Effect of SiC and Al2O3 particles on the electrodeposition of Zn, Co and ZnCo: II. Electrodeposition in the presence of SiC and Al2O3 and production of ZnCo–SiC and ZnCo–Al2O3 coatings

SiC or Al 2 O 3 microsized particles were added to acid sulfate-based solutions for the electrodeposition of Zn, Co, and ZnCo. Initially, their effects on the electrochemical processes were evaluated. The Zn electrodeposition rate was increased in both SiC and Al 2 O 3 -loaded solutions. The Co elec...

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Veröffentlicht in:Journal of applied electrochemistry 2009-08, Vol.39 (8), p.1305-1311
Hauptverfasser: Tulio, Paulo C., Carlos, Ivani A.
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description SiC or Al 2 O 3 microsized particles were added to acid sulfate-based solutions for the electrodeposition of Zn, Co, and ZnCo. Initially, their effects on the electrochemical processes were evaluated. The Zn electrodeposition rate was increased in both SiC and Al 2 O 3 -loaded solutions. The Co electrodeposition rate was also increased by SiC. However, Al 2 O 3 decreased it, especially at the beginning. Both SiC and Al 2 O 3 influenced the electrodeposition of ZnCo positively at moderate loadings. The factors involved in producing ZnCo–SiC and ZnCo–Al 2 O 3 composites were evaluated. ZnCo–SiC composites could be deposited with a higher [Co/Zn] ratio in the metal matrix than for pure ZnCo. In ZnCo–Al 2 O 3 , the [Co/Zn] ratio was smaller than in ZnCo and ZnCo–SiC. It was necessary to reduce the CoSO 4 concentration to improve the Al 2 O 3 co-deposition. The variation in [Co/Zn] ratio could, in principle, be related to the effects of SiC and Al 2 O 3 on the individual Zn and Co electrodeposition.
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Electrodeposition in the presence of SiC and Al2O3 and production of ZnCo–SiC and ZnCo–Al2O3 coatings</title><source>SpringerNature Journals</source><creator>Tulio, Paulo C. ; Carlos, Ivani A.</creator><creatorcontrib>Tulio, Paulo C. ; Carlos, Ivani A.</creatorcontrib><description>SiC or Al 2 O 3 microsized particles were added to acid sulfate-based solutions for the electrodeposition of Zn, Co, and ZnCo. Initially, their effects on the electrochemical processes were evaluated. The Zn electrodeposition rate was increased in both SiC and Al 2 O 3 -loaded solutions. The Co electrodeposition rate was also increased by SiC. However, Al 2 O 3 decreased it, especially at the beginning. Both SiC and Al 2 O 3 influenced the electrodeposition of ZnCo positively at moderate loadings. The factors involved in producing ZnCo–SiC and ZnCo–Al 2 O 3 composites were evaluated. ZnCo–SiC composites could be deposited with a higher [Co/Zn] ratio in the metal matrix than for pure ZnCo. In ZnCo–Al 2 O 3 , the [Co/Zn] ratio was smaller than in ZnCo and ZnCo–SiC. It was necessary to reduce the CoSO 4 concentration to improve the Al 2 O 3 co-deposition. 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It was necessary to reduce the CoSO 4 concentration to improve the Al 2 O 3 co-deposition. The variation in [Co/Zn] ratio could, in principle, be related to the effects of SiC and Al 2 O 3 on the individual Zn and Co electrodeposition.</description><subject>Aluminum oxide</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coatings</subject><subject>Deposition</subject><subject>Electrochemistry</subject><subject>Electrodeposition</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Original Paper</subject><subject>Particulate composites</subject><subject>Physical Chemistry</subject><subject>Silicon carbide</subject><subject>Zinc</subject><issn>0021-891X</issn><issn>1572-8838</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNp9kT1OwzAYhi0EEqVwADaPDKT4ixPHZquiApUqdQAk1MVKHaekSu1gpwMbd-A6nIaT4JIiBiQm_-h5Xv-8CJ0DGQEh2ZUHwgmJCBGR4IRG_AANIM3iiHPKD9GAkBgiLuDpGJ14vyYBjFkyQB-TqtKqw7bC93WOC1PicRPPKW4L19Wq0R5bg7tnjXUTOGdL3Vpfd3XYDc7CXOLcfmsLk9trPJ2O8OQPWfcRrdNeG6X_nrabtUHZqt_k3H6-vf9g-2VPK1t0tVn5U3RUFY3XZ_txiB5vJg_5XTSb307z8SxScQpdVFQsFZzqKiElcAJZpQD4kvJMpSKhUAiSLCEWTAnGE87SlGecsTiBlC5pyegQXfS54YovW-07uam90k1TGG23XgLLIAkfnIqAQo8qZ713upKtqzeFe5VA5K4p2TclQwFy15TkwYl7xwfWrLSTa7t1JrzoH-kLi-CVtA</recordid><startdate>20090801</startdate><enddate>20090801</enddate><creator>Tulio, Paulo C.</creator><creator>Carlos, Ivani A.</creator><general>Springer Netherlands</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QQ</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20090801</creationdate><title>Effect of SiC and Al2O3 particles on the electrodeposition of Zn, Co and ZnCo: II. 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Electrodeposition in the presence of SiC and Al2O3 and production of ZnCo–SiC and ZnCo–Al2O3 coatings</atitle><jtitle>Journal of applied electrochemistry</jtitle><stitle>J Appl Electrochem</stitle><date>2009-08-01</date><risdate>2009</risdate><volume>39</volume><issue>8</issue><spage>1305</spage><epage>1311</epage><pages>1305-1311</pages><issn>0021-891X</issn><eissn>1572-8838</eissn><abstract>SiC or Al 2 O 3 microsized particles were added to acid sulfate-based solutions for the electrodeposition of Zn, Co, and ZnCo. Initially, their effects on the electrochemical processes were evaluated. The Zn electrodeposition rate was increased in both SiC and Al 2 O 3 -loaded solutions. The Co electrodeposition rate was also increased by SiC. However, Al 2 O 3 decreased it, especially at the beginning. Both SiC and Al 2 O 3 influenced the electrodeposition of ZnCo positively at moderate loadings. The factors involved in producing ZnCo–SiC and ZnCo–Al 2 O 3 composites were evaluated. ZnCo–SiC composites could be deposited with a higher [Co/Zn] ratio in the metal matrix than for pure ZnCo. In ZnCo–Al 2 O 3 , the [Co/Zn] ratio was smaller than in ZnCo and ZnCo–SiC. It was necessary to reduce the CoSO 4 concentration to improve the Al 2 O 3 co-deposition. The variation in [Co/Zn] ratio could, in principle, be related to the effects of SiC and Al 2 O 3 on the individual Zn and Co electrodeposition.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10800-009-9803-8</doi><tpages>7</tpages></addata></record>
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subjects Aluminum oxide
Chemistry
Chemistry and Materials Science
Coatings
Deposition
Electrochemistry
Electrodeposition
Industrial Chemistry/Chemical Engineering
Original Paper
Particulate composites
Physical Chemistry
Silicon carbide
Zinc
title Effect of SiC and Al2O3 particles on the electrodeposition of Zn, Co and ZnCo: II. Electrodeposition in the presence of SiC and Al2O3 and production of ZnCo–SiC and ZnCo–Al2O3 coatings
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