A General and Efficient Method for the Alkoxycarbonylation of [alpha]-Chloro Ketones

The alkoxycarbonylation of [alpha]-chloro ketones with carbon monoxide in alcoholic solvents could be optimized to generate [beta]-keto esters in high yields using much lower catalyst loadings than previously reported in the literature. Among the different screened parameters, the nature of the liga...

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Veröffentlicht in:	Advanced synthesis & catalysis 2012-11, Vol.354 (16), p.3105-3114
Hauptverfasser:	Wahl, Benoit, Bonin, Helene, Mortreux, Andre, Giboulot, Steven, Liron, Frederic, Poli, Giovanni, Sauthier, Mathieu
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon monoxide Catalysis Catalysts Esters Ketones Ligands Solvents Synthesis
Online-Zugang:	Volltext
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