Simulated annealing reconstruction and characterization of a LiCoO2 Lithium-ion battery cathode

We reconstruct the three-dimensional microstructure of a cathode from a commercial LiCoO2 Lithium-ion battery with an adapted simulated annealing approach. The real size distribution curve of LiCoO2 particles is applied to regulate the reconstruction process. By discretizing a 40 μm×40 μm×40 μm cath...

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Veröffentlicht in:Chinese science bulletin 2013-12, Vol.58 (36), p.4692-4695
Hauptverfasser: Wu, Wei, Jiang, FangMing
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description We reconstruct the three-dimensional microstructure of a cathode from a commercial LiCoO2 Lithium-ion battery with an adapted simulated annealing approach. The real size distribution curve of LiCoO2 particles is applied to regulate the reconstruction process. By discretizing a 40 μm×40 μm×40 μm cathode volume with 8000000 numerical cubes, the cathode involving three individual phases: (1) LiCoO2 as active material, (2) pores or electrolyte, and (3) additives (polyvinylidene fluoride+carbon black) is reconstructed. Characterization of the reconstructed cathode gives important structural and transport properties including volume-specific surface area between phases, tortuosity and geometrical connectivity of individual phase.
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subjects additives
annealing
batteries
Cathodes
Chemistry/Food Science
Earth Sciences
electrodes
Electrolytes
Engineering
Humanities and Social Sciences
Life Sciences
Lithium-ion batteries
microstructure
multidisciplinary
Phases
Physics
Reconstruction
Science
Science (multidisciplinary)
Simulated annealing
surface area
Three dimensional
Tortuosity
三维微结构
分布曲线
模拟退火方法
聚偏氟乙烯
表征
钴酸锂
锂离子电池
阴极
title Simulated annealing reconstruction and characterization of a LiCoO2 Lithium-ion battery cathode
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