Effects of Ti addition to Sn–Ag and Sn–Cu solders

► Ti additions to Sn–Cu and Sn–Ag solders can effectively reduce the undercooling. ► Increasing the cooling rate will increase the hardness of Ti-added solders. ► Ti2Sn3 networks stabilize the morphology of β-Sn even in a severe aging condition. ► The orientation distribution of β-Sn can be preserve...

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Veröffentlicht in:Journal of alloys and compounds 2012-04, Vol.520, p.244-249
Hauptverfasser: Chen, W.M., Kang, S.K., Kao, C.R.
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container_title Journal of alloys and compounds
container_volume 520
creator Chen, W.M.
Kang, S.K.
Kao, C.R.
description ► Ti additions to Sn–Cu and Sn–Ag solders can effectively reduce the undercooling. ► Increasing the cooling rate will increase the hardness of Ti-added solders. ► Ti2Sn3 networks stabilize the morphology of β-Sn even in a severe aging condition. ► The orientation distribution of β-Sn can be preserved after a minor addition of Ti. ► Ti-added solder may be a superior candidate for enhanced electromigration resistance. Minor alloying addition to solders has been an important strategy to improve the integrity and reliability of Pb-free solder joints. In this study, a small amount of Ti was added to Sn–Cu and Sn–Ag solders, and their microstructures, solidification behaviors, mechanical properties, and high temperature aging characteristics were investigated. Thermal analysis confirmed Ti addition being very effective in reducing the undercooling. Correlations between cooling rates, microstructure, and microhardness were established. One pronounced feature of Ti addition was that Ti-added solders had microstructures very stable against extreme aging conditions.
doi_str_mv 10.1016/j.jallcom.2012.01.032
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subjects Alloying
Alloys
Applied sciences
Brazing. Soldering
Correlation
Exact sciences and technology
Joining, thermal cutting: metallurgical aspects
Metals. Metallurgy
Microstructure
Minor alloying elements
Pb-free solders
Solders
Supercooling
Ti addition
Tin
Titanium
title Effects of Ti addition to Sn–Ag and Sn–Cu solders
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