Synthesis and luminescence properties of a novel red Sr3Bi(PO4)3:Sm3+ phosphor
A series of Sr3Bi1–x(PO4)3: xSm3+phosphors were prepared by solid state method at 1250 °C for 4 h. X-ray diffraction (XRD) indicated that the sample was of a pure phase of Sr3Bi(PO4)3. The main excitation peaks were located at 343 (6H5/2→4H9/2), 360 (6H5/2→4D3/2), 373 (6H5/2→6P7/2), 400 (6H5/2→4F7/2...
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Veröffentlicht in: | Journal of rare earths 2012-12, Vol.30 (12), p.1199-1202 |
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creator | YANG, Zhiping HAN, Yue SONG, Yanchun ZHAO, Yinhong LIU, Pengfei |
description | A series of Sr3Bi1–x(PO4)3: xSm3+phosphors were prepared by solid state method at 1250 °C for 4 h. X-ray diffraction (XRD) indicated that the sample was of a pure phase of Sr3Bi(PO4)3. The main excitation peaks were located at 343 (6H5/2→4H9/2), 360 (6H5/2→4D3/2), 373 (6H5/2→6P7/2), 400 (6H5/2→4F7/2), 414 (6H5/2→6P5/2) and 467 nm (6H5/2→4I13/2). The main emission were located at 563 (4G5/2→6H5/2), 599 (4G5/2→6H7/2), 646 (4G5/2→6H9/2) and 708 nm (4G5/2→6H11/2). The intensest emission was excited by 400 nm. We studied the effect of different doping concentrations of Sm3+ activator on the luminescence properties and found that the luminescent intensity first increased with Sm3+ concentration increasing, and then decreased. The luminescent intensity had the best value when x=0.04. The chromaticity coordinates of the sample Sr3Bi0.96(PO4)3:0.04Sm3+ were (x=0.57, y=0.36), and the lifetime was 2.12 ms. |
doi_str_mv | 10.1016/S1002-0721(12)60205-1 |
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X-ray diffraction (XRD) indicated that the sample was of a pure phase of Sr3Bi(PO4)3. The main excitation peaks were located at 343 (6H5/2→4H9/2), 360 (6H5/2→4D3/2), 373 (6H5/2→6P7/2), 400 (6H5/2→4F7/2), 414 (6H5/2→6P5/2) and 467 nm (6H5/2→4I13/2). The main emission were located at 563 (4G5/2→6H5/2), 599 (4G5/2→6H7/2), 646 (4G5/2→6H9/2) and 708 nm (4G5/2→6H11/2). The intensest emission was excited by 400 nm. We studied the effect of different doping concentrations of Sm3+ activator on the luminescence properties and found that the luminescent intensity first increased with Sm3+ concentration increasing, and then decreased. The luminescent intensity had the best value when x=0.04. The chromaticity coordinates of the sample Sr3Bi0.96(PO4)3:0.04Sm3+ were (x=0.57, y=0.36), and the lifetime was 2.12 ms.</description><identifier>ISSN: 1002-0721</identifier><identifier>EISSN: 2509-4963</identifier><identifier>DOI: 10.1016/S1002-0721(12)60205-1</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Diffraction ; Emission ; Excitation ; Luminescence ; Phosphors ; photoluminescence ; Rare earth metals ; rare earths ; red-emitting phosphor ; Sr3Bi(PO4)3 ; Synthesis ; X-rays</subject><ispartof>Journal of rare earths, 2012-12, Vol.30 (12), p.1199-1202</ispartof><rights>2012 The Chinese Society of Rare Earths</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1870-1f1cd07a25aa3130c9e7fb3587e8a31ac1e3c814c901acf40b81e16950a3263</citedby><cites>FETCH-LOGICAL-c1870-1f1cd07a25aa3130c9e7fb3587e8a31ac1e3c814c901acf40b81e16950a3263</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S1002072112602051$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>YANG, Zhiping</creatorcontrib><creatorcontrib>HAN, Yue</creatorcontrib><creatorcontrib>SONG, Yanchun</creatorcontrib><creatorcontrib>ZHAO, Yinhong</creatorcontrib><creatorcontrib>LIU, Pengfei</creatorcontrib><title>Synthesis and luminescence properties of a novel red Sr3Bi(PO4)3:Sm3+ phosphor</title><title>Journal of rare earths</title><description>A series of Sr3Bi1–x(PO4)3: xSm3+phosphors were prepared by solid state method at 1250 °C for 4 h. X-ray diffraction (XRD) indicated that the sample was of a pure phase of Sr3Bi(PO4)3. The main excitation peaks were located at 343 (6H5/2→4H9/2), 360 (6H5/2→4D3/2), 373 (6H5/2→6P7/2), 400 (6H5/2→4F7/2), 414 (6H5/2→6P5/2) and 467 nm (6H5/2→4I13/2). The main emission were located at 563 (4G5/2→6H5/2), 599 (4G5/2→6H7/2), 646 (4G5/2→6H9/2) and 708 nm (4G5/2→6H11/2). The intensest emission was excited by 400 nm. We studied the effect of different doping concentrations of Sm3+ activator on the luminescence properties and found that the luminescent intensity first increased with Sm3+ concentration increasing, and then decreased. The luminescent intensity had the best value when x=0.04. The chromaticity coordinates of the sample Sr3Bi0.96(PO4)3:0.04Sm3+ were (x=0.57, y=0.36), and the lifetime was 2.12 ms.