The potential for ionic liquid electrolytes to stabilise the magnesium interface for magnesium/air batteries
Magnesium/air batteries are a possible high-energy density power source that, to date, have not received strong commercial interest due to issues with the corrosion of the magnesium and evaporation of the electrolyte. In this work we report on the use of ionic liquid based electrolytes to stabilise...
Gespeichert in:
| Veröffentlicht in: | Electrochimica acta 2011-12, Vol.58, p.583-588 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 588 |
|---|---|
| container_issue | |
| container_start_page | 583 |
| container_title | Electrochimica acta |
| container_volume | 58 |
| creator | Khoo, Timothy Howlett, Patrick C. Tsagouria, Maureen MacFarlane, Douglas R. Forsyth, Maria |
| description | Magnesium/air batteries are a possible high-energy density power source that, to date, have not received strong commercial interest due to issues with the corrosion of the magnesium and evaporation of the electrolyte. In this work we report on the use of ionic liquid based electrolytes to stabilise the metal/electrolyte interface and their impact on the electrochemical performance. Galvanostatic measurements indicate that the water content of the ionic liquid electrolyte plays an important role in the cell discharge characteristics. Surface characterisation using EIS, ATR-FTIR and powder diffraction examined the unique properties of the surface film formed on the magnesium anode. |
| doi_str_mv | 10.1016/j.electacta.2011.10.006 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1671394514</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0013468611014952</els_id><sourcerecordid>1671394514</sourcerecordid><originalsourceid>FETCH-LOGICAL-c378t-27997264ed5c5f18fb569a84657f49bc25f4196125b17b8448193038c47ef91f3</originalsourceid><addsrcrecordid>eNqFUEtrGzEQFqWBukl-Q3Up9LKOtHqtjiH0BYFckrPQyqN0jLxyJLmQf185Dr4WBgbmezEfIV84W3PG9c12DQlC833WI-O8X9eM6Q9kxScjBjEp-5GsGONikHrSn8jnWreMMaMNW5H0-AfoPjdYGvpEYy4U84KBJnw54Ia-eZecXhtU2jKtzc-YsAJtXbjzzwtUPOwoLg1K9AHeLM73G4-Fzr51EKFekYvoU4Xr931Jnn58f7z7Ndw__Px9d3s_BGGmNozGWjNqCRsVVORTnJW2fpJamSjtHEYVJbeaj2rmZp6knLgVTExBGoiWR3FJvp189yW_HKA2t8MaICW_QD5Ux7XhwkrFZaeaEzWUXGuB6PYFd768Os7csV-3ded-3bHfI9D77cqv7yG-Bp9i8UvAepaParRCi2PC7YkH_eO_CMXVgLAE2GDpvm6T8b9Z_wDXfJYB</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1671394514</pqid></control><display><type>article</type><title>The potential for ionic liquid electrolytes to stabilise the magnesium interface for magnesium/air batteries</title><source>Elsevier ScienceDirect Journals</source><creator>Khoo, Timothy ; Howlett, Patrick C. ; Tsagouria, Maureen ; MacFarlane, Douglas R. ; Forsyth, Maria</creator><creatorcontrib>Khoo, Timothy ; Howlett, Patrick C. ; Tsagouria, Maureen ; MacFarlane, Douglas R. ; Forsyth, Maria</creatorcontrib><description>Magnesium/air batteries are a possible high-energy density power source that, to date, have not received strong commercial interest due to issues with the corrosion of the magnesium and evaporation of the electrolyte. In this work we report on the use of ionic liquid based electrolytes to stabilise the metal/electrolyte interface and their impact on the electrochemical performance. Galvanostatic measurements indicate that the water content of the ionic liquid electrolyte plays an important role in the cell discharge characteristics. Surface characterisation using EIS, ATR-FTIR and powder diffraction examined the unique properties of the surface film formed on the magnesium anode.