Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamido]diamminecopper(II): aqua or ammine ligands?
Diffraction results obtained at 100 and 291 K, the former at high resolution, are reported for the title compound, [Cu(C10H9N4O2S)2(NH3)2] or [Cu(sulfa)2(NH3)2] [Hsulfa is 4‐amino‐N‐(pyrimidin‐2‐yl)benzenesulfonamide]. The CuII cation is coordinated by two N‐atom donors from a bidentate sulfa ligand...
Gespeichert in:
| Veröffentlicht in: | Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2013-11, Vol.69 (11), p.1221-1224 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1224 |
|---|---|
| container_issue | 11 |
| container_start_page | 1221 |
| container_title | Acta crystallographica. Section C, Crystal structure communications |
| container_volume | 69 |
| creator | Pan, Fangfang Kalf, Irmgard Englert, Ulli |
| description | Diffraction results obtained at 100 and 291 K, the former at high resolution, are reported for the title compound, [Cu(C10H9N4O2S)2(NH3)2] or [Cu(sulfa)2(NH3)2] [Hsulfa is 4‐amino‐N‐(pyrimidin‐2‐yl)benzenesulfonamide]. The CuII cation is coordinated by two N‐atom donors from a bidentate sulfa ligand, by two ammonia molecules in the equatorial plane and by a monohapto (η1) sulfadiazine at the apex of a distorted square pyramid. The present interpretation and two earlier reports [Brown, Cook & Sengier (1987). Acta Cryst. C43, 2332–2334; Tommasino, Renaud, Luneau & Pilet (2011). Polyhedron, 30, 1663–1670] disagree about the nature and geometry of the ligands. The relationship between the present result and the former is discussed, and evidence is provided that the latter erroneously assigned an ammine as an aqua ligand. |
| doi_str_mv | 10.1107/S0108270113025948 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1671433267</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1671433267</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4493-108bc63cbb8c12d58928917728549935e0bfc48f88505b800c5833b929ac42203</originalsourceid><addsrcrecordid>eNqFkUtvEzEUhS0EoiHwA9igSGzSheH6NbbZoBLREiktr0JBgCyPx4Nc5lW7Iwi_HkdTuoBFV16c7xyd64PQQwJPCAH59D0QUFQCIQyo0FzdQjNSAGAhhb6NZjsZ7_Q9dC-lcwCglLK7aI9yoikp6Ax9fRHSF45tG7oen-DlsI2hDVXoMMXbZr_03W_f-TQ2dd9lqOq_VcG2mfauHwYfl-v1_rOFvRjtoo-LSVk04bvtqvT8PrpT2yb5B1fvHH04fHm6eoU3r4_Wq4MNdpxrhnPL0hXMlaVyhFZCaao0kZIqwbVmwkNZO65qpQSIUgE4oRgrNdXWcUqBzdFyyh1ifzH6dGnakJxvGtv5fkyGFJJwxmghb0ZzI6pAgcjo43_Q836MXT5kRykltczt54hMlIt9StHXZsg_aOPWEDC7lcx_K2XPo6vksWx9de34O0sG1AT8DI3f3pxoDj6vDo8ZAMtWPFlDuvS_rq02_jD5fCnM2cmR2bx5e_zx09mpecf-ACa-qI0</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1448879749</pqid></control><display><type>article</type><title>Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamido]diamminecopper(II): aqua or ammine ligands?</title><source>MEDLINE</source><source>Wiley Online Library Journals Frontfile Complete</source><source>Alma/SFX Local Collection</source><creator>Pan, Fangfang ; Kalf, Irmgard ; Englert, Ulli</creator><creatorcontrib>Pan, Fangfang ; Kalf, Irmgard ; Englert, Ulli</creatorcontrib><description>Diffraction results obtained at 100 and 291 K, the former at high resolution, are reported for the title compound, [Cu(C10H9N4O2S)2(NH3)2] or [Cu(sulfa)2(NH3)2] [Hsulfa is 4‐amino‐N‐(pyrimidin‐2‐yl)benzenesulfonamide]. The CuII cation is coordinated by two N‐atom donors from a bidentate sulfa ligand, by two ammonia molecules in the equatorial plane and by a monohapto (η1) sulfadiazine at the apex of a distorted square pyramid. The present interpretation and two earlier reports [Brown, Cook & Sengier (1987). Acta Cryst. C43, 2332–2334; Tommasino, Renaud, Luneau & Pilet (2011). Polyhedron, 30, 1663–1670] disagree about the nature and geometry of the ligands. The relationship between the present result and the former is discussed, and evidence is provided that the latter erroneously assigned an ammine as an aqua ligand.