Direct hydrofluorothermal synthesis of sodium transition metal fluorosulfates as possible Na-ion battery cathode materials
Synthesis under hydrofluorothermal conditions produces new iron, manganese and vanadium fluorosulfates; these include the isomorphous Na(3)M(III)F(2)(SO(4))(2), M = V, Mn, Fe, with a sheet-like structure formed of linked M(III)F(2)O(4) and SO(4) polyhedra separated by sodium ions which may be extrac...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2013-03, Vol.49 (21), p.2121-2123 |
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creator | Wang, Qianlong Madsen, Alex Owen, John R Weller, Mark T |
description | Synthesis under hydrofluorothermal conditions produces new iron, manganese and vanadium fluorosulfates; these include the isomorphous Na(3)M(III)F(2)(SO(4))(2), M = V, Mn, Fe, with a sheet-like structure formed of linked M(III)F(2)O(4) and SO(4) polyhedra separated by sodium ions which may be extracted electrochemically at potentials of >3.5 V. |
doi_str_mv | 10.1039/c3cc38897b |
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these include the isomorphous Na(3)M(III)F(2)(SO(4))(2), M = V, Mn, Fe, with a sheet-like structure formed of linked M(III)F(2)O(4) and SO(4) polyhedra separated by sodium ions which may be extracted electrochemically at potentials of >3.5 V.</description><subject>Electric batteries</subject><subject>Iron</subject><subject>Manganese</subject><subject>Polyhedrons</subject><subject>Sodium</subject><subject>Synthesis</subject><subject>Transition metals</subject><subject>Vanadium</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNqFkU9r3DAQxUVpaf60l36AomMpOJUs25KOIWmTQEgvDeRmRvKIVbFXW4182H76atk0PXZgeO_wmwfDY-yDFBdSKPvFK--VMVa7V-xUqqFr-s48vT743jZadf0JOyP6KerI3rxlJ61SxtY9Zb-vY0Zf-GY_5RTmNeVUNpgXmDntt9VSJJ4CpzTFdeElw5ZiiWnLFywVOp7QOgcoSByI7xJRdDPyB2gOnINSMO-5h7JJE_KlgjnCTO_Ym1AF3z_rOXv89vXH1W1z__3m7uryvvGqFaWRWk5OIUg7aD2BHgJ4MUDX6g6EGpzonHYhoBCTQQcheD-hHnwvlIA-WHXOPh1zdzn9WpHKuETyOM-wxbTSKActO6Os7f6PtsYoYduhr-jnI-rr-5QxjLscF8j7UYrxUMv4r5YKf3zOXd2C0wv6twf1B94RjHs</recordid><startdate>20130314</startdate><enddate>20130314</enddate><creator>Wang, Qianlong</creator><creator>Madsen, Alex</creator><creator>Owen, John R</creator><creator>Weller, Mark T</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20130314</creationdate><title>Direct hydrofluorothermal synthesis of sodium transition metal fluorosulfates as possible Na-ion battery cathode materials</title><author>Wang, Qianlong ; Madsen, Alex ; Owen, John R ; Weller, Mark T</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c320t-171db3ea19677da76fac06a4274a036b04b7bffe00d8ebaffccde76c5030a5f93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Electric batteries</topic><topic>Iron</topic><topic>Manganese</topic><topic>Polyhedrons</topic><topic>Sodium</topic><topic>Synthesis</topic><topic>Transition metals</topic><topic>Vanadium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Qianlong</creatorcontrib><creatorcontrib>Madsen, Alex</creatorcontrib><creatorcontrib>Owen, John R</creatorcontrib><creatorcontrib>Weller, Mark T</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Qianlong</au><au>Madsen, Alex</au><au>Owen, John R</au><au>Weller, Mark T</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Direct hydrofluorothermal synthesis of sodium transition metal fluorosulfates as possible Na-ion battery cathode materials</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2013-03-14</date><risdate>2013</risdate><volume>49</volume><issue>21</issue><spage>2121</spage><epage>2123</epage><pages>2121-2123</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Synthesis under hydrofluorothermal conditions produces new iron, manganese and vanadium fluorosulfates; these include the isomorphous Na(3)M(III)F(2)(SO(4))(2), M = V, Mn, Fe, with a sheet-like structure formed of linked M(III)F(2)O(4) and SO(4) polyhedra separated by sodium ions which may be extracted electrochemically at potentials of >3.5 V.</abstract><cop>England</cop><pmid>23389338</pmid><doi>10.1039/c3cc38897b</doi><tpages>3</tpages></addata></record> |
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source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Electric batteries Iron Manganese Polyhedrons Sodium Synthesis Transition metals Vanadium |
title | Direct hydrofluorothermal synthesis of sodium transition metal fluorosulfates as possible Na-ion battery cathode materials |
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