EPR study of nanocrystalline tin dioxide
We have detected that O2‐ and OH• radicals are the main type of spin centers in nanocrystalline tin dioxide. Their integral concentrations increase proportionally to a growth of specific surface in the investigated samples. Concentration of OH• radicals increases after sample treatment in water vapo...
Gespeichert in:
| Veröffentlicht in: | Physica status solidi. C 2011-06, Vol.8 (6), p.1957-1960 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1960 |
|---|---|
| container_issue | 6 |
| container_start_page | 1957 |
| container_title | Physica status solidi. C |
| container_volume | 8 |
| creator | Konstantinova, E. A. Pentegov, I. S. Marikutsa, A. V. Rumyantseva, M. N. Gaskov, A. M. Kashkarov, P. K. |
| description | We have detected that O2‐ and OH• radicals are the main type of spin centers in nanocrystalline tin dioxide. Their integral concentrations increase proportionally to a growth of specific surface in the investigated samples. Concentration of OH• radicals increases after sample treatment in water vapour. Concentration decrease of O2‐ radicals is provided through the surface modification of tin dioxide with palladium and additionally water molecules, that is probably due to the formation of PdO‐layer on the surface of the samples. It is shown that the SnO2/Pd samples have promising sensor properties. (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) |
| doi_str_mv | 10.1002/pssc.201000140 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1671398674</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1671398674</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3600-f1c0d0f2151cb2bdc02288edd25e7378672daaaf185e756537305c130c4135933</originalsourceid><addsrcrecordid>eNqFkMFLwzAYxYMoOKdXzz3u0vl9SZN2Rx3bFKYOp3gMWZJCtGtn0-L635tRGd48fe-D93vwHiHXCGMEoDc77_WYQtCACZyQAQqEGEVCT4POBI0F43hOLrz_AGAcUAzIaLZ6iXzTmi6q8qhUZaXrzjeqKFxpo8aVkXHV3hl7Sc5yVXh79XuH5G0-e53ex8vnxcP0dhlrJgDiHDUYyCly1Bu6MRoozTJrDOU2ZWkmUmqUUjlm4eeCs5QB18hAJ8j4hLEhGfW5u7r6aq1v5NZ5bYtClbZqvUSRIpuEnCRYx71V15X3tc3lrnZbVXcSQR4mkYdJ5HGSAEx64NsVtvvHLVfr9fQvG_es843dH1lVf0oRinH5_rSQTNwt-XzO5CP7ASxzcik</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1671398674</pqid></control><display><type>article</type><title>EPR study of nanocrystalline tin dioxide</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Konstantinova, E. A. ; Pentegov, I. S. ; Marikutsa, A. V. ; Rumyantseva, M. N. ; Gaskov, A. M. ; Kashkarov, P. K.</creator><creatorcontrib>Konstantinova, E. A. ; Pentegov, I. S. ; Marikutsa, A. V. ; Rumyantseva, M. N. ; Gaskov, A. M. ; Kashkarov, P. K.</creatorcontrib><description>We have detected that O2‐ and OH• radicals are the main type of spin centers in nanocrystalline tin dioxide. Their integral concentrations increase proportionally to a growth of specific surface in the investigated samples. Concentration of OH• radicals increases after sample treatment in water vapour. Concentration decrease of O2‐ radicals is provided through the surface modification of tin dioxide with palladium and additionally water molecules, that is probably due to the formation of PdO‐layer on the surface of the samples. It is shown that the SnO2/Pd samples have promising sensor properties. (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)</description><identifier>ISSN: 1862-6351</identifier><identifier>ISSN: 1610-1642</identifier><identifier>EISSN: 1610-1642</identifier><identifier>DOI: 10.1002/pssc.201000140</identifier><language>eng</language><publisher>Berlin: WILEY-VCH Verlag</publisher><subject>electron paramagnetic resonance ; Integrals ; Nanocrystals ; Palladium ; Radicals ; sensor ; Solid state physics ; spin centers ; Tin dioxide ; Tin oxides ; Vapour</subject><ispartof>Physica status solidi. C, 2011-06, Vol.8 (6), p.1957-1960</ispartof><rights>Copyright © 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3600-f1c0d0f2151cb2bdc02288edd25e7378672daaaf185e756537305c130c4135933</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpssc.201000140$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpssc.201000140$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Konstantinova, E. A.</creatorcontrib><creatorcontrib>Pentegov, I. S.</creatorcontrib><creatorcontrib>Marikutsa, A. V.</creatorcontrib><creatorcontrib>Rumyantseva, M. N.</creatorcontrib><creatorcontrib>Gaskov, A. M.</creatorcontrib><creatorcontrib>Kashkarov, P. K.