Synthesis of poly(3,4-ethylenedioxythiophene) nanoparticles via chemical oxidation polymerization
Poly(3,4‐ethylenedioxythiophene) (PEDOT) nanoparticles were synthesized via chemical oxidation polymerization using 3,4‐ethylenedioxythiophene as the starting monomer and ammonium peroxydisulfate (APS) as the oxidant. The effects of APS concentration, surfactant concentration and type of surfactant,...
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| Veröffentlicht in: | Polymer international 2014-01, Vol.63 (1), p.106-113 |
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| creator | Paradee, Nophawan Sirivat, Anuvat |
| description | Poly(3,4‐ethylenedioxythiophene) (PEDOT) nanoparticles were synthesized via chemical oxidation polymerization using 3,4‐ethylenedioxythiophene as the starting monomer and ammonium peroxydisulfate (APS) as the oxidant. The effects of APS concentration, surfactant concentration and type of surfactant, namely dodecylbenzenesulfonic acid and sodium dodecylsulfate, were investigated. Distinct particle shapes were obtained: irregular, raspberry agglomerate, coralliform, orange‐peel, globular and plum shapes. The particle sizes and the electrical conductivity are in the ranges 60 to 900 nm and |
| doi_str_mv | 10.1002/pi.4538 |
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This work reports the tailor‐made poly(3,4‐ethylenedioxythiophene) (PEDOT) shapes and properties relationship under various synthesis conditions, such as ammonium peroxydisulfate (APS) initiator concentration and type of surfactant.</description><identifier>ISSN: 0959-8103</identifier><identifier>EISSN: 1097-0126</identifier><identifier>DOI: 10.1002/pi.4538</identifier><identifier>CODEN: PLYIEI</identifier><language>eng</language><publisher>Chichester, UK: John Wiley & Sons, Ltd</publisher><subject>4-ethylenedioxythiophene ; Applied sciences ; chemical oxidation polymerization ; Electrical conductivity ; Electrical resistivity ; Exact sciences and technology ; nanoparticle synthesis ; Organic polymers ; Oxidation ; Particle size ; Physicochemistry of polymers ; poly ; poly(3,4‐ethylenedioxythiophene) ; Polymerization ; Polymers with particular properties ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; Resistivity ; Surfactants ; Synthesis</subject><ispartof>Polymer international, 2014-01, Vol.63 (1), p.106-113</ispartof><rights>2013 Society of Chemical Industry</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3958-fe63cf5fbc29fe4c890d47dfb33c421af9a650ce490836ed60b21851bfe02d193</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpi.4538$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpi.4538$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,4024,27923,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28036564$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Paradee, Nophawan</creatorcontrib><creatorcontrib>Sirivat, Anuvat</creatorcontrib><title>Synthesis of poly(3,4-ethylenedioxythiophene) nanoparticles via chemical oxidation polymerization</title><title>Polymer international</title><addtitle>Polym. Int</addtitle><description>Poly(3,4‐ethylenedioxythiophene) (PEDOT) nanoparticles were synthesized via chemical oxidation polymerization using 3,4‐ethylenedioxythiophene as the starting monomer and ammonium peroxydisulfate (APS) as the oxidant. The effects of APS concentration, surfactant concentration and type of surfactant, namely dodecylbenzenesulfonic acid and sodium dodecylsulfate, were investigated. Distinct particle shapes were obtained: irregular, raspberry agglomerate, coralliform, orange‐peel, globular and plum shapes. The particle sizes and the electrical conductivity are in the ranges 60 to 900 nm and <1 to 153 S cm−1, respectively, depending on the polymerization conditions. PEDOT synthesis in the absence of a surfactant yields a smaller particle size because a larger amount of initiator induces lower molecular weights and smaller PEDOT particles. The smaller PEDOT particles correspond to higher electrical conductivity because of the larger surface areas for electron transfer and a smaller amount of obstructing surfactant aliphatic segments. Moreover, particle size and shape can be varied, depending on surfactant type and concentration which dictate the micellar shapes in the polymerization reaction. This work is focused on the tailor‐made PEDOT shape and property relationship under synthesis conditions where several shapes have not been previously seen. © 2013 Society of Chemical Industry