</description><identifier>ISSN: 0013-4686</identifier><identifier>EISSN: 1873-3859</identifier><identifier>DOI: 10.1016/j.electacta.2011.10.006</identifier><identifier>CODEN: ELCAAV</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Air batteries ; Applied sciences ; Density ; Diffraction ; Direct energy conversion and energy accumulation ; Electrical engineering. Electrical power engineering ; Electrical power engineering ; Electrochemical conversion: primary and secondary batteries, fuel cells ; Electrolyte ; Electrolytes ; Evaporation ; Exact sciences and technology ; Interface ; Ionic liquid ; Ionic liquids ; Magnesium ; Magnesium battery ; Moisture content</subject><ispartof>Electrochimica acta, 2011-12, Vol.58, p.583-588</ispartof><rights>2011 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c378t-27997264ed5c5f18fb569a84657f49bc25f4196125b17b8448193038c47ef91f3</citedby><cites>FETCH-LOGICAL-c378t-27997264ed5c5f18fb569a84657f49bc25f4196125b17b8448193038c47ef91f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0013468611014952$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=25293634$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Khoo, Timothy</creatorcontrib><creatorcontrib>Howlett, Patrick C.</creatorcontrib><creatorcontrib>Tsagouria, Maureen</creatorcontrib><creatorcontrib>MacFarlane, Douglas R.</creatorcontrib><creatorcontrib>Forsyth, Maria</creatorcontrib><title>The potential for ionic liquid electrolytes to stabilise the magnesium interface for magnesium/air batteries</title><title>Electrochimica acta</title><description>Magnesium/air batteries are a possible high-energy density power source that, to date, have not received strong commercial interest due to issues with the corrosion of the magnesium and evaporation of the electrolyte. In this work we report on the use of ionic liquid based electrolytes to stabilise the metal/electrolyte interface and their impact on the electrochemical performance. Galvanostatic measurements indicate that the water content of the ionic liquid electrolyte plays an important role in the cell discharge characteristics. Surface characterisation using EIS, ATR-FTIR and powder diffraction examined the unique properties of the surface film formed on the magnesium anode.</description><subject>Air batteries</subject><subject>Applied sciences</subject><subject>Density</subject><subject>Diffraction</subject><subject>Direct energy conversion and energy accumulation</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Electrical power engineering</subject><subject>Electrochemical conversion: primary and secondary batteries, fuel cells</subject><subject>Electrolyte</subject><subject>Electrolytes</subject><subject>Evaporation</subject><subject>Exact sciences and technology</subject><subject>Interface</subject><subject>Ionic liquid</subject><subject>Ionic liquids</subject><subject>Magnesium</subject><subject>Magnesium battery</subject><subject>Moisture content</subject><issn>0013-4686</issn><issn>1873-3859</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFUEtrGzEQFqWBukl-Q3Up9LKOtHqtjiH0BYFckrPQyqN0jLxyJLmQf185Dr4WBgbmezEfIV84W3PG9c12DQlC833WI-O8X9eM6Q9kxScjBjEp-5GsGONikHrSn8jnWreMMaMNW5H0-AfoPjdYGvpEYy4U84KBJnw54Ia-eZecXhtU2jKtzc-YsAJtXbjzzwtUPOwoLg1K9AHeLM73G4-Fzr51EKFekYvoU4Xr931Jnn58f7z7Ndw__Px9d3s_BGGmNozGWjNqCRsVVORTnJW2fpJamSjtHEYVJbeaj2rmZp6knLgVTExBGoiWR3FJvp189yW_HKA2t8MaICW_QD5Ux7XhwkrFZaeaEzWUXGuB6PYFd768Os7csV-3ded-3bHfI9D77cqv7yG-Bp9i8UvAepaParRCi2PC7YkH_eO_CMXVgLAE2GDpvm6T8b9Z_wDXfJYB</recordid><startdate>20111230</startdate><enddate>20111230</enddate><creator>Khoo, Timothy</creator><creator>Howlett, Patrick C.</creator><creator>Tsagouria, Maureen</creator><creator>MacFarlane, Douglas R.