Sol–gel processed Cu2ZnSnS4 thin films for a photovoltaic absorber layer without sulfurization
Sol–gel processed Cu 2 ZnSnS 4 (CZTS) thin films were fabricated without sulfurization for application as a photovoltaic absorber layer. The precursor solution was made from CuCl 2 , Zn(ac) 2 , SnCl 2 , thiourea, and 2-methoxyethanol and the spin-coated film was annealed at temperature above 500 °C...
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| Veröffentlicht in: | Journal of sol-gel science and technology 2013, Vol.65 (1), p.23-27 |
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| container_title | Journal of sol-gel science and technology |
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| creator | Park, Hyungjin Hwang, Young Hwan Bae, Byeong-Soo |
| description | Sol–gel processed Cu
2
ZnSnS
4
(CZTS) thin films were fabricated without sulfurization for application as a photovoltaic absorber layer. The precursor solution was made from CuCl
2
, Zn(ac)
2
, SnCl
2
, thiourea, and 2-methoxyethanol and the spin-coated film was annealed at temperature above 500 °C under a N
2
atmosphere. A homogeneous and compositionally uniform film with single CZTS phase was obtained. Film composition featuring larger grains, which is desirable in photovoltaic cells, was obtained with heat treatment at 540 °C. The grain size was up to 1 μm and the Cu/(Zn + Sn) and Zn/Sn ratios were 0.93 and 1.07, respectively and the band gap energy was 1.56 eV. |
| doi_str_mv | 10.1007/s10971-012-2703-0 |
| format | Article |
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2
ZnSnS
4
(CZTS) thin films were fabricated without sulfurization for application as a photovoltaic absorber layer. The precursor solution was made from CuCl
2
, Zn(ac)
2
, SnCl
2
, thiourea, and 2-methoxyethanol and the spin-coated film was annealed at temperature above 500 °C under a N
2
atmosphere. A homogeneous and compositionally uniform film with single CZTS phase was obtained. Film composition featuring larger grains, which is desirable in photovoltaic cells, was obtained with heat treatment at 540 °C. The grain size was up to 1 μm and the Cu/(Zn + Sn) and Zn/Sn ratios were 0.93 and 1.07, respectively and the band gap energy was 1.56 eV.</description><identifier>ISSN: 0928-0707</identifier><identifier>EISSN: 1573-4846</identifier><identifier>DOI: 10.1007/s10971-012-2703-0</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Absorbers ; Ceramics ; Chemistry ; Chemistry and Materials Science ; Colloidal gels. Colloidal sols ; Colloidal state and disperse state ; Composites ; Copper ; Copper zinc tin sulfide ; CZT ; Energy gap ; Exact sciences and technology ; General and physical chemistry ; Glass ; Grain size ; Heat treatment ; Inorganic Chemistry ; Materials Science ; Methyl cellosolve ; Nanotechnology ; Natural Materials ; Optical and Electronic Materials ; Original Paper ; Photovoltaic cells ; Sol-gel processes ; Solar cells ; Spin coating ; Sulfurization ; Thin films ; Tin ; Zinc</subject><ispartof>Journal of sol-gel science and technology, 2013, Vol.65 (1), p.23-27</ispartof><rights>Springer Science+Business Media, LLC 2012</rights><rights>2014 INIST-CNRS</rights><rights>Journal of Sol-Gel Science and Technology is a copyright of Springer, (2012). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c453t-e5af1a7d69c7175ed7b25fc7039575cbe7e7b23c18faba9f9d66631dc6d859ee3</citedby><cites>FETCH-LOGICAL-c453t-e5af1a7d69c7175ed7b25fc7039575cbe7e7b23c18faba9f9d66631dc6d859ee3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10971-012-2703-0$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10971-012-2703-0$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>309,310,314,776,780,785,786,4036,4037,23909,23910,25118,27901,27902,41464,42533,51294</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27652336$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Park, Hyungjin</creatorcontrib><creatorcontrib>Hwang, Young Hwan</creatorcontrib><creatorcontrib>Bae, Byeong-Soo</creatorcontrib><title>Sol–gel processed Cu2ZnSnS4 thin films for a photovoltaic absorber layer without sulfurization</title><title>Journal of sol-gel science and technology</title><addtitle>J Sol-Gel Sci Technol</addtitle><description>Sol–gel processed Cu
2
ZnSnS
4
(CZTS) thin films were fabricated without sulfurization for application as a photovoltaic absorber layer. The precursor solution was made from CuCl
2
, Zn(ac)
2
, SnCl
2
, thiourea, and 2-methoxyethanol and the spin-coated film was annealed at temperature above 500 °C under a N
2
