Lithium polymer battery with high energy density

Polymer cathode materials based on organosulfur compounds are developed for lithium rechargeable batteries with high energy density. Making a well‐mixed composite with a conducting polymer polyaniline (PAn) accelerates slow redox reactions of organosulfur compounds such as 2,5‐dimercapto‐1,3,4‐thiad...

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Veröffentlicht in:Macromolecular symposia. 2000-07, Vol.156 (1), p.171-178
Hauptverfasser: Oyama, Noboru, Hatozaki, Osamu
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Hatozaki, Osamu
description Polymer cathode materials based on organosulfur compounds are developed for lithium rechargeable batteries with high energy density. Making a well‐mixed composite with a conducting polymer polyaniline (PAn) accelerates slow redox reactions of organosulfur compounds such as 2,5‐dimercapto‐1,3,4‐thiadiazole (DMcT). Using a copper cathode current collector, battery performances of the DMcT/PAn composite cathode are significantly improved due to a formation of a complex between DMcT and a copper ion: discharge capacity exceeding 225 Ah/kg‐cathode and cyclability more than 500 charge‐discharge cycles being achieved. Furthermore, addition of elemental sulfur (S8) to the composite further augments the discharge capacity of the composite cathode to more than 500 Ah/kg‐cathode.
doi_str_mv 10.1002/1521-3900(200007)156:1<171::AID-MASY171>3.0.CO;2-2
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subjects Battery
Cathodes
Conducting polymers
Copper
Discharge
Electric batteries
Energy density
Lithium
title Lithium polymer battery with high energy density
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