Kinetics of reduction of water to hydrogen by visible light on alumina supported Pt–CdS photocatalysts
The kinetics of hydrogen production from photolysis of water on alumina supported Pt–CdS catalyst using visible light has been studied. An induction period with negligible rate was observed upon illumination of catalyst. The rate gradually increases and again falls down. The rate has been observed t...
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| Veröffentlicht in: | International journal of hydrogen energy 2009, Vol.34 (1), p.130-137 |
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| container_title | International journal of hydrogen energy |
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| creator | Sahu, Namita Upadhyay, S.N. Sinha, A.S.K. |
| description | The kinetics of hydrogen production from photolysis of water on alumina supported Pt–CdS catalyst using visible light has been studied. An induction period with negligible rate was observed upon illumination of catalyst. The rate gradually increases and again falls down. The rate has been observed to be proportional to the sulfide ions adsorbed on the surface of CdS. The induction period has been related to the re-establishment of adsorption equilibrium of sulfide ions on the catalyst surface under illumination. The decrease in rate is due to the deactivation of catalyst by hydrogen. A power law type rate expression for hydrogen production has been proposed which takes into account the deactivation of the catalyst. |
| doi_str_mv | 10.1016/j.ijhydene.2008.09.043 |
| format | Article |
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An induction period with negligible rate was observed upon illumination of catalyst. The rate gradually increases and again falls down. The rate has been observed to be proportional to the sulfide ions adsorbed on the surface of CdS. The induction period has been related to the re-establishment of adsorption equilibrium of sulfide ions on the catalyst surface under illumination. The decrease in rate is due to the deactivation of catalyst by hydrogen. A power law type rate expression for hydrogen production has been proposed which takes into account the deactivation of the catalyst.</description><identifier>ISSN: 0360-3199</identifier><identifier>EISSN: 1879-3487</identifier><identifier>DOI: 10.1016/j.ijhydene.2008.09.043</identifier><identifier>CODEN: IJHEDX</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Alternative fuels. 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An induction period with negligible rate was observed upon illumination of catalyst. The rate gradually increases and again falls down. The rate has been observed to be proportional to the sulfide ions adsorbed on the surface of CdS. The induction period has been related to the re-establishment of adsorption equilibrium of sulfide ions on the catalyst surface under illumination. The decrease in rate is due to the deactivation of catalyst by hydrogen. A power law type rate expression for hydrogen production has been proposed which takes into account the deactivation of the catalyst.</description><subject>Alternative fuels. Production and utilization</subject><subject>Aluminum oxide</subject><subject>Applied sciences</subject><subject>Catalysts</subject><subject>Deactivation</subject><subject>Energy</subject><subject>Exact sciences and technology</subject><subject>Fuels</subject><subject>Hydrogen</subject><subject>Hydrogen production</subject><subject>Illumination</subject><subject>Kinetics</subject><subject>Photocatalysis</subject><subject>Platinum</subject><subject>Solar energy</subject><subject>Sulfides</subject><subject>Surface chemistry</subject><issn>0360-3199</issn><issn>1879-3487</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNqFkEGO1DAQRSMEEs3AFZA3SGwSquIkjnegFgMjRgIJWFuOU552K20H25lR77gDF-AsHIWTkFYPbFmVSnr_l-oVxXOECgG7V_vK7XfHkTxVNUBfgayg4Q-KDfZClrzpxcNiA7yDkqOUj4snKe0BUEAjN4X74DxlZxILlkUaF5Nd8KflTmeKLAe2dsdwQ54NR3brkhsmYpO72WUW_K-feloOzmuWlnkOMdPIPuXf339sx89s3oUcjM56OqacnhaPrJ4SPbufF8XXy7dftu_L64_vrrZvrkvDRZtLwa0FK4zuWg2DbAc71NYQoGlHaceaD40wtuE1R7IDokTQWvd1LXvBedPwi-LluXeO4dtCKauDS4amSXsKS1LYCeQC-w5XtDujJoaUIlk1R3fQ8agQ1Mmt2qu_btXJrQKpVrdr8MX9DZ2MnmzU3rj0L10jtFh3J-71maP14VtHUSXjyBsaXSST1Rjc_079AUbVlr0</recordid><startdate>2009</startdate><enddate>2009</enddate><creator>Sahu, Namita</creator><creator>Upadhyay, S.N.</creator><creator>Sinha, A.S.K.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QQ</scope><scope>7SP</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>2009</creationdate><title>Kinetics of reduction of water to hydrogen by visible light on alumina supported Pt–CdS photocatalysts</title><author>Sahu, Namita ; Upadhyay, S.N. ; Sinha, A.S.K.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c375t-73ff0f7ca65a0b95bfb2fce01c5d9fd23b47cf43231efb11910aaa82298733443</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Alternative fuels. 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| ispartof | International journal of hydrogen energy, 2009, Vol.34 (1), p.130-137 |
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| source | Elsevier ScienceDirect Journals |
| subjects | Alternative fuels. Production and utilization Aluminum oxide Applied sciences Catalysts Deactivation Energy Exact sciences and technology Fuels Hydrogen Hydrogen production Illumination Kinetics Photocatalysis Platinum Solar energy Sulfides Surface chemistry |
| title | Kinetics of reduction of water to hydrogen by visible light on alumina supported Pt–CdS photocatalysts |
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