Organoboranes-atmospheric oxygen systems as unconventional initiators of radical polymerization

This paper provides the first generalization and analysis of our results and published data about a new type of pseudoliving process: radical polymerization mediated by boroxyl radicals generated through the oxidation of organoboranes by atmospheric oxygen. The kinetics and mechanism of polymerizati...

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Veröffentlicht in:	Polymer science. Series B 2013-05, Vol.55 (5-6), p.304-326
Hauptverfasser:	Zaremski, M. Yu, Garina, E. S., Gurskii, M. E., Bubnov, Yu. N.
Format:	Artikel
Sprache:	eng
Schlagworte:	Atmospherics Chemistry Chemistry and Materials Science Design engineering Initiators Oxidation Polymer Sciences Polymerization Polymethyl methacrylates Radicals Reviews Vinyl acetate
Online-Zugang:	Volltext
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