An artificial muscle model unit based on inorganic nanosheet sliding by photochemical reaction
From the viewpoint of developing photoresponsive supramolecular systems in microenvironments to exhibit more sophisticated photo-functions even at the macroscopic level, inorganic/organic hybrid compounds based on clay or niobate nanosheets as the microenvironments were prepared, characterized, and...
Gespeichert in:
| Veröffentlicht in: | Nanoscale 2013-04, Vol.5 (8), p.3182-3193 |
|---|---|
| Hauptverfasser: | , , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 3193 |
|---|---|
| container_issue | 8 |
| container_start_page | 3182 |
| container_title | Nanoscale |
| container_volume | 5 |
| creator | Nabetani, Yu Takamura, Hazuki Hayasaka, Yuika Sasamoto, Shin Tanamura, Yoshihiko Shimada, Tetsuya Masui, Dai Takagi, Shinsuke Tachibana, Hiroshi Tong, Zhiwei Inoue, Haruo |
| description | From the viewpoint of developing photoresponsive supramolecular systems in microenvironments to exhibit more sophisticated photo-functions even at the macroscopic level, inorganic/organic hybrid compounds based on clay or niobate nanosheets as the microenvironments were prepared, characterized, and examined for their photoreactions. We show here a novel type of artificial muscle model unit having much similarity with that in natural muscle fibrils. Upon photoirradiation, the organic/inorganic hybrid nanosheets reversibly slide horizontally on a giant scale, and the interlayer spaces in the layered hybrid structure shrink and expand vertically. In particular, our layered hybrid molecular system exhibits a macroscopic morphological change on a giant scale (~1500 nm) compared with the molecular size of ~1 nm, based on a reversible sliding mechanism. |
| doi_str_mv | 10.1039/c3nr34308a |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_proquest_miscellaneous_1671421862</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1321794258</sourcerecordid><originalsourceid>FETCH-LOGICAL-p174t-fc4e5794f65fcd21ba49bb967f2e282d9f25c0c5a0c8edacb671a186e61923983</originalsourceid><addsrcrecordid>eNqFkDtPwzAcxC0EolBY-ADII0vArzjxWFW8pEossBL58U9rlNjBToZ-e4IorEx3w91Pp0PoipJbSri6szwkLjip9RE6Y0SQgvOKHf95KRboPOcPQqTikp-iBeOiorTiZ-h9FbBOo2-99brD_ZRtB7iPDjo8BT9iozM4HAP2IaatDt7ioEPMO4AR5847H7bY7PGwi2O0O-i9nTkJtB19DBfopNVdhsuDLtHbw_3r-qnYvDw-r1ebYqCVGIvWCigrJVpZttYxarRQxihZtQxYzZxqWWmJLTWxNThtjayoprUESRXjquZLdPPDHVL8nCCPTe-zha7TAeKUGzoXBJsb7P8oZ3Sewspv6vUhOpkeXDMk3-u0b37v41_8a3Hb</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1321794258</pqid></control><display><type>article</type><title>An artificial muscle model unit based on inorganic nanosheet sliding by photochemical reaction</title><source>MEDLINE</source><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Nabetani, Yu ; Takamura, Hazuki ; Hayasaka, Yuika ; Sasamoto, Shin ; Tanamura, Yoshihiko ; Shimada, Tetsuya ; Masui, Dai ; Takagi, Shinsuke ; Tachibana, Hiroshi ; Tong, Zhiwei ; Inoue, Haruo</creator><creatorcontrib>Nabetani, Yu ; Takamura, Hazuki ; Hayasaka, Yuika ; Sasamoto, Shin ; Tanamura, Yoshihiko ; Shimada, Tetsuya ; Masui, Dai ; Takagi, Shinsuke ; Tachibana, Hiroshi ; Tong, Zhiwei ; Inoue, Haruo</creatorcontrib><description>From the viewpoint of developing photoresponsive supramolecular systems in microenvironments to exhibit more sophisticated photo-functions even at the macroscopic level, inorganic/organic hybrid compounds based on clay or niobate nanosheets as the microenvironments were prepared, characterized, and examined for their photoreactions. We show here a novel type of artificial muscle model unit having much similarity with that in natural muscle fibrils. Upon photoirradiation, the organic/inorganic hybrid nanosheets reversibly slide horizontally on a giant scale, and the interlayer spaces in the layered hybrid structure shrink and expand vertically. In particular, our layered hybrid molecular system exhibits a macroscopic morphological change on a giant scale (~1500 nm) compared with the molecular size of ~1 nm, based on a reversible sliding mechanism.