Solid-state 13C NMR analyses of the structures of crystallized and quenched poly(lactide)s: Effects of crystallinity, water absorption, hydrolytic degradation, and tacticity

The effects of crystallinity, water absorption, hydrolytic degradation, and tacticity on the solid structure and chain mobility of poly(lactide)s were investigated by solid-state 13C NMR spectroscopy. The following results were obtained from the line shapes of the carbonyl and methine carbons in 13C...

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Veröffentlicht in:Polymer (Guilford) 2010-05, Vol.51 (10), p.2215-2220
Hauptverfasser: Tsuji, Hideto, Kamo, Sachie, Horii, Fumitaka
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Sprache:eng
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