Molecular dynamics revealed from frequency dependent heat capacity

Temperature modulated DSC (TMDSC) measurements at reasonably high frequencies allow for the determination of baseline heat capacity. In this particular case vitrification and devitrification of the rigid amorphous fraction (RAF) can be directly observed. 0.01 Hz seems to be a reasonably high frequen...

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Veröffentlicht in:	Macromolecular symposia. 2001-03, Vol.165 (1), p.83-90
Hauptverfasser:	Schick, Christoph, Wurm, Andreas, Merzlyakov, Mikhail, Minakov, Alexander, Marand, Hervé
Format:	Artikel
Sprache:	eng
Schlagworte:	Crystals Devitrification Differential scanning calorimetry Heat capacity High frequencies Melting Polycarbonates Specific heat
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