Microwave-assisted synthesis of TiO2-reduced graphene oxide composites for the photocatalytic reduction of Cr(vi)

TiO 2 -reduced graphene oxide (RGO) composites are successfully synthesized via the microwave-assisted reduction of graphite oxide in a TiO 2 suspension using a microwave synthesis system. Their morphology, structure and photocatalytic performance in the reduction of Cr( vi ) are characterized by sc...

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Veröffentlicht in:RSC advances 2011-01, Vol.1 (7), p.1245-1249
Hauptverfasser: Liu, Xinjuan, Pan, Likun, Lv, Tian, Zhu, Guang, Lu, Ting, Sun, Zhuo, Sun, Changqing
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Sprache:eng
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Zusammenfassung:TiO 2 -reduced graphene oxide (RGO) composites are successfully synthesized via the microwave-assisted reduction of graphite oxide in a TiO 2 suspension using a microwave synthesis system. Their morphology, structure and photocatalytic performance in the reduction of Cr( vi ) are characterized by scanning electron microscopy, transmission electron microscopy, atomic force microscopy, X-ray diffraction spectroscopy and UV-vis absorption spectrophotometer. The results show that in the composite the RGO nanosheets are densely decorated by TiO 2 nanoparticles, which displays a good combination between RGO and TiO 2 . TiO 2 -RGO composites exhibit enhanced photocatalytic performance for the reduction of Cr( vi ) with a maximum removal rate of 91% under UV light irradiation as compared with pure TiO 2 (83%) and commercial TiO 2 P25 (70%) due to the increased light absorption intensity and range as well as the reduction of electron-hole pair recombination in TiO 2 with the introduction of RGO. TiO 2 -reduced graphene oxide is synthesized using a microwave-assisted reaction for the UV photocatalytic reduction of Cr( vi ) with a high removal rate.
ISSN:2046-2069
2046-2069
DOI:10.1039/c1ra00298h