Nylon-6/liquid natural rubber blends prepared via emulsion dispersion
Nylon-6 is widely used as engineering plastic because it is easy to process, high tensile properties, resistant to chemical and abrasion. However, poor impact strength at low temperature makes it limitedly used in some applications. Nylon-6/liquid natural rubber (LNR) blends were prepared via emulsi...
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| Veröffentlicht in: | Journal of polymer research 2009-07, Vol.16 (4), p.381-387 |
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| creator | Shamsuri, Ahmad Adlie Daik, Rusli Ahmad, Ishak Jumali, Mohd Hafizuddin Hj |
| description | Nylon-6 is widely used as engineering plastic because it is easy to process, high tensile properties, resistant to chemical and abrasion. However, poor impact strength at low temperature makes it limitedly used in some applications. Nylon-6/liquid natural rubber (LNR) blends were prepared via emulsion dispersion with composition of 100nylon-6/0LNR, 95nylon-6/5LNR, 90nylon-6/10LNR, 85nylon-6/15LNR, 80nylon-6/20LNR and 75nylon-6/25LNR. Nylon-6 was dissolved in a 2,2,2-trifluoroethanol and chloroform mixture (1:1 TFE/CHCl₃) and emulsified with hexadecyltrimethylammonium bromide (HTAB). LNR was dispersed into the nylon-6 emulsion to form homogeneous nylon-6/LNR emulsions and the emulsions were de-emulsified with methanol, filtered and dried. High impact behaviour was achieved at 85nylon-6/15LNR composition. DSC thermogram indicated a single glass transition temperature, T g and SEM images showed no phase separation between blend components implying homogeneous blends were obtained. |
| doi_str_mv | 10.1007/s10965-008-9239-6 |
| format | Article |
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However, poor impact strength at low temperature makes it limitedly used in some applications. Nylon-6/liquid natural rubber (LNR) blends were prepared via emulsion dispersion with composition of 100nylon-6/0LNR, 95nylon-6/5LNR, 90nylon-6/10LNR, 85nylon-6/15LNR, 80nylon-6/20LNR and 75nylon-6/25LNR. Nylon-6 was dissolved in a 2,2,2-trifluoroethanol and chloroform mixture (1:1 TFE/CHCl₃) and emulsified with hexadecyltrimethylammonium bromide (HTAB). LNR was dispersed into the nylon-6 emulsion to form homogeneous nylon-6/LNR emulsions and the emulsions were de-emulsified with methanol, filtered and dried. High impact behaviour was achieved at 85nylon-6/15LNR composition. 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However, poor impact strength at low temperature makes it limitedly used in some applications. Nylon-6/liquid natural rubber (LNR) blends were prepared via emulsion dispersion with composition of 100nylon-6/0LNR, 95nylon-6/5LNR, 90nylon-6/10LNR, 85nylon-6/15LNR, 80nylon-6/20LNR and 75nylon-6/25LNR. Nylon-6 was dissolved in a 2,2,2-trifluoroethanol and chloroform mixture (1:1 TFE/CHCl₃) and emulsified with hexadecyltrimethylammonium bromide (HTAB). LNR was dispersed into the nylon-6 emulsion to form homogeneous nylon-6/LNR emulsions and the emulsions were de-emulsified with methanol, filtered and dried. High impact behaviour was achieved at 85nylon-6/15LNR composition. DSC thermogram indicated a single glass transition temperature, T g and SEM images showed no phase separation between blend components implying homogeneous blends were obtained.</description><subject>Abrasion resistance</subject><subject>Blends</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Dispersions</subject><subject>Emulsion dispersion</subject><subject>Emulsions</subject><subject>Glass</subject><subject>Impact strength</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Liquid natural rubber</subject><subject>Liquids</subject><subject>Natural rubber</subject><subject>Nylon</subject><subject>Polymer blend</subject><subject>Polymer blends</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Thermoplastic elastomer</subject><issn>1022-9760</issn><issn>1572-8935</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kEtPwzAQhC0EEuXxAzgRceJiumvHjn1EVXlIFRygZ8tJncpVmqR2g9R_j6sgIXHgtHP4ZjQ7hNwgPCBAMY0IWgoKoKhmXFN5QiYoCkaV5uI0aWCM6kLCObmIcQMgRCHVhMzfDk3XUjlt_G7wq6y1-yHYJgtDWbqQlY1rVzHrg-ttcKvsy9vMbYcm-q7NVj72LhzlFTmrbRPd9c-9JMun-efshS7en19njwta8YLtqUWd16rIrZVlXtfcplIMOdTauVpWnKFFVkJlJa-YyksJCkHkUpRKSKuRX5L7MbcP3W5wcW-2PlauaWzruiEalAXmnHMsEnr3B910Q2hTO6MUV5JjDgnCEapCF2NwtemD39pwMAjmuKsZdzVpV3Pc1cjkYaMnJrZdu_Ab_J_pdjTVtjN2HXw0yw8G6XeUueKC8W9tCYKg</recordid><startdate>20090701</startdate><enddate>20090701</enddate><creator>Shamsuri, Ahmad Adlie</creator><creator>Daik, Rusli</creator><creator>Ahmad, Ishak</creator><creator>Jumali, Mohd Hafizuddin Hj</creator><general>Dordrecht : Springer Netherlands</general><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>FBQ</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20090701</creationdate><title>Nylon-6/liquid natural rubber blends prepared via emulsion dispersion</title><author>Shamsuri, Ahmad Adlie ; 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However, poor impact strength at low temperature makes it limitedly used in some applications. Nylon-6/liquid natural rubber (LNR) blends were prepared via emulsion dispersion with composition of 100nylon-6/0LNR, 95nylon-6/5LNR, 90nylon-6/10LNR, 85nylon-6/15LNR, 80nylon-6/20LNR and 75nylon-6/25LNR. Nylon-6 was dissolved in a 2,2,2-trifluoroethanol and chloroform mixture (1:1 TFE/CHCl₃) and emulsified with hexadecyltrimethylammonium bromide (HTAB). LNR was dispersed into the nylon-6 emulsion to form homogeneous nylon-6/LNR emulsions and the emulsions were de-emulsified with methanol, filtered and dried. High impact behaviour was achieved at 85nylon-6/15LNR composition. DSC thermogram indicated a single glass transition temperature, T g and SEM images showed no phase separation between blend components implying homogeneous blends were obtained.</abstract><cop>Dordrecht</cop><pub>Dordrecht : Springer Netherlands</pub><doi>10.1007/s10965-008-9239-6</doi><tpages>7</tpages></addata></record> |
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| subjects | Abrasion resistance Blends Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Dispersions Emulsion dispersion Emulsions Glass Impact strength Industrial Chemistry/Chemical Engineering Liquid natural rubber Liquids Natural rubber Nylon Polymer blend Polymer blends Polymer Sciences Polymers Thermoplastic elastomer |
| title | Nylon-6/liquid natural rubber blends prepared via emulsion dispersion |
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