Synthesis and optical properties of non-stoichiometric lanthanide (Sm, Eu, Tm, Yb) fluorides
Nonstoichiometric samarium, europium, ytterbium, and thulium fluorides were prepared by reduction of the corresponding trifluorides with the same lanthanide metal or silicon. Crystal lattice type and lattice parameters of the compounds were determined by powder X-ray diffraction. In the synthesis of...
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| Veröffentlicht in: | Russian journal of inorganic chemistry 2010, Vol.55 (6), p.841-847 |
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| container_title | Russian journal of inorganic chemistry |
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| creator | Ivanenko, A. P Kompanichenko, N. M Omelchuk, A. A Zinchenko, V. F Timukhina, E. V |
| description | Nonstoichiometric samarium, europium, ytterbium, and thulium fluorides were prepared by reduction of the corresponding trifluorides with the same lanthanide metal or silicon. Crystal lattice type and lattice parameters of the compounds were determined by powder X-ray diffraction. In the synthesis of ytterbium fluoride, the formation of cubic superstructure Yb₂₇F₆₄ was detected. Data reflecting the relationship between the structure and optical characteristics of the phases (IR spectra, electronic diffuse reflectance spectra) were obtained and the spectral bands were assigned. |
| doi_str_mv | 10.1134/S0036023610060045 |
| format | Article |
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| subjects | Chemistry Chemistry and Materials Science Crystal lattices Electronics Europium Fluorides Inorganic Chemistry Spectra Spectral bands Synthesis Synthesis and Properties of Inorganic Compounds Ytterbium |
| title | Synthesis and optical properties of non-stoichiometric lanthanide (Sm, Eu, Tm, Yb) fluorides |
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