Thermal conductivity and dynamic mechanical property of glycidyl methacrylate-grafted multiwalled carbon nanotube/epoxy composites
The well dispersed multiwalled carbon nanotube (MWCNT)/epoxy composites were prepared by functionalization of the MWCNT surfaces with glycidyl methacrylate (GMA). The morphology and thermal properties of the epoxy nanocomposites were investigated and compared with the surface characteristics of MWCN...
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| Veröffentlicht in: | Journal of applied polymer science 2012-01, Vol.123 (2), p.888-896 |
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| container_title | Journal of applied polymer science |
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| creator | Teng, Chih-Chun Ma, Chen-Chi M. Yang, Shin-Yi Chiou, Kuo-Chan Lee, Tzong-Ming Chiang, Chin-Lung |
| description | The well dispersed multiwalled carbon nanotube (MWCNT)/epoxy composites were prepared by functionalization of the MWCNT surfaces with glycidyl methacrylate (GMA). The morphology and thermal properties of the epoxy nanocomposites were investigated and compared with the surface characteristics of MWCNTs. GMA‐grafted MWCNTs improved the dispersion and interfacial adhesion in epoxy resin, and enhanced the network structure. The storage modulus of 3 phr GMA‐MWCNTs/epoxy composites at 50°C increased from 0.32 GPa to 2.87 GPa (enhanced by 799%) and the increased tanδ from 50.5°C to 61.7°C (increased by 11.2°C) comparing with neat epoxy resin, respectively. Furthermore, the thermal conductivity of 3 phr GMA‐MWCNTs/epoxy composite is increased by 183%, from 0.2042 W/mK (neat epoxy) to 0.5781 W/mK. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 |
| doi_str_mv | 10.1002/app.34580 |
| format | Article |
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The morphology and thermal properties of the epoxy nanocomposites were investigated and compared with the surface characteristics of MWCNTs. GMA‐grafted MWCNTs improved the dispersion and interfacial adhesion in epoxy resin, and enhanced the network structure. The storage modulus of 3 phr GMA‐MWCNTs/epoxy composites at 50°C increased from 0.32 GPa to 2.87 GPa (enhanced by 799%) and the increased tanδ from 50.5°C to 61.7°C (increased by 11.2°C) comparing with neat epoxy resin, respectively. Furthermore, the thermal conductivity of 3 phr GMA‐MWCNTs/epoxy composite is increased by 183%, from 0.2042 W/mK (neat epoxy) to 0.5781 W/mK. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011</description><identifier>ISSN: 0021-8995</identifier><identifier>ISSN: 1097-4628</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.34580</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Adhesion ; Applied sciences ; carbon nanotubes ; Composites ; Dispersions ; Epoxy resins ; Exact sciences and technology ; Forms of application and semi-finished materials ; Heat transfer ; Materials science ; Multi wall carbon nanotubes ; Nanocomposites ; Polymer industry, paints, wood ; Polymer matrix composites ; Polymers ; Technology of polymers ; Thermal conductivity ; thermal properties</subject><ispartof>Journal of applied polymer science, 2012-01, Vol.123 (2), p.888-896</ispartof><rights>Copyright © 2011 Wiley Periodicals, Inc.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3980-b28343f028858c142f5f6f5f7b022a17899880e90899965dd358a8a43d0ed2013</citedby><cites>FETCH-LOGICAL-c3980-b28343f028858c142f5f6f5f7b022a17899880e90899965dd358a8a43d0ed2013</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.34580$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.34580$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=25505793$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Teng, Chih-Chun</creatorcontrib><creatorcontrib>Ma, Chen-Chi M.</creatorcontrib><creatorcontrib>Yang, Shin-Yi</creatorcontrib><creatorcontrib>Chiou, Kuo-Chan</creatorcontrib><creatorcontrib>Lee, Tzong-Ming</creatorcontrib><creatorcontrib>Chiang, Chin-Lung</creatorcontrib><title>Thermal conductivity and dynamic mechanical property of glycidyl methacrylate-grafted multiwalled carbon nanotube/epoxy composites</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>The well dispersed multiwalled carbon nanotube (MWCNT)/epoxy composites were prepared by functionalization of the MWCNT surfaces with glycidyl methacrylate (GMA). The morphology and thermal properties of the epoxy nanocomposites were investigated and compared with the surface characteristics of MWCNTs. GMA‐grafted MWCNTs improved the dispersion and interfacial adhesion in epoxy resin, and enhanced the network structure. The storage modulus of 3 phr GMA‐MWCNTs/epoxy composites at 50°C increased from 0.32 GPa to 2.87 GPa (enhanced by 799%) and the increased tanδ from 50.5°C to 61.7°C (increased by 11.2°C) comparing with neat epoxy resin, respectively. Furthermore, the thermal conductivity of 3 phr GMA‐MWCNTs/epoxy composite is increased by 183%, from 0.2042 W/mK (neat epoxy) to 0.5781 W/mK. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011</description><subject>Adhesion</subject><subject>Applied sciences</subject><subject>carbon nanotubes</subject><subject>Composites</subject><subject>Dispersions</subject><subject>Epoxy resins</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>Heat transfer</subject><subject>Materials science</subject><subject>Multi wall carbon nanotubes</subject><subject>Nanocomposites</subject><subject>Polymer industry, paints, wood</subject><subject>Polymer matrix composites</subject><subject>Polymers</subject><subject>Technology of polymers</subject><subject>Thermal conductivity</subject><subject>thermal properties</subject><issn>0021-8995</issn><issn>1097-4628</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNp1kU9v1DAQxS0EEkvhwDeIhJDgkK7_xLFzrKqyrbSCHorozZp1nK6LYwfboc2VT17Dlh6QOFge6f3eG48HobcEHxOM6Rqm6Zg1XOJnaEVwJ-qmpfI5WhWN1LLr-Ev0KqVbjAnhuF2hX1d7E0dwlQ6-n3W2P21eKvB91S8eRqur0eg9eKsLM8UwmVj0MFQ3btG2X1zR8x50XBxkU99EGLLpq3F22d6Bc6XWEHfBVx58yPPOrM0U7pfSb5xCstmk1-jFAC6ZN4_3Efr66ezq9LzeftlcnJ5sa806iesdlaxhA6ZScqlJQwc-tOWIHaYUiCjDSYlNh0vRtbzvGZcgoWE9Nj3FhB2hD4fcMsaP2aSsRpu0cQ68CXNSpBWEta3AoqDv_kFvwxx9eZ0inLQdJ1R0hfp4oHQMKUUzqCnaEeKiCFa_t6HKNtSfbRT2_WMipPKVQwSvbXoyUM4xL5GFWx-4O-vM8v9AdXJ5-Te5Pjhsyub-yQHxu2oFE1x9-7xR8npDttfiXHH2AJm8qVc</recordid><startdate>20120115</startdate><enddate>20120115</enddate><creator>Teng, Chih-Chun</creator><creator>Ma, Chen-Chi M.</creator><creator>Yang, Shin-Yi</creator><creator>Chiou, Kuo-Chan</creator><creator>Lee, Tzong-Ming</creator><creator>Chiang, Chin-Lung</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20120115</creationdate><title>Thermal conductivity and dynamic mechanical property of glycidyl methacrylate-grafted multiwalled carbon nanotube/epoxy composites</title><author>Teng, Chih-Chun ; Ma, Chen-Chi M. ; Yang, Shin-Yi ; Chiou, Kuo-Chan ; Lee, Tzong-Ming ; Chiang, Chin-Lung</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3980-b28343f028858c142f5f6f5f7b022a17899880e90899965dd358a8a43d0ed2013</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Adhesion</topic><topic>Applied sciences</topic><topic>carbon nanotubes</topic><topic>Composites</topic><topic>Dispersions</topic><topic>Epoxy resins</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>Heat transfer</topic><topic>Materials science</topic><topic>Multi wall carbon nanotubes</topic><topic>Nanocomposites</topic><topic>Polymer industry, paints, wood</topic><topic>Polymer matrix composites</topic><topic>Polymers</topic><topic>Technology of polymers</topic><topic>Thermal conductivity</topic><topic>thermal properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Teng, Chih-Chun</creatorcontrib><creatorcontrib>Ma, Chen-Chi M.</creatorcontrib><creatorcontrib>Yang, Shin-Yi</creatorcontrib><creatorcontrib>Chiou, Kuo-Chan</creatorcontrib><creatorcontrib>Lee, Tzong-Ming</creatorcontrib><creatorcontrib>Chiang, Chin-Lung</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Teng, Chih-Chun</au><au>Ma, Chen-Chi M.</au><au>Yang, Shin-Yi</au><au>Chiou, Kuo-Chan</au><au>Lee, Tzong-Ming</au><au>Chiang, Chin-Lung</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermal conductivity and dynamic mechanical property of glycidyl methacrylate-grafted multiwalled carbon nanotube/epoxy composites</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2012-01-15</date><risdate>2012</risdate><volume>123</volume><issue>2</issue><spage>888</spage><epage>896</epage><pages>888-896</pages><issn>0021-8995</issn><issn>1097-4628</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>The well dispersed multiwalled carbon nanotube (MWCNT)/epoxy composites were prepared by functionalization of the MWCNT surfaces with glycidyl methacrylate (GMA). The morphology and thermal properties of the epoxy nanocomposites were investigated and compared with the surface characteristics of MWCNTs. GMA‐grafted MWCNTs improved the dispersion and interfacial adhesion in epoxy resin, and enhanced the network structure. The storage modulus of 3 phr GMA‐MWCNTs/epoxy composites at 50°C increased from 0.32 GPa to 2.87 GPa (enhanced by 799%) and the increased tanδ from 50.5°C to 61.7°C (increased by 11.2°C) comparing with neat epoxy resin, respectively. Furthermore, the thermal conductivity of 3 phr GMA‐MWCNTs/epoxy composite is increased by 183%, from 0.2042 W/mK (neat epoxy) to 0.5781 W/mK. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.34580</doi><tpages>9</tpages></addata></record> |
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| subjects | Adhesion Applied sciences carbon nanotubes Composites Dispersions Epoxy resins Exact sciences and technology Forms of application and semi-finished materials Heat transfer Materials science Multi wall carbon nanotubes Nanocomposites Polymer industry, paints, wood Polymer matrix composites Polymers Technology of polymers Thermal conductivity thermal properties |
| title | Thermal conductivity and dynamic mechanical property of glycidyl methacrylate-grafted multiwalled carbon nanotube/epoxy composites |
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