</description><subject>Diffraction</subject><subject>Emission</subject><subject>Excitation</subject><subject>Luminescence</subject><subject>Phosphors</subject><subject>photoluminescence</subject><subject>Rare earth metals</subject><subject>rare earths</subject><subject>red-emitting phosphor</subject><subject>Sr3Bi(PO4)3</subject><subject>Synthesis</subject><subject>X-rays</subject><issn>1002-0721</issn><issn>2509-4963</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNqFkFtLAzEQhYMoWKs_QchjRVZnkr36Ilq8QbHC-h7S7CyN7M2kLfTfm7biqw_DMMM5w5mPsUuEGwRMb0sEEBFkAicorlIQkER4xEYigSKKi1Qes9Gf5JSdef8FILOkgBF7L7fdakneeq67ijfr1nbkDXWG-OD6gdzKkud9zTXv-g013FHFSycf7eRjHl_Ju7KV13xY9j6UO2cntW48Xfz2MSufnz6nr9Fs_vI2fZhFBvMMIqzRVJBpkWgtUYIpKKsXMskzysNCGyRpcoxNAWGoY1jkSJgWCWgpUjlmk8PVkPB7TX6lWhsyN43uqF97hWmGscA4gyBNDlLjeu8d1WpwttVuqxDUjp7a01M7NAqF2tNTGHz3Bx-FLzaWnPLG7qhU1pFZqaq3_1z4ARZ7dKY</recordid><startdate>201212</startdate><enddate>201212</enddate><creator>YANG, Zhiping</creator><creator>HAN, Yue</creator><creator>SONG, Yanchun</creator><creator>ZHAO, Yinhong</creator><creator>LIU, Pengfei</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>201212</creationdate><title>Synthesis and luminescence properties of a novel red Sr3Bi(PO4)3:Sm3+ phosphor</title><author>YANG, Zhiping ; HAN, Yue ; SONG, Yanchun ; ZHAO, Yinhong ; LIU, Pengfei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1870-1f1cd07a25aa3130c9e7fb3587e8a31ac1e3c814c901acf40b81e16950a3263</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Diffraction</topic><topic>Emission</topic><topic>Excitation</topic><topic>Luminescence</topic><topic>Phosphors</topic><topic>photoluminescence</topic><topic>Rare earth metals</topic><topic>rare earths</topic><topic>red-emitting phosphor</topic><topic>Sr3Bi(PO4)3</topic><topic>Synthesis</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>YANG, Zhiping</creatorcontrib><creatorcontrib>HAN, Yue</creatorcontrib><creatorcontrib>SONG, Yanchun</creatorcontrib><creatorcontrib>ZHAO, Yinhong</creatorcontrib><creatorcontrib>LIU, Pengfei</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of rare earths</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>YANG, Zhiping</au><au>HAN, Yue</au><au>SONG, Yanchun</au><au>ZHAO, Yinhong</au><au>LIU, Pengfei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and luminescence properties of a novel red Sr3Bi(PO4)3:Sm3+ phosphor</atitle><jtitle>Journal of rare earths</jtitle><date>2012-12</date><risdate>2012</risdate><volume>30</volume><issue>12</issue><spage>1199</spage><epage>1202</epage><pages>1199-1202</pages><issn>1002-0721</issn><eissn>2509-4963</eissn><abstract>A series of Sr3Bi1–x(PO4)3: xSm3+phosphors were prepared by solid state method at 1250 °C for 4 h. X-ray diffraction (XRD) indicated that the sample was of a pure phase of Sr3Bi(PO4)3. The main excitation peaks were located at 343 (6H5/2→4H9/2), 360 (6H5/2→4D3/2), 373 (6H5/2→6P7/2), 400 (6H5/2→4F7/2), 414 (6H5/2→6P5/2) and 467 nm (6H5/2→4I13/2). The main emission were located at 563 (4G5/2→6H5/2), 599 (4G5/2→6H7/2), 646 (4G5/2→6H9/2) and 708 nm (4G5/2→6H11/2). The intensest emission was excited by 400 nm. We studied the effect of different doping concentrations of Sm3+ activator on the luminescence properties and found that the luminescent intensity first increased with Sm3+ concentration increasing, and then decreased. The luminescent intensity had the best value when x=0.04. The chromaticity coordinates of the sample Sr3Bi0.96(PO4)3:0.04Sm3+ were (x=0.57, y=0.36), and the lifetime was 2.12 ms.</abstract><pub>Elsevier B.V</pub><doi>10.1016/S1002-0721(12)60205-1</doi><tpages>4</tpages></addata></record> |
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subjects | Diffraction Emission Excitation Luminescence Phosphors photoluminescence Rare earth metals rare earths red-emitting phosphor Sr3Bi(PO4)3 Synthesis X-rays |
title | Synthesis and luminescence properties of a novel red Sr3Bi(PO4)3:Sm3+ phosphor |
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