polymer Polymer industry, paints, wood Polymethyl methacrylates polymethylmethacrylate Stability Surface activation Surface chemistry Surface energy Technology of polymers X-ray photoelectron spectroscopy XPS |
| title | Activation of poly(methyl methacrylate) surfaces by atmospheric pressure plasma |
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