This work reports the tailor‐made poly(3,4‐ethylenedioxythiophene) (PEDOT) shapes and properties relationship under various synthesis conditions, such as ammonium peroxydisulfate (APS) initiator concentration and type of surfactant.</description><subject>4-ethylenedioxythiophene</subject><subject>Applied sciences</subject><subject>chemical oxidation polymerization</subject><subject>Electrical conductivity</subject><subject>Electrical resistivity</subject><subject>Exact sciences and technology</subject><subject>nanoparticle synthesis</subject><subject>Organic polymers</subject><subject>Oxidation</subject><subject>Particle size</subject><subject>Physicochemistry of polymers</subject><subject>poly</subject><subject>poly(3,4‐ethylenedioxythiophene)</subject><subject>Polymerization</subject><subject>Polymers with particular properties</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Resistivity</subject><subject>Surfactants</subject><subject>Synthesis</subject><issn>0959-8103</issn><issn>1097-0126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNpdkV9L3EAUxQep4HYtfoWAFCxt9E7mT2Ye26VaQdSi4uMwO7lDxmYzaSbbbvrpm3XFBx8uh8P9cbiXQ8gRhVMKUJx14ZQLpvbIjIIuc6CFfEdmoIXOFQV2QN6n9AQASms9I_ZubIcaU0hZ9FkXm_GEfeE5DvXYYItViJtxqEPs6sl9ylrbxs72Q3ANpuxPsJmrcRWcbbK4CZUdQmyfU1bYh3_P9pDse9sk_PCic_Jw_v1-8SO_urm4XHy9yh3TQuUeJXNe-KUrtEfulIaKl5VfMuZ4Qa3XVgpwyDUoJrGSsCyoEnTpEYqKajYnJ7vcro-_15gGswrJYdPYFuM6GSpLygsmp5mT4zfoU1z37XSdoVwKJURZbgM_vlA2TQ_63rYuJNP1YWX70RQKmBSST9znHfc3NDi-7imYbR-mC2bbh7m93MpE5zs6pAE3r7TtfxlZslKYx-sLw36e399-u1sYwf4DPh2OuA</recordid><startdate>201401</startdate><enddate>201401</enddate><creator>Paradee, Nophawan</creator><creator>Sirivat, Anuvat</creator><general>John Wiley & Sons, Ltd</general><general>Wiley</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>IQODW</scope><scope>7SR</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><scope>7U5</scope><scope>L7M</scope></search><sort><creationdate>201401</creationdate><title>Synthesis of poly(3,4-ethylenedioxythiophene) nanoparticles via chemical oxidation polymerization</title><author>Paradee, Nophawan ; Sirivat, Anuvat</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3958-fe63cf5fbc29fe4c890d47dfb33c421af9a650ce490836ed60b21851bfe02d193</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>4-ethylenedioxythiophene</topic><topic>Applied sciences</topic><topic>chemical oxidation polymerization</topic><topic>Electrical conductivity</topic><topic>Electrical resistivity</topic><topic>Exact sciences and technology</topic><topic>nanoparticle synthesis</topic><topic>Organic polymers</topic><topic>Oxidation</topic><topic>Particle size</topic><topic>Physicochemistry of polymers</topic><topic>poly</topic><topic>poly(3,4‐ethylenedioxythiophene)</topic><topic>Polymerization</topic><topic>Polymers with particular properties</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>Resistivity</topic><topic>Surfactants</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Paradee, Nophawan</creatorcontrib><creatorcontrib>Sirivat, Anuvat</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Polymer international</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Paradee, Nophawan</au><au>Sirivat, Anuvat</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of poly(3,4-ethylenedioxythiophene) nanoparticles via chemical oxidation polymerization</atitle><jtitle>Polymer international</jtitle><addtitle>Polym. Int</addtitle><date>2014-01</date><risdate>2014</risdate><volume>63</volume><issue>1</issue><spage>106</spage><epage>113</epage><pages>106-113</pages><issn>0959-8103</issn><eissn>1097-0126</eissn><coden>PLYIEI</coden><abstract>Poly(3,4‐ethylenedioxythiophene) (PEDOT) nanoparticles were synthesized via chemical oxidation polymerization using 3,4‐ethylenedioxythiophene as the starting monomer and ammonium peroxydisulfate (APS) as the oxidant. The effects of APS concentration, surfactant concentration and type of surfactant, namely dodecylbenzenesulfonic acid and sodium dodecylsulfate, were investigated. Distinct particle shapes were obtained: irregular, raspberry agglomerate, coralliform, orange‐peel, globular and plum shapes. The particle sizes and the electrical conductivity are in the ranges 60 to 900 nm and <1 to 153 S cm−1, respectively, depending on the polymerization conditions. PEDOT synthesis in the absence of a surfactant yields a smaller particle size because a larger amount of initiator induces lower molecular weights and smaller PEDOT particles. The smaller PEDOT particles correspond to higher electrical conductivity because of the larger surface areas for electron transfer and a smaller amount of obstructing surfactant aliphatic segments. Moreover, particle size and shape can be varied, depending on surfactant type and concentration which dictate the micellar shapes in the polymerization reaction. This work is focused on the tailor‐made PEDOT shape and property relationship under synthesis conditions where several shapes have not been previously seen. © 2013 Society of Chemical Industry
This work reports the tailor‐made poly(3,4‐ethylenedioxythiophene) (PEDOT) shapes and properties relationship under various synthesis conditions, such as ammonium peroxydisulfate (APS) initiator concentration and type of surfactant.</abstract><cop>Chichester, UK</cop><pub>John Wiley & Sons, Ltd</pub><doi>10.1002/pi.4538</doi><tpages>8</tpages></addata></record> |
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| subjects | 4-ethylenedioxythiophene Applied sciences chemical oxidation polymerization Electrical conductivity Electrical resistivity Exact sciences and technology nanoparticle synthesis Organic polymers Oxidation Particle size Physicochemistry of polymers poly poly(3,4‐ethylenedioxythiophene) Polymerization Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts Resistivity Surfactants Synthesis |
| title | Synthesis of poly(3,4-ethylenedioxythiophene) nanoparticles via chemical oxidation polymerization |
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