atmosphere. A homogeneous and compositionally uniform film with single CZTS phase was obtained. Film composition featuring larger grains, which is desirable in photovoltaic cells, was obtained with heat treatment at 540 °C. The grain size was up to 1 μm and the Cu/(Zn + Sn) and Zn/Sn ratios were 0.93 and 1.07, respectively and the band gap energy was 1.56 eV.</description><subject>Absorbers</subject><subject>Ceramics</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Colloidal gels. Colloidal sols</subject><subject>Colloidal state and disperse state</subject><subject>Composites</subject><subject>Copper</subject><subject>Copper zinc tin sulfide</subject><subject>CZT</subject><subject>Energy gap</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Glass</subject><subject>Grain size</subject><subject>Heat treatment</subject><subject>Inorganic Chemistry</subject><subject>Materials Science</subject><subject>Methyl cellosolve</subject><subject>Nanotechnology</subject><subject>Natural Materials</subject><subject>Optical and Electronic Materials</subject><subject>Original Paper</subject><subject>Photovoltaic cells</subject><subject>Sol-gel processes</subject><subject>Solar cells</subject><subject>Spin coating</subject><subject>Sulfurization</subject><subject>Thin films</subject><subject>Tin</subject><subject>Zinc</subject><issn>0928-0707</issn><issn>1573-4846</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNqFkc2qFDEQhYMoOHf0AdwF5MLdtOank3SWl8E_GHAxunET0-lkJpdMZ0x1XxlXvoNv6JOYYQYFQdxUQdVXhzochJ5R8oISol4CJVrRhlDWMEV4Qx6gBRWKN23XyodoQTTrGqKIeoyuAO4IIaKlaoE-b3L6-f3H1id8KNl5AD_g1cw-jZtx0-JpF0ccYtoDDrlgiw-7POX7nCYbHbY95NL7gpM91vo1Trs8TxjmFOYSv9kp5vEJehRsAv_00pfo4-tXH1Zvm_X7N-9Wt-vGtYJPjRc2UKsGqZ2iSvhB9UwEV61ooYTrvfJ1wh3tgu2tDnqQUnI6ODl0QnvPl-jmrFttfJk9TGYfwfmU7OjzDIZKRbnitNP_R1umNeGi5RV9_hd6l-cyViOGMaEFbzsmKkXPlCsZoPhgDiXubTkaSswpHnOOx9R4zCkeQ-rN9UXZgrMpFDu6CL8PmZKCcS4rx84c1NW49eXPB_8W_wUFj6CT</recordid><startdate>2013</startdate><enddate>2013</enddate><creator>Park, Hyungjin</creator><creator>Hwang, Young Hwan</creator><creator>Bae, Byeong-Soo</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>7SP</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>2013</creationdate><title>Sol–gel processed Cu2ZnSnS4 thin films for a photovoltaic absorber layer without sulfurization</title><author>Park, Hyungjin ; Hwang, Young Hwan ; Bae, Byeong-Soo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c453t-e5af1a7d69c7175ed7b25fc7039575cbe7e7b23c18faba9f9d66631dc6d859ee3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Absorbers</topic><topic>Ceramics</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Colloidal gels. Colloidal sols</topic><topic>Colloidal state and disperse state</topic><topic>Composites</topic><topic>Copper</topic><topic>Copper zinc tin sulfide</topic><topic>CZT</topic><topic>Energy gap</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Glass</topic><topic>Grain size</topic><topic>Heat treatment</topic><topic>Inorganic Chemistry</topic><topic>Materials Science</topic><topic>Methyl cellosolve</topic><topic>Nanotechnology</topic><topic>Natural Materials</topic><topic>Optical and Electronic Materials</topic><topic>Original Paper</topic><topic>Photovoltaic cells</topic><topic>Sol-gel processes</topic><topic>Solar cells</topic><topic>Spin coating</topic><topic>Sulfurization</topic><topic>Thin films</topic><topic>Tin</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Park, Hyungjin</creatorcontrib><creatorcontrib>Hwang, Young Hwan</creatorcontrib><creatorcontrib>Bae, Byeong-Soo</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of sol-gel science and technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Park, Hyungjin</au><au>Hwang, Young Hwan</au><au>Bae, Byeong-Soo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Sol–gel processed Cu2ZnSnS4 thin films for a photovoltaic absorber layer without sulfurization</atitle><jtitle>Journal of sol-gel science and technology</jtitle><stitle>J Sol-Gel Sci Technol</stitle><date>2013</date><risdate>2013</risdate><volume>65</volume><issue>1</issue><spage>23</spage><epage>27</epage><pages>23-27</pages><issn>0928-0707</issn><eissn>1573-4846</eissn><abstract>Sol–gel processed Cu
2
ZnSnS
4
(CZTS) thin films were fabricated without sulfurization for application as a photovoltaic absorber layer. The precursor solution was made from CuCl
2
, Zn(ac)
2
, SnCl
2
, thiourea, and 2-methoxyethanol and the spin-coated film was annealed at temperature above 500 °C under a N
2
atmosphere. A homogeneous and compositionally uniform film with single CZTS phase was obtained. Film composition featuring larger grains, which is desirable in photovoltaic cells, was obtained with heat treatment at 540 °C. The grain size was up to 1 μm and the Cu/(Zn + Sn) and Zn/Sn ratios were 0.93 and 1.07, respectively and the band gap energy was 1.56 eV.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s10971-012-2703-0</doi><tpages>5</tpages></addata></record> |
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| subjects | Absorbers Ceramics Chemistry Chemistry and Materials Science Colloidal gels. Colloidal sols Colloidal state and disperse state Composites Copper Copper zinc tin sulfide CZT Energy gap Exact sciences and technology General and physical chemistry Glass Grain size Heat treatment Inorganic Chemistry Materials Science Methyl cellosolve Nanotechnology Natural Materials Optical and Electronic Materials Original Paper Photovoltaic cells Sol-gel processes Solar cells Spin coating Sulfurization Thin films Tin Zinc |
| title | Sol–gel processed Cu2ZnSnS4 thin films for a photovoltaic absorber layer without sulfurization |
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