</description><identifier>ISSN: 2040-3364</identifier><identifier>EISSN: 2040-3372</identifier><identifier>DOI: 10.1039/c3nr34308a</identifier><identifier>PMID: 23471173</identifier><language>eng</language><publisher>England</publisher><subject>Aluminum Silicates - chemistry ; Artificial muscles ; Azo Compounds - chemistry ; Catalysis ; Fluorides - chemistry ; Humans ; Interlayers ; Minerals - chemistry ; Models, Anatomic ; Models, Biological ; Muscles ; Nanocomposites ; Nanomaterials ; Nanostructure ; Nanostructures - chemistry ; Photochemical Processes ; Polymerization - radiation effects ; Polymers - chemical synthesis ; Polymers - chemistry ; Similarity ; Sliding ; Stereoisomerism</subject><ispartof>Nanoscale, 2013-04, Vol.5 (8), p.3182-3193</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/23471173$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Nabetani, Yu</creatorcontrib><creatorcontrib>Takamura, Hazuki</creatorcontrib><creatorcontrib>Hayasaka, Yuika</creatorcontrib><creatorcontrib>Sasamoto, Shin</creatorcontrib><creatorcontrib>Tanamura, Yoshihiko</creatorcontrib><creatorcontrib>Shimada, Tetsuya</creatorcontrib><creatorcontrib>Masui, Dai</creatorcontrib><creatorcontrib>Takagi, Shinsuke</creatorcontrib><creatorcontrib>Tachibana, Hiroshi</creatorcontrib><creatorcontrib>Tong, Zhiwei</creatorcontrib><creatorcontrib>Inoue, Haruo</creatorcontrib><title>An artificial muscle model unit based on inorganic nanosheet sliding by photochemical reaction</title><title>Nanoscale</title><addtitle>Nanoscale</addtitle><description>From the viewpoint of developing photoresponsive supramolecular systems in microenvironments to exhibit more sophisticated photo-functions even at the macroscopic level, inorganic/organic hybrid compounds based on clay or niobate nanosheets as the microenvironments were prepared, characterized, and examined for their photoreactions. We show here a novel type of artificial muscle model unit having much similarity with that in natural muscle fibrils. Upon photoirradiation, the organic/inorganic hybrid nanosheets reversibly slide horizontally on a giant scale, and the interlayer spaces in the layered hybrid structure shrink and expand vertically. In particular, our layered hybrid molecular system exhibits a macroscopic morphological change on a giant scale (~1500 nm) compared with the molecular size of ~1 nm, based on a reversible sliding mechanism.</description><subject>Aluminum Silicates - chemistry</subject><subject>Artificial muscles</subject><subject>Azo Compounds - chemistry</subject><subject>Catalysis</subject><subject>Fluorides - chemistry</subject><subject>Humans</subject><subject>Interlayers</subject><subject>Minerals - chemistry</subject><subject>Models, Anatomic</subject><subject>Models, Biological</subject><subject>Muscles</subject><subject>Nanocomposites</subject><subject>Nanomaterials</subject><subject>Nanostructure</subject><subject>Nanostructures - chemistry</subject><subject>Photochemical Processes</subject><subject>Polymerization - radiation effects</subject><subject>Polymers - chemical synthesis</subject><subject>Polymers - chemistry</subject><subject>Similarity</subject><subject>Sliding</subject><subject>Stereoisomerism</subject><issn>2040-3364</issn><issn>2040-3372</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkDtPwzAcxC0EolBY-ADII0vArzjxWFW8pEossBL58U9rlNjBToZ-e4IorEx3w91Pp0PoipJbSri6szwkLjip9RE6Y0SQgvOKHf95KRboPOcPQqTikp-iBeOiorTiZ-h9FbBOo2-99brD_ZRtB7iPDjo8BT9iozM4HAP2IaatDt7ioEPMO4AR5847H7bY7PGwi2O0O-i9nTkJtB19DBfopNVdhsuDLtHbw_3r-qnYvDw-r1ebYqCVGIvWCigrJVpZttYxarRQxihZtQxYzZxqWWmJLTWxNThtjayoprUESRXjquZLdPPDHVL8nCCPTe-zha7TAeKUGzoXBJsb7P8oZ3Sewspv6vUhOpkeXDMk3-u0b37v41_8a3Hb</recordid><startdate>20130421</startdate><enddate>20130421</enddate><creator>Nabetani, Yu</creator><creator>Takamura, Hazuki</creator><creator>Hayasaka, Yuika</creator><creator>Sasamoto, Shin</creator><creator>Tanamura, Yoshihiko</creator><creator>Shimada, Tetsuya</creator><creator>Masui, Dai</creator><creator>Takagi, Shinsuke</creator><creator>Tachibana, Hiroshi</creator><creator>Tong, Zhiwei</creator><creator>Inoue, Haruo</creator><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20130421</creationdate><title>An artificial muscle model unit based on inorganic nanosheet sliding by photochemical reaction</title><author>Nabetani, Yu ; Takamura, Hazuki ; Hayasaka, Yuika ; Sasamoto, Shin ; Tanamura, Yoshihiko ; Shimada, Tetsuya ; Masui, Dai ; Takagi, Shinsuke ; Tachibana, Hiroshi ; Tong, Zhiwei ; Inoue, Haruo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p174t-fc4e5794f65fcd21ba49bb967f2e282d9f25c0c5a0c8edacb671a186e61923983</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Aluminum