</creatorcontrib><title>EPR study of nanocrystalline tin dioxide</title><title>Physica status solidi. C</title><addtitle>Phys. Status Solidi C</addtitle><description>We have detected that O2‐ and OH• radicals are the main type of spin centers in nanocrystalline tin dioxide. Their integral concentrations increase proportionally to a growth of specific surface in the investigated samples. Concentration of OH• radicals increases after sample treatment in water vapour. Concentration decrease of O2‐ radicals is provided through the surface modification of tin dioxide with palladium and additionally water molecules, that is probably due to the formation of PdO‐layer on the surface of the samples. It is shown that the SnO2/Pd samples have promising sensor properties. (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)</description><subject>electron paramagnetic resonance</subject><subject>Integrals</subject><subject>Nanocrystals</subject><subject>Palladium</subject><subject>Radicals</subject><subject>sensor</subject><subject>Solid state physics</subject><subject>spin centers</subject><subject>Tin dioxide</subject><subject>Tin oxides</subject><subject>Vapour</subject><issn>1862-6351</issn><issn>1610-1642</issn><issn>1610-1642</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkMFLwzAYxYMoOKdXzz3u0vl9SZN2Rx3bFKYOp3gMWZJCtGtn0-L635tRGd48fe-D93vwHiHXCGMEoDc77_WYQtCACZyQAQqEGEVCT4POBI0F43hOLrz_AGAcUAzIaLZ6iXzTmi6q8qhUZaXrzjeqKFxpo8aVkXHV3hl7Sc5yVXh79XuH5G0-e53ex8vnxcP0dhlrJgDiHDUYyCly1Bu6MRoozTJrDOU2ZWkmUmqUUjlm4eeCs5QB18hAJ8j4hLEhGfW5u7r6aq1v5NZ5bYtClbZqvUSRIpuEnCRYx71V15X3tc3lrnZbVXcSQR4mkYdJ5HGSAEx64NsVtvvHLVfr9fQvG_es843dH1lVf0oRinH5_rSQTNwt-XzO5CP7ASxzcik</recordid><startdate>201106</startdate><enddate>201106</enddate><creator>Konstantinova, E. A.</creator><creator>Pentegov, I. S.</creator><creator>Marikutsa, A. V.</creator><creator>Rumyantseva, M. N.</creator><creator>Gaskov, A. M.</creator><creator>Kashkarov, P. K.</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope></search><sort><creationdate>201106</creationdate><title>EPR study of nanocrystalline tin dioxide</title><author>Konstantinova, E. A. ; Pentegov, I. S. ; Marikutsa, A. V. ; Rumyantseva, M. N. ; Gaskov, A. M. ; Kashkarov, P. K.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3600-f1c0d0f2151cb2bdc02288edd25e7378672daaaf185e756537305c130c4135933</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>electron paramagnetic resonance</topic><topic>Integrals</topic><topic>Nanocrystals</topic><topic>Palladium</topic><topic>Radicals</topic><topic>sensor</topic><topic>Solid state physics</topic><topic>spin centers</topic><topic>Tin dioxide</topic><topic>Tin oxides</topic><topic>Vapour</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Konstantinova, E. A.</creatorcontrib><creatorcontrib>Pentegov, I. S.</creatorcontrib><creatorcontrib>Marikutsa, A. V.</creatorcontrib><creatorcontrib>Rumyantseva, M. N.</creatorcontrib><creatorcontrib>Gaskov, A. M.</creatorcontrib><creatorcontrib>Kashkarov, P. K.</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Physica status solidi. C</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Konstantinova, E. A.</au><au>Pentegov, I. S.</au><au>Marikutsa, A. V.</au><au>Rumyantseva, M. N.</au><au>Gaskov, A. M.</au><au>Kashkarov, P. K.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>EPR study of nanocrystalline tin dioxide</atitle><jtitle>Physica status solidi. C</jtitle><addtitle>Phys. Status Solidi C</addtitle><date>2011-06</date><risdate>2011</risdate><volume>8</volume><issue>6</issue><spage>1957</spage><epage>1960</epage><pages>1957-1960</pages><issn>1862-6351</issn><issn>1610-1642</issn><eissn>1610-1642</eissn><abstract>We have detected that O2‐ and OH• radicals are the main type of spin centers in nanocrystalline tin dioxide. Their integral concentrations increase proportionally to a growth of specific surface in the investigated samples. Concentration of OH• radicals increases after sample treatment in water vapour. Concentration decrease of O2‐ radicals is provided through the surface modification of tin dioxide with palladium and additionally water molecules, that is probably due to the formation of PdO‐layer on the surface of the samples. It is shown that the SnO2/Pd samples have promising sensor properties. (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)</abstract><cop>Berlin</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/pssc.201000140</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1862-6351 |
| ispartof | Physica status solidi. C, 2011-06, Vol.8 (6), p.1957-1960 |
| issn | 1862-6351 1610-1642 1610-1642 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1671398674 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | electron paramagnetic resonance Integrals Nanocrystals Palladium Radicals sensor Solid state physics spin centers Tin dioxide Tin oxides Vapour |
| title | EPR study of nanocrystalline tin dioxide |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-20T15%3A37%3A21IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=EPR%20study%20of%20nanocrystalline%20tin%20dioxide&rft.jtitle=Physica%20status%20solidi.%20C&rft.au=Konstantinova,%20E.%20A.&rft.date=2011-06&rft.volume=8&rft.issue=6&rft.spage=1957&rft.epage=1960&rft.pages=1957-1960&rft.issn=1862-6351&rft.eissn=1610-1642&rft_id=info:doi/10.1002/pssc.201000140&rft_dat=%3Cproquest_cross%3E1671398674%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1671398674&rft_id=info:pmid/&rfr_iscdi=true |