Crystal structure and chiral recognition of supramolecular complex composed of tris(1,2-diaminoethane)cobalt(iii) carbonate and [small alpha]-cyclodextrin, [Co(en)3]2(CO3)3 times 2([small alpha]-CDX)

Crystal structure and chiral recognition of supramolecular complex composed of tris(1,2-diaminoethane)cobalt(iii) carbonate and [small alpha]-cyclodextrin, [Co(en)3]2(CO3)3 times 2([small alpha]-CDX)

The novel CoIII-CDX supramolecular complex [Co(en)3]2(CO3)3[middle dot]2([small alpha]-CDX) (1) was prepared and the circular dichroism spectrum showed that complex 1 is 25% [capital Lambda]-rich ([capital Lambda] : [capital Delta] = 62.5 : 37.5). X-ray crystallography revealed the crystal structure...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2010-01, Vol.46 (20), p.3535-3537
Hauptverfasser: Ohta, Natsuki, Fuyuhiro, Akira, Yamanari, Kazuaki
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Sprache:eng
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Carbonates
Crystal structure
Crystallography
Deltas
Dichroism
Recognition
X-rays
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container_title Chemical communications (Cambridge, England)
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creator Ohta, Natsuki
Fuyuhiro, Akira
Yamanari, Kazuaki
description The novel CoIII-CDX supramolecular complex [Co(en)3]2(CO3)3[middle dot]2([small alpha]-CDX) (1) was prepared and the circular dichroism spectrum showed that complex 1 is 25% [capital Lambda]-rich ([capital Lambda] : [capital Delta] = 62.5 : 37.5). X-ray crystallography revealed the crystal structure of complex 1 and the reasonable chiral recognition mechanism of this system.
doi_str_mv 10.1039/B923824G
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Carbonates
Crystal structure
Crystallography
Deltas
Dichroism
Recognition
X-rays
title Crystal structure and chiral recognition of supramolecular complex composed of tris(1,2-diaminoethane)cobalt(iii) carbonate and [small alpha]-cyclodextrin, [Co(en)3]2(CO3)3 times 2([small alpha]-CDX)
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