Silicates - chemistry</topic><topic>Artificial muscles</topic><topic>Azo Compounds - chemistry</topic><topic>Catalysis</topic><topic>Fluorides - chemistry</topic><topic>Humans</topic><topic>Interlayers</topic><topic>Minerals - chemistry</topic><topic>Models, Anatomic</topic><topic>Models, Biological</topic><topic>Muscles</topic><topic>Nanocomposites</topic><topic>Nanomaterials</topic><topic>Nanostructure</topic><topic>Nanostructures - chemistry</topic><topic>Photochemical Processes</topic><topic>Polymerization - radiation effects</topic><topic>Polymers - chemical synthesis</topic><topic>Polymers - chemistry</topic><topic>Similarity</topic><topic>Sliding</topic><topic>Stereoisomerism</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nabetani, Yu</creatorcontrib><creatorcontrib>Takamura, Hazuki</creatorcontrib><creatorcontrib>Hayasaka, Yuika</creatorcontrib><creatorcontrib>Sasamoto, Shin</creatorcontrib><creatorcontrib>Tanamura, Yoshihiko</creatorcontrib><creatorcontrib>Shimada, Tetsuya</creatorcontrib><creatorcontrib>Masui, Dai</creatorcontrib><creatorcontrib>Takagi, Shinsuke</creatorcontrib><creatorcontrib>Tachibana, Hiroshi</creatorcontrib><creatorcontrib>Tong, Zhiwei</creatorcontrib><creatorcontrib>Inoue, Haruo</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Nanoscale</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nabetani, Yu</au><au>Takamura, Hazuki</au><au>Hayasaka, Yuika</au><au>Sasamoto, Shin</au><au>Tanamura, Yoshihiko</au><au>Shimada, Tetsuya</au><au>Masui, Dai</au><au>Takagi, Shinsuke</au><au>Tachibana, Hiroshi</au><au>Tong, Zhiwei</au><au>Inoue, Haruo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An artificial muscle model unit based on inorganic nanosheet sliding by photochemical reaction</atitle><jtitle>Nanoscale</jtitle><addtitle>Nanoscale</addtitle><date>2013-04-21</date><risdate>2013</risdate><volume>5</volume><issue>8</issue><spage>3182</spage><epage>3193</epage><pages>3182-3193</pages><issn>2040-3364</issn><eissn>2040-3372</eissn><abstract>From the viewpoint of developing photoresponsive supramolecular systems in microenvironments to exhibit more sophisticated photo-functions even at the macroscopic level, inorganic/organic hybrid compounds based on clay or niobate nanosheets as the microenvironments were prepared, characterized, and examined for their photoreactions. We show here a novel type of artificial muscle model unit having much similarity with that in natural muscle fibrils. Upon photoirradiation, the organic/inorganic hybrid nanosheets reversibly slide horizontally on a giant scale, and the interlayer spaces in the layered hybrid structure shrink and expand vertically. In particular, our layered hybrid molecular system exhibits a macroscopic morphological change on a giant scale (~1500 nm) compared with the molecular size of ~1 nm, based on a reversible sliding mechanism.</abstract><cop>England</cop><pmid>23471173</pmid><doi>10.1039/c3nr34308a</doi><tpages>12</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2040-3364 |
| ispartof | Nanoscale, 2013-04, Vol.5 (8), p.3182-3193 |
| issn | 2040-3364 2040-3372 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1671421862 |
| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Aluminum Silicates - chemistry Artificial muscles Azo Compounds - chemistry Catalysis Fluorides - chemistry Humans Interlayers Minerals - chemistry Models, Anatomic Models, Biological Muscles Nanocomposites Nanomaterials Nanostructure Nanostructures - chemistry Photochemical Processes Polymerization - radiation effects Polymers - chemical synthesis Polymers - chemistry Similarity Sliding Stereoisomerism |
| title | An artificial muscle model unit based on inorganic nanosheet sliding by photochemical reaction |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-19T09%3A21%3A59IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=An%20artificial%20muscle%20model%20unit%20based%20on%20inorganic%20nanosheet%20sliding%20by%20photochemical%20reaction&rft.jtitle=Nanoscale&rft.au=Nabetani,%20Yu&rft.date=2013-04-21&rft.volume=5&rft.issue=8&rft.spage=3182&rft.epage=3193&rft.pages=3182-3193&rft.issn=2040-3364&rft.eissn=2040-3372&rft_id=info:doi/10.1039/c3nr34308a&rft_dat=%3Cproquest_pubme%3E1321794258%3C/proquest_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1321794258&rft_id=info:pmid/23471173&rfr_iscdi=true |