Mechanism of Co3O4/graphene catalytic activity in LiaO2 batteries using carbonate based electrolytes

We synthesized a hybrid graphene/Co3O4 catalyst by a simple chemical reduction method, and demonstrated that a LiaO2 cell with the hybrid catalyst delivers a highly reversible capacity. We examined the role of the catalyst in LiaO2 batteries and through careful analyses of the reactions in the batte...

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Veröffentlicht in:Electrochimica acta 2013-02, Vol.90, p.63-70
Hauptverfasser: Lim, Hee-Dae, Gwon, Hyeokjo, Kim, Haegyeom, Kim, Sung-Wook, Yoon, Taeho, Choi, Jang, Oh, Seung, Kang, Kisuk
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container_title Electrochimica acta
container_volume 90
creator Lim, Hee-Dae
Gwon, Hyeokjo
Kim, Haegyeom
Kim, Sung-Wook
Yoon, Taeho
Choi, Jang
Oh, Seung
Kang, Kisuk
description We synthesized a hybrid graphene/Co3O4 catalyst by a simple chemical reduction method, and demonstrated that a LiaO2 cell with the hybrid catalyst delivers a highly reversible capacity. We examined the role of the catalyst in LiaO2 batteries and through careful analyses of the reactions in the battery, we found that the reaction path fundamentally changes with the use of catalyst, and propose a mechanism of how the rechargeability is improved in LiaO2 batteries.
doi_str_mv 10.1016/j.electacta.2012.12.020
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source Elsevier ScienceDirect Journals
subjects Carbonates
Catalysts
Catalytic activity
Electric batteries
Electrolytes
Electrolytic cells
Graphene
Reduction (chemical)
title Mechanism of Co3O4/graphene catalytic activity in LiaO2 batteries using carbonate based electrolytes
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