</creator><creator>Forsyth, Maria</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7SE</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20111230</creationdate><title>The potential for ionic liquid electrolytes to stabilise the magnesium interface for magnesium/air batteries</title><author>Khoo, Timothy ; Howlett, Patrick C. ; Tsagouria, Maureen ; MacFarlane, Douglas R. ; Forsyth, Maria</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c378t-27997264ed5c5f18fb569a84657f49bc25f4196125b17b8448193038c47ef91f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Air batteries</topic><topic>Applied sciences</topic><topic>Density</topic><topic>Diffraction</topic><topic>Direct energy conversion and energy accumulation</topic><topic>Electrical engineering. Electrical power engineering</topic><topic>Electrical power engineering</topic><topic>Electrochemical conversion: primary and secondary batteries, fuel cells</topic><topic>Electrolyte</topic><topic>Electrolytes</topic><topic>Evaporation</topic><topic>Exact sciences and technology</topic><topic>Interface</topic><topic>Ionic liquid</topic><topic>Ionic liquids</topic><topic>Magnesium</topic><topic>Magnesium battery</topic><topic>Moisture content</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Khoo, Timothy</creatorcontrib><creatorcontrib>Howlett, Patrick C.</creatorcontrib><creatorcontrib>Tsagouria, Maureen</creatorcontrib><creatorcontrib>MacFarlane, Douglas R.</creatorcontrib><creatorcontrib>Forsyth, Maria</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Electrochimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Khoo, Timothy</au><au>Howlett, Patrick C.</au><au>Tsagouria, Maureen</au><au>MacFarlane, Douglas R.</au><au>Forsyth, Maria</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The potential for ionic liquid electrolytes to stabilise the magnesium interface for magnesium/air batteries</atitle><jtitle>Electrochimica acta</jtitle><date>2011-12-30</date><risdate>2011</risdate><volume>58</volume><spage>583</spage><epage>588</epage><pages>583-588</pages><issn>0013-4686</issn><eissn>1873-3859</eissn><coden>ELCAAV</coden><abstract>Magnesium/air batteries are a possible high-energy density power source that, to date, have not received strong commercial interest due to issues with the corrosion of the magnesium and evaporation of the electrolyte. In this work we report on the use of ionic liquid based electrolytes to stabilise the metal/electrolyte interface and their impact on the electrochemical performance. Galvanostatic measurements indicate that the water content of the ionic liquid electrolyte plays an important role in the cell discharge characteristics. Surface characterisation using EIS, ATR-FTIR and powder diffraction examined the unique properties of the surface film formed on the magnesium anode.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.electacta.2011.10.006</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0013-4686 |
| ispartof | Electrochimica acta, 2011-12, Vol.58, p.583-588 |
| issn | 0013-4686 1873-3859 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1671394514 |
| source | Elsevier ScienceDirect Journals |
| subjects | Air batteries Applied sciences Density Diffraction Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Electrolyte Electrolytes Evaporation Exact sciences and technology Interface Ionic liquid Ionic liquids Magnesium Magnesium battery Moisture content |
| title | The potential for ionic liquid electrolytes to stabilise the magnesium interface for magnesium/air batteries |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-08T11%3A27%3A19IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=The%20potential%20for%20ionic%20liquid%20electrolytes%20to%20stabilise%20the%20magnesium%20interface%20for%20magnesium/air%20batteries&rft.jtitle=Electrochimica%20acta&rft.au=Khoo,%20Timothy&rft.date=2011-12-30&rft.volume=58&rft.spage=583&rft.epage=588&rft.pages=583-588&rft.issn=0013-4686&rft.eissn=1873-3859&rft.coden=ELCAAV&rft_id=info:doi/10.1016/j.electacta.2011.10.006&rft_dat=%3Cproquest_cross%3E1671394514%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1671394514&rft_id=info:pmid/&rft_els_id=S0013468611014952&rfr_iscdi=true |