</description><identifier>ISSN: 0108-2701</identifier><identifier>EISSN: 1600-5759</identifier><identifier>DOI: 10.1107/S0108270113025948</identifier><identifier>PMID: 24192162</identifier><language>eng</language><publisher>5 Abbey Square, Chester, Cheshire CH1 2HU, England: International Union of Crystallography</publisher><subject>Amino acids ; Ammines ; Ammonia ; Atoms & subatomic particles ; Coordination Complexes - chemistry ; Copper - chemistry ; copper compounds ; Crystal structure ; Crystallography, X-Ray ; Diffraction ; Distortion ; Ligands ; Molecular Structure ; Polyhedrons ; Pyramids ; sulfadiazine ; sulfonamide compounds</subject><ispartof>Acta crystallographica. Section C, Crystal structure communications, 2013-11, Vol.69 (11), p.1221-1224</ispartof><rights>International Union of Crystallography, 2013</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4493-108bc63cbb8c12d58928917728549935e0bfc48f88505b800c5833b929ac42203</citedby><cites>FETCH-LOGICAL-c4493-108bc63cbb8c12d58928917728549935e0bfc48f88505b800c5833b929ac42203</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1107%2FS0108270113025948$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1107%2FS0108270113025948$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27904,27905,45554,45555</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/24192162$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Pan, Fangfang</creatorcontrib><creatorcontrib>Kalf, Irmgard</creatorcontrib><creatorcontrib>Englert, Ulli</creatorcontrib><title>Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamido]diamminecopper(II): aqua or ammine ligands?</title><title>Acta crystallographica. Section C, Crystal structure communications</title><addtitle>Acta Cryst. C</addtitle><description>Diffraction results obtained at 100 and 291 K, the former at high resolution, are reported for the title compound, [Cu(C10H9N4O2S)2(NH3)2] or [Cu(sulfa)2(NH3)2] [Hsulfa is 4‐amino‐N‐(pyrimidin‐2‐yl)benzenesulfonamide]. The CuII cation is coordinated by two N‐atom donors from a bidentate sulfa ligand, by two ammonia molecules in the equatorial plane and by a monohapto (η1) sulfadiazine at the apex of a distorted square pyramid. The present interpretation and two earlier reports [Brown, Cook & Sengier (1987). Acta Cryst. C43, 2332–2334; Tommasino, Renaud, Luneau & Pilet (2011). Polyhedron, 30, 1663–1670] disagree about the nature and geometry of the ligands. The relationship between the present result and the former is discussed, and evidence is provided that the latter erroneously assigned an ammine as an aqua ligand.</description><subject>Amino acids</subject><subject>Ammines</subject><subject>Ammonia</subject><subject>Atoms & subatomic particles</subject><subject>Coordination Complexes - chemistry</subject><subject>Copper - chemistry</subject><subject>copper compounds</subject><subject>Crystal structure</subject><subject>Crystallography, X-Ray</subject><subject>Diffraction</subject><subject>Distortion</subject><subject>Ligands</subject><subject>Molecular Structure</subject><subject>Polyhedrons</subject><subject>Pyramids</subject><subject>sulfadiazine</subject><subject>sulfonamide compounds</subject><issn>0108-2701</issn><issn>1600-5759</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkUtvEzEUhS0EoiHwA9igSGzSheH6NbbZoBLREiktr0JBgCyPx4Nc5lW7Iwi_HkdTuoBFV16c7xyd64PQQwJPCAH59D0QUFQCIQyo0FzdQjNSAGAhhb6NZjsZ7_Q9dC-lcwCglLK7aI9yoikp6Ax9fRHSF45tG7oen-DlsI2hDVXoMMXbZr_03W_f-TQ2dd9lqOq_VcG2mfauHwYfl-v1_rOFvRjtoo-LSVk04bvtqvT8PrpT2yb5B1fvHH04fHm6eoU3r4_Wq4MNdpxrhnPL0hXMlaVyhFZCaao0kZIqwbVmwkNZO65qpQSIUgE4oRgrNdXWcUqBzdFyyh1ifzH6dGnakJxvGtv5fkyGFJJwxmghb0ZzI6pAgcjo43_Q836MXT5kRykltczt54hMlIt9StHXZsg_aOPWEDC7lcx_K2XPo6vksWx9de34O0sG1AT8DI3f3pxoDj6vDo8ZAMtWPFlDuvS_rq02_jD5fCnM2cmR2bx5e_zx09mpecf-ACa-qI0</recordid><startdate>201311</startdate><enddate>201311</enddate><creator>Pan, Fangfang</creator><creator>Kalf, Irmgard</creator><creator>Englert, Ulli</creator><general>International Union of Crystallography</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>201311</creationdate><title>Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamido]diamminecopper(II): aqua or ammine ligands?</title><author>Pan, Fangfang ; Kalf, Irmgard ; Englert, Ulli</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4493-108bc63cbb8c12d58928917728549935e0bfc48f88505b800c5833b929ac42203</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Amino acids</topic><topic>Ammines</topic><topic>Ammonia</topic><topic>Atoms & subatomic particles</topic><topic>Coordination Complexes - chemistry</topic><topic>Copper - chemistry</topic><topic>copper compounds</topic><topic>Crystal structure</topic><topic>Crystallography, X-Ray</topic><topic>Diffraction</topic><topic>Distortion</topic><topic>Ligands</topic><topic>Molecular Structure</topic><topic>Polyhedrons</topic><topic>Pyramids</topic><topic>sulfadiazine</topic><topic>sulfonamide compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pan, Fangfang</creatorcontrib><creatorcontrib>Kalf, Irmgard</creatorcontrib><creatorcontrib>Englert, Ulli</creatorcontrib><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Acta crystallographica. Section C, Crystal structure communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pan, Fangfang</au><au>Kalf, Irmgard</au><au>Englert, Ulli</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamido]diamminecopper(II): aqua or ammine ligands?</atitle><jtitle>Acta crystallographica. Section C, Crystal structure communications</jtitle><addtitle>Acta Cryst. C</addtitle><date>2013-11</date><risdate>2013</risdate><volume>69</volume><issue>11</issue><spage>1221</spage><epage>1224</epage><pages>1221-1224</pages><issn>0108-2701</issn><eissn>1600-5759</eissn><abstract>Diffraction results obtained at 100 and 291 K, the former at high resolution, are reported for the title compound, [Cu(C10H9N4O2S)2(NH3)2] or [Cu(sulfa)2(NH3)2] [Hsulfa is 4‐amino‐N‐(pyrimidin‐2‐yl)benzenesulfonamide]. The CuII cation is coordinated by two N‐atom donors from a bidentate sulfa ligand, by two ammonia molecules in the equatorial plane and by a monohapto (η1) sulfadiazine at the apex of a distorted square pyramid. The present interpretation and two earlier reports [Brown, Cook & Sengier (1987). Acta Cryst. C43, 2332–2334; Tommasino, Renaud, Luneau & Pilet (2011). Polyhedron, 30, 1663–1670] disagree about the nature and geometry of the ligands. The relationship between the present result and the former is discussed, and evidence is provided that the latter erroneously assigned an ammine as an aqua ligand.</abstract><cop>5 Abbey Square, Chester, Cheshire CH1 2HU, England</cop><pub>International Union of Crystallography</pub><pmid>24192162</pmid><doi>10.1107/S0108270113025948</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0108-2701 |
| ispartof | Acta crystallographica. Section C, Crystal structure communications, 2013-11, Vol.69 (11), p.1221-1224 |
| issn | 0108-2701 1600-5759 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1671433267 |
| source | MEDLINE; Wiley Online Library Journals Frontfile Complete; Alma/SFX Local Collection |
| subjects | Amino acids Ammines Ammonia Atoms & subatomic particles Coordination Complexes - chemistry Copper - chemistry copper compounds Crystal structure Crystallography, X-Ray Diffraction Distortion Ligands Molecular Structure Polyhedrons Pyramids sulfadiazine sulfonamide compounds |
| title | Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamido]diamminecopper(II): aqua or ammine ligands? |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-21T09%3A51%3A53IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Bis%5B4-amino-N-(pyrimidin-2-yl)benzenesulfonamido%5Ddiamminecopper(II):%20aqua%20or%20ammine%20ligands?&rft.jtitle=Acta%20crystallographica.%20Section%20C,%20Crystal%20structure%20communications&rft.au=Pan,%20Fangfang&rft.date=2013-11&rft.volume=69&rft.issue=11&rft.spage=1221&rft.epage=1224&rft.pages=1221-1224&rft.issn=0108-2701&rft.eissn=1600-5759&rft_id=info:doi/10.1107/S0108270113025948&rft_dat=%3Cproquest_cross%3E1671433267%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1448879749&rft_id=info:pmid/24192162&rfr